Abstract
A new matrix resin was recently introduced for composite materials, based on acrylic resin chemistry allowing standard room temperature infusion techniques to be used to produce recyclable thermoplastic composites. This is a significant advance, particularly for more environmentally-friendly production of large marine structures such as boats. However, for such applications it is essential to demonstrate that composites produced with these resins resist sea water exposure in service. This paper presents results from a wet aging study of unreinforced acrylic and glass and carbon fibre reinforced acrylic composites. It is shown that the acrylic matrix resin is very stable in seawater, showing lower property losses after seawater aging than those of a commonly-used epoxy matrix resin. Carbon fibre reinforced acrylic also shows good property retention after aging, while reductions in glass fibre reinforced composite strengths suggest that specific glass fibre sizing may be required for optimum durability.
Similar content being viewed by others
References
Smith CS.: Design of Marine Structures in Composite Materials. Elsevier, London (1990)
Mouritz A., Gellert E., Burchill P., Challis K.: Review of advanced composite structures for naval ships and submarines. Compos. Struct. 53(1), 21–41 (2001)
Shenoi R.A., Wellicome J.F.: Composite materials in Maritime Structures. Technology series, Cambridge Ocean (1993)
Barblou P, APER (Association pour la Plaisance Eco-Responsable), Network of dismantling recreational craft in France, presented at “The Future of Yacht Recycling”, METS 2015, 16th November (2015), Amsterdam.
Smith R (Editor), Biodegradable Polymers for Industrial Applications, CRC Woodhead Publishers, (2005)
Arkema website, http://www.arkema.com/en/innovation/arkema-sailing/arkema-boats/mini-6-50-prototype/
Josserand C., Schirrer R., Davies P.: Influence of water on crack propagation in poly methyl methacrylate: craze stress and craze fibril lifetime. J. Mater. Sci. 30, 1772–1780 (1995)
Mouritz AP, Gibson AG, Fire Properties of Polymer Composite Materials, Springer publishers, (2006), p34.
Manfredi L.B., Rodrıguez E.S., Wladyka-Przybylak M., Vazquez A.: Thermal degradation and fire resistance of unsaturated polyester, modified acrylic resins and their composites with natural fibres. Polym. Degrad. Stab. 91, 255–261 (2006)
Kalachandra S., Turner D.T.: Water sorption of plasticized denture acrylic lining materials, pp. 161–164. Dent. Mater, May (1989)
Arima T., Murata H., Hamada T.: Properties of highly cross-linked auto-polymerizing reline acrylic resins, pp. 55–59. J. Prosthetic Dentistry, January (1995)
Weitsman Y.J.: Fluid Effects in Polymers and Polymeric Composites. Springer, New York (2012)
Davies P., Rajapakse Y. (eds.): Durability of Composites in a Marine Environment. Springer, Amsterdam (2014)
Gutierrez J, LeLay F, Hoarau P, A study of the aging of glass fibre-resin composites in a marine environment, in Proceedings Nautical Construction with composite materials, editors P. Davies, L. Lemoine, Paris, (1992, IFREMER) Publication ISSN-0761–3989, pp 338–346
Gellert EP, Turley DM, Seawater immersion ageing of glass-fibre reinforced polymer laminates for marine applications, Composites Part A, 30, Issue 11, November (1999), 1259–1265
Davies P., Mazeas F., Casari P.: Sea water aging of glass reinforced composites: shear behaviour and damage modeling. J. Compos. Mater. 35(15), 1343–1372 (2001)
Kootsookos A., Mouritz A.P.: Seawater durability of glass- and carbon-polymer composites. Compos. Sci. Technol. 64, 1503–1511 (2004)
Marouani S, Curtil L, Hamelin P, Ageing of carbon/epoxy and carbon/vinylester composites used in the reinforcement and/or the repair of civil engineering structures, Compos. Part B, Volume 43, Issue 4, June (2012), 2020–2030
Siriruk A, Penumadu D, Degradation in fatigue behavior of carbon fiber–vinyl ester based composites due to sea environment, Compos. Part B, Volume 61, May (2014), 94–98
Lee S-B, Rockett TJ, Hoffman RD, Interactions of water with unsaturated polyester, vinyl ester and acrylic resins, Polymer, (1992), 33, 17 3691–3697
Pritchard G., Speake S.D.: The use of water absorption kinetic data to predict laminate property changes. Composites. 18(3), 227–232 (1987)
Boisseau A., Davies P., Thiebaud F.: Sea water ageing of composites for ocean energy conversion systems: influence of glass fibre type on static behaviour. Appl. Compos. Mater. 19, 459–473 (2012)
Tual N., Carrere N., Davies P., Bonnemains T., Lolive E.: Characterization of sea water ageing effects on mechanical properties of carbon/epoxy composites for tidal turbine blades. Compos. Part A. 78, 380–389 (2015)
Acknowledgments
The authors are grateful to Pierre Gérard and Sebastien Taillemite of Arkema, for the gift of unreinforced and carbon fibre reinforced acrylic specimens, and for helpful discussions.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Davies, P., Le Gac, PY. & Le Gall, M. Influence of Sea Water Aging on the Mechanical Behaviour of Acrylic Matrix Composites. Appl Compos Mater 24, 97–111 (2017). https://doi.org/10.1007/s10443-016-9516-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10443-016-9516-1