Corrosion of 3D-Printed Orthopaedic Implant Materials


3D-printing technologies such as electron beam melting (EBM) have allowed for patient-specific orthopaedic implants, however differences generated from the fabrication process may alter the corrosion properties of Ti6Al4V implants. This study evaluated the corrosion characteristics of EBM-fabricated Ti6Al4V, alongside any linked microstructural and surface changes. EBM-fabricated Ti6Al4V and wrought Ti6Al4V specimens (n = 10 per group) underwent microstructural and surface characterisation before and after corrosion testing. Cyclic potentiodynamic polarisation of specimens was conducted in accordance with ASTM Standard F2129-17. The degree of corrosion damage was subsequently assessed via qualitative and quantitative measures. EBM-fabricated Ti6Al4V demonstrated a higher proportion of β phases and greater surface roughness, compared to wrought Ti6Al4V. Significant differences were observed for all corrosion parameters between the two groups. The lower breakdown potentials (Eb) for EBM-fabricated Ti6Al4V (2.035 V), compared to wrought Ti6Al4V (3.667 V), indicate a lower resistance to pitting corrosion. A greater resultant spread, and severity of corrosion damage was noted on wrought Ti6Al4V. An inferior in vitro corrosion resistance was observed for EBM-fabricated Ti6Al4V. Without post-processing, the rougher surface and differences in microstructure are likely to contribute to this. This suggests potential clinical implications upon in vivo implantation, although corrosion measures remain above recommended minimums.

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Correspondence to Matthew Henry Pelletier.

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Associate Editor Andreas Anayiotos oversaw the review of this article.

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Mah, D., Pelletier, M.H., Lovric, V. et al. Corrosion of 3D-Printed Orthopaedic Implant Materials. Ann Biomed Eng 47, 162–173 (2019).

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  • Electron beam melting
  • Titanium alloy
  • Pedicle screw
  • Corrosion
  • In vitro study