Abstract
This work is to study the removal of phenol from aqueous solutions by adsorption using three different adsorbents, clinoptilolite, montmorillonite, and hydrotalcite (HT). Except for montmorillonite, the other adsorbents were treated. Clinoptilolite was modified using cetyltrimethylammonium bromide (CTAB) and hydrotalcite was calcined by heating to 550∘C. Adsorption isotherms of phenol on all of the mentioned adsorbents was determined by using the batch equilibration technique and indicated that, the adsorption behavior could be modelled by using the Modified Freundlich equation. The differences observed in the isotherms were explained by the variations in adsorbent-adsorbate interactions under the effects of the different surface structures of adsorbents and the pH dependent ionization behavior of phenol. Calcined hydrotalcite (HTC) was found to be the best among the studied adsorbents since it can adsorb 52% of phenol from a solution containing initially 1 g/L phenol for the 1/100 adsorbent solution ratio while the others can adsorb only 8% of phenol for the same concentration and adsorbent solution ratio.
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References
Banat, F.A., B. Al-Bashir, S. Al-Asheh, and O. Hayajneh, “Adsorption of Phenol by Bentonite,” Environmental Pollution, 107, 390–398 (2000).
Bowman, R.S., G.M. Haggerty, R.G. Huddleston, D. Neel, and M.M. Flynn, “Sorption of Nonpolar Organic Compounds, Inorganic Cations, and Inorganic Oxyanions by Surfactant Modified Zeolites,” in Surfactant-Enhanced Subsurface Remediation, D.A. Sabatini, R.C. Knox, and J.H. Harwell (Eds.), American Chemical Society, Washington, DC, 1995.
Brownawell, B.J., H. Chen, J.M. Collier, and J.C. Westall, “Adsorption of Organic Cations to Natural Materials,” Environmental ScienceTechnol, 24, 1234–1241 (1990).
Grim, R.E., Clay Mineralogy, 78, Mc Graw-Hill, Inc., New York, 1968.
Haggerty, G.M. and R.S. Bowman, “Sorption of Chromate and Other Inorganic Anions by Organo-Zeolite,” Environmental Science and Technology, 28(3), 452–458 (1994).
Hermosin, M.C., I. Pavlovic, M.A. Ulibarri, and J. Cornejo, “Hydrotalcite as Sorbent for Trinitrophenol: Sorption Capacity and Mechanism,” Wat. Res., 30(1), 171–177 (1996).
Klumpp, E., C. Contreras-Ortega, P. Klahre, F.J. Tino, S. Yapar, C. Portillo, S. Stegen, F. Queirolo, and M.J. Shcwuger, “Sorption of 2,4-dichlorophenol on Modified Hydrotalcites,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 230, 111–116 (2004).
Li, Z. and R.S. Bowman, “Counterion Effects on the Sorption of Cationic Surfactant and Chromate on Natural Clinoptilolite,” Environ. Sci. Technol., 31, 2407–2412, 1997.
Li, Z., I. Anghel, and R.S. Bowman, “Sorption of Oxyanions by Surfactant Modified Zeolite,” J. Dispersion Science and Technology, 19(6/7), 843–857 (1998).
Li, Z., T. Burt, and R.S. Bowman, “Sorption of Ionizable Organic Solutes by Surfactant Modified Zeolite,” Environ. Sci. Technol., 34, 3756–3760 (2000).
Ming, D.W. and J.B. Dixon, “Quantitative Determination of Clinoptilolite in Soils by a Cation Exchange Capacity Method,” Clays and Clay Minerals, 35(6), 463–468, 1987.
Nevskaia, D.M., A. Santianes, V. Munoz, and A. Guerro-Ruiz, “Interaction of Aqueous Solutions of Phenol with Commercial Activated Carbons: An Adsorption and Kinetic Study,” Carbon, 37, 1065–1074 (1999).
Oscik, J., Adsorption, John Wiley & Sons, Newyork, 1982.
Reichle, W.T., “Anionic Clay Minerals,” Chemtech, 58–63 (1986).
Shen, Y.H., “Removal of Phenol from Water by Adsorption Flocculation Using Organo-Bentonite,” Water Research, 36, 1107–1114 (2002).
Şişmanoglu, T. and S. Pura, “Adsorption of Aqueous Nitrophenols on Clinoptilolite,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 180, 1–6 (2001).
Urano, K., Y. Koichi, and Y. Nakazawa, “Equilibria for Adsorption of Organic Compounds on Activated Carbons in Aqueous Solutions 1. Modified Freundlich Isotherm Equation and Adsorption Potentials of Organic Compounds,” Journal of Colloid and Interface Science, 81(2), 477–485 (1981).
Vaccari, A., “Preparation and Catalytic Properties of Cationic and Anionic Clays,” Catalysis Today, 41, 53–71, 1998.
Viraraghavan, T. and F. de Mario Alfaro, “Adsorption of Phenol from Waste Water by Peat, Fly Ash and Bentonite,” Journal of Hazardous Materials, 57, 59–70, 1998.
Wang, L.K. and D.F. Langley, “Determining Cationic Surfactant Concentration,” Ind. Eng. Chem. Prod. Res. Dev., 14(3), 210–213 (1975).
Wu, P.X., Z.W. Liao, H.F. Zhang, and J.G. Guo, “Adsorption of Phenol on Inorganic-Organic Pillared Montmorillonite in Polluted Water,” Environment International, 26, 401–407 (2001).
Yapar, S., P. Klahre, and E. Klumpp, “Hydrotalcite as a Potential Sorbent for the Removal of 2,4 Dicholorophenol,” Turkish Journal of Engineering and Environmental Sciences, 28, 41–48 (2004).
Yilmaz, N. and S. Yapar, “Adsorption Properties of Tetradecyl- and Hexadecyl Trimethylammonium Bentonites,” Applied Clay Sciecne, 27, 223–228 (2004).
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Yapar, S., Yilmaz, M. Removal of Phenol by Using Montmorillonite, Clinoptilolite and Hydrotalcite. Adsorption 10, 287–298 (2005). https://doi.org/10.1007/s10450-005-4814-1
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DOI: https://doi.org/10.1007/s10450-005-4814-1