Abstract
CNT nanofluid is getting attention in heat transfer applications due to its high thermal conductivity in comparison with conventional fluids. Effective dispersion of CNT in a polar base fluid is a challenging task because CNT is hydrophobic. Researchers used surfactants to overcome this problem but the addition of surfactants has some disadvantages like foaming, stickiness and an increase in viscosity, which increases pumping power required to pump the nanofluid. Alternate methods to prepare efficient nanofluid have to be found. This led to the synthesis of hybrid nanofluid. In this paper, Cu–CNT hybrid nanoparticles have been synthesized by in situ synthesis of Cu nanoparticles in the presence of CNT nanoparticles and dispersed in double-distilled water without surfactant to get stable nanofluid. FESEM with EDX and Raman spectroscopy were used to characterize surface morphology of Cu–CNT hybrid nanoparticles and it was found that copper nanoparticles were present on the outer surface of MWCNT. The dispersibility of Cu–CNT hybrid nanofluid was investigated by spectral analysis method, Zeta potential and DLS. The results revealed that samples were highly stable and the maximum stability was found to be more than 170 days. Nanofluid showed a negligible increase in density and viscosity and showed an enhancement in thermal conductivity compared to base fluid which is essential for heat transfer applications.
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References
Afrand M, Toghraie D, Ruhani B (2016) Effects of temperature and nanoparticles concentration on rheological behavior of Fe3O4-Ag/EG hybrid nanofluid: An experimental study. Exp Therm Fluid Sci. https://doi.org/10.1016/j.expthermflusci.2016.04.007
Ahmadi AA, Arabbeiki M, Ali HM et al (2020) Configuration and optimization of a minichannel using water–alumina nanofluid by non-dominated sorting genetic algorithm and response surface method. Nanomaterials. https://doi.org/10.3390/nano10050901
Ahmed W, Chowdhury ZZ, Kazi SN et al (2020) Characteristics investigation on heat transfer growth of sonochemically synthesized ZnO-DW based nanofluids inside square heat exchanger. J Therm Anal Calorim. https://doi.org/10.1007/s10973-020-09593-z
Ali HM (2020) Recent advancements in PV cooling and efficiency enhancement integrating phase change materials based systems—a comprehensive review. Sol Energy 197:163–198
Ali H, Raza Shah T, Babar H, Ali AM (2018) Hybrid nanofluids: Techniques and challenges of stability enhancement. In: 4Th Int Conf Adv Mech Eng Istanbul 2018 60–76
Alimohammadi F, Gashti MP, Shamei A, Kiumarsi A (2012) Deposition of silver nanoparticles on carbon nanotube by chemical reduction method: Evaluation of surface, thermal and optical properties. Superlattices Microstruct. https://doi.org/10.1016/j.spmi.2012.04.015
Amiri A, Shanbedi M, Eshghi H et al (2012) Highly dispersed multiwalled carbon nanotubes decorated with Ag nanoparticles in water and experimental investigation of the thermophysical properties. J Phys Chem C. https://doi.org/10.1021/jp210484a
Arani AAA, Pourmoghadam F (2019) Experimental investigation of thermal conductivity behavior of MWCNTS-Al2O3/ethylene glycol hybrid Nanofluid: providing new thermal conductivity correlation. Heat Mass Transf und Stoffuebertragung 55:2329–2339. https://doi.org/10.1007/s00231-019-02572-7
Aravind SSJ, Baskar P, Baby TT et al (2011) Investigation of structural stability, dispersion, viscosity, and conductive heat transfer properties of functionalized carbon nanotube based nanofluids. J Phys Chem C. https://doi.org/10.1021/jp201672p
Ardani HK, Imawan C, Handayani W, et al (2017) Enhancement of the stability of silver nanoparticles synthesized using aqueous extract of Diospyros discolor Willd. leaves using polyvinyl alcohol. In: IOP Conference Series: Materials Science and Engineering
Asadi A (2018) A guideline towards easing the decision-making process in selecting an effective nanofluid as a heat transfer fluid. Energy Convers Manag. https://doi.org/10.1016/j.enconman.2018.08.101
Babar H, Ali HM (2019) Towards hybrid nanofluids: Preparation, thermophysical properties, applications, and challenges. J Mol Liq 70
Babita Sharma SK, Gupta SM (2016) Preparation and evaluation of stable nanofluids for heat transfer application: A review. Exp Therm Fluid Sci 79:202–212
Baghbanzadeh M, Rashidi A, Rashtchian D et al (2012) Synthesis of spherical silica/multiwall carbon nanotubes hybrid nanostructures and investigation of thermal conductivity of related nanofluids. Thermochim Acta 549:87–94. https://doi.org/10.1016/j.tca.2012.09.006
Batmunkh M, Tanshen MR, Nine MJ et al (2014) Thermal conductivity of TiO2 nanoparticles based aqueous nanofluids with an addition of a modified silver particle. Ind Eng Chem Res 53:8445–8451. https://doi.org/10.1021/ie403712f
Bellos E, Tzivanidis C, Antonopoulos KA (2017) A detailed working fluid investigation for solar parabolic trough collectors. Appl Therm Eng 114:374–386. https://doi.org/10.1016/j.applthermaleng.2016.11.201
Bhattacharjee S (2016) DLS and zeta potential—what they are and what they are not? J Control Release
Chamsa-ard W, Brundavanam S, Fung CC et al (2017) Nanofluid types, their synthesis, properties and incorporation in direct solar thermal collectors: A review. Nanomaterials 7:131
Chandrasekar M, Suresh S, Bose AC (2010) Experimental investigations and theoretical determination of thermal conductivity and viscosity of Al 2 O 3 / water nanofluid. Exp Therm Fluid Sci 34:210–216. https://doi.org/10.1016/j.expthermflusci.2009.10.022
Chen L, Xie H (2010) Properties of carbon nanotube nanofluids stabilized by cationic gemini surfactant. Thermochim Acta. https://doi.org/10.1016/j.tca.2010.04.016
Chen L, Yu W, Xie H (2012) Enhanced thermal conductivity of nanofluids containing Ag/MWNT composites. Powder Technol. https://doi.org/10.1016/j.powtec.2012.07.028
Chen LF, Cheng M, Yang DJ, Yang L (2014) Enhanced thermal conductivity of nanofluid by synergistic effect of multi-walled carbon nanotubes and Fe2O3 nanoparticles. In: Applied mechanics and materials
Chen A, Lin TF, Ali HM, Yan WM (2020) Experimental study on bubble characteristics of time periodic subcooled flow boiling in annular ducts due to wall heat flux oscillation. Int J Heat Mass Transf. https://doi.org/10.1016/j.ijheatmasstransfer.2020.119974
Choi C, Yoo HS, Oh JM (2008) Preparation and heat transfer properties of nanoparticle-in-transformer oil dispersions as advanced energy-efficient coolants. Curr Appl Phys 8:710–712. https://doi.org/10.1016/j.cap.2007.04.060
Devarajan M, Krishnamurthy NP, Balasubramanian M et al (2018) Thermophysical properties of CNT and CNT/Al2O3 hybrid nanofluid. Micro Nano Lett. https://doi.org/10.1049/mnl.2017.0029
Dhinesh Kumar D, Valan Arasu A (2018) A comprehensive review of preparation, characterization, properties and stability of hybrid nanofluids. Renew Sustain Energy Rev 81:1669–1689
Farajzadeh E, Movahed S, Hosseini R (2018) Experimental and numerical investigations on the effect of Al2O3/TiO2[sbnd]H2O nanofluids on thermal efficiency of the flat plate solar collector. Renew Energy 118:122–130. https://doi.org/10.1016/j.renene.2017.10.102
Farbod M, Ahangarpour A (2016) Improved thermal conductivity of Ag decorated carbon nanotubes water based nanofluids. Phys Lett Sect A Gen At Solid State Phys. https://doi.org/10.1016/j.physleta.2016.10.014
Fares M, AL-MayyahiAL-Saad MMM (2020) Heat transfer analysis of a shell and tube heat exchanger operated with graphene nanofluids. Case Stud Therm Eng. https://doi.org/10.1016/j.csite.2020.100584
Ghaffarkhah A, Bazzi A, Azimi Dijvejin Z et al (2019) Experimental and numerical analysis of rheological characterization of hybrid nano-lubricants containing COOH-Functionalized MWCNTs and oxide nanoparticles. Int Commun Heat Mass Transf. https://doi.org/10.1016/j.icheatmasstransfer.2019.01.003
Ghaneifar M, Raisi A, Ali HM, Talebizadehsardari P (2020) Mixed convection heat transfer of AL2O3 nanofluid in a horizontal channel subjected with two heat sources. J Therm Anal Calorim. https://doi.org/10.1007/s10973-020-09887-2
Ghozatloo A, Morad A, Shariaty-niasar M (2014) Effects of surface modi fi cation on the dispersion and thermal conductivity of CNT /water nano fluids. 54:1–7. https://doi.org/10.1016/j.icheatmasstransfer.2014.02.013
Gupta N, Gupta SM, Sharma SK (2019) Carbon nanotubes: synthesis, properties and engineering applications. Carbon Lett. https://doi.org/10.1007/s42823-019-00068-2
Gupta N, Mital S, Sharma SK (2020) Materials Today : Proceedings Preparation of stable metal / COOH-MWCNT hybrid nanofluid. Mater Today Proc. https://doi.org/10.1016/j.matpr.2020.04.492
Hamid KA, Azmi WH, Nabil MF, Mamat R (2017) Improved thermal conductivity of TiO2-SiO2 hybrid nanofluid in ethylene glycol and water mixture. In: IOP Conference Series: Materials Science and Engineering
Hemmat Esfe M, Afrand M, Yan WM et al (2016) Effects of temperature and concentration on rheological behavior of MWCNTs/SiO2(20–80)-SAE40 hybrid nano-lubricant. Int Commun Heat Mass Transf 76:133–138. https://doi.org/10.1016/j.icheatmasstransfer.2016.05.015
Hemmat Esfe M, Alirezaie A, Rejvani M (2017) An applicable study on the thermal conductivity of SWCNT-MgO hybrid nanofluid and price-performance analysis for energy management. Appl Therm Eng. https://doi.org/10.1016/j.applthermaleng.2016.09.091
Hsieh SS, Leu HY, Liu HH (2015) Spray cooling characteristics of nanofluids for electronic power devices. Nanoscale Res Lett. https://doi.org/10.1186/s11671-015-0793-7
Jamil F, Ali HM (2020) Applications of hybrid nanofluids in different fields. INC, New Delhi
Jana S, Salehi-Khojin A, Zhong WH (2007) Enhancement of fluid thermal conductivity by the addition of single and hybrid nano-additives. Thermochim Acta. https://doi.org/10.1016/j.tca.2007.06.009
Javadian S, Motaee A, Sharifi M et al (2017) Dispersion stability of multi-walled carbon nanotubes in catanionic surfactant mixtures. Colloids Surfaces A Physicochem Eng Asp. https://doi.org/10.1016/j.colsurfa.2017.07.081
Jha N, Ramaprabhu S (2008) Synthesis and thermal conductivity of copper nanoparticle decorated multiwalled carbon nanotubes based nanofluids. J Phys Chem C. https://doi.org/10.1021/jp8017309
Jha N, Ramaprabhu S (2009) Thermal conductivity studies of metal dispersed multiwalled carbon nanotubes in water and ethylene glycol based nanofluids. J Appl Phys doi 10(1063/1):3240307
Jiang L, Gao L, Sun J (2003) Production of aqueous colloidal dispersions of carbon nanotubes. J Colloid Interface Sci. https://doi.org/10.1016/S0021-9797(02)00176-5
Karami M, Akhavan Bahabadi MA, Delfani S, Ghozatloo A (2014) A new application of carbon nanotubes nanofluid as working fluid of low-temperature direct absorption solar collector. Sol Energy Mater Sol Cells. https://doi.org/10.1016/j.solmat.2013.11.004
Khairul MA, Alim MA, Mahbubul IM et al (2014) Heat transfer performance and exergy analyses of a corrugated plate heat exchanger using metal oxide nanofluids. Int Commun Heat Mass Transf. https://doi.org/10.1016/j.icheatmasstransfer.2013.11.006
Khalid SU, Babar H, Ali HM et al (2020) Heat pipes: progress in thermal performance enhancement for microelectronics. J Therm Anal Calorim. https://doi.org/10.1007/s10973-020-09820-7
Kim P, Shi L, Majumdar A, McEuen PL (2001) Thermal transport measurements of individual multiwalled nanotubes. Phys Rev Lett. https://doi.org/10.1103/PhysRevLett.87.215502
Kim Y, Kwon SM, Kim DY et al (2009) Dispersity and stability measurements of functionalized multiwalled carbon nanotubes in organic solvents. Curr Appl Phys. https://doi.org/10.1016/j.cap.2008.12.039
Lee SW, Park SD, Kang S et al (2011) Investigation of viscosity and thermal conductivity of SiC nanofluids for heat transfer applications. Int J Heat Mass Transf. https://doi.org/10.1016/j.ijheatmasstransfer.2010.09.026
Leong KY, Razali I, Ku Ahmad KZ et al (2018) Thermal conductivity of an ethylene glycol/water-based nanofluid with copper-titanium dioxide nanoparticles: an experimental approach. Int Commun Heat Mass Transf 90:23–28. https://doi.org/10.1016/j.icheatmasstransfer.2017.10.005
Liu QM, Zhou DB, Yamamoto Y et al (2012) Preparation of Cu nanoparticles with NaBH 4 by aqueous reduction method. Trans Nonferrous Met Soc China Eng Ed. https://doi.org/10.1016/S1003-6326(11)61149-7
Madhesh D, Parameshwaran R, Kalaiselvam S (2014) Experimental investigation on convective heat transfer and rheological characteristics of Cu-TiO2 hybrid nanofluids. Exp Therm Fluid Sci. https://doi.org/10.1016/j.expthermflusci.2013.08.026
Manasrah AD, Almanassra IW, Marei NN et al (2018) Surface modification of carbon nanotubes with copper oxide nanoparticles for heat transfer enhancement of nanofluids. RSC Adv. https://doi.org/10.1039/c7ra10406e
Mashali F, Languri E, Mirshekari G et al (2019) Nanodiamond nanofluid microstructural and thermo-electrical characterization. Int Commun Heat Mass Transf. https://doi.org/10.1016/j.icheatmasstransfer.2019.01.007
Menbari A, Alemrajabi AA, Rezaei A (2017) Experimental investigation of thermal performance for direct absorption solar parabolic trough collector (DASPTC) based on binary nanofluids. Exp Therm Fluid Sci. https://doi.org/10.1016/j.expthermflusci.2016.08.023
Missana T, Adell A (2000) On the applicability of DLVO theory to the prediction of clay colloids stability. J Colloid Interface Sci. https://doi.org/10.1006/jcis.2000.7003
Mourdikoudis S, Pallares RM, Thanh NTK (2018) Characterization techniques for nanoparticles: comparison and complementarity upon studying nanoparticle properties. Nanoscale pp 64. https://doi.org/10.1039/C8NR02278J
Mukherjee S (2013) Preparation and Stability of Nanofluids-A Review. IOSR J Mech Civ Eng. https://doi.org/10.9790/1684-0926369
Muneeshwaran M, Sajjad U, Ahmed T et al (2020) Performance improvement of photovoltaic modules via temperature homogeneity improvement. Energy. https://doi.org/10.1016/j.energy.2020.117816
Munkhbayar B, Tanshen MR, Jeoun J et al (2013) Surfactant-free dispersion of silver nanoparticles into MWCNT-aqueous nanofluids prepared by one-step technique and their thermal characteristics. Ceram Int. https://doi.org/10.1016/j.ceramint.2013.01.069
Nimmagadda R, Venkatasubbaiah K (2015) Conjugate heat transfer analysis of micro-channel using novel hybrid nanofluids (Al2O3 + Ag / Water). Eur J Mech B/Fluids 52:19–27. https://doi.org/10.1016/j.euromechflu.2015.01.007
Popa I, Gillies G, Papastavrou G, Borkovec M (2010) Attractive and repulsive electrostatic forces between positively charged latex particles in the presence of anionic linear polyelectrolytes. J Phys Chem B. https://doi.org/10.1021/jp911482a
Qing SH, Rashmi W, Khalid M et al (2017) Thermal conductivity and electrical properties of Hybrid SiO2-graphene naphthenic mineral oil nanofluid as potential transformer oil. Mater Res Express. https://doi.org/10.1088/2053-1591/aa550e
Qiu L, Zou H, Wang X et al (2019) Enhancing the interfacial interaction of carbon nanotubes fibers by Au nanoparticles with improved performance of the electrical and thermal conductivity. Carbon N Y. https://doi.org/10.1016/j.carbon.2018.09.073
Rehman WU, Merican ZMA, Bhat AH et al (2019) Synthesis, characterization, stability and thermal conductivity of multi-walled carbon nanotubes (MWCNTs) and eco-friendly jatropha seed oil based nanofluid: an experimental investigation and modeling approach. J Mol Liq. https://doi.org/10.1016/j.molliq.2019.111534
Reinert L, Zeiger M, Suárez S et al (2015) Dispersion analysis of carbon nanotubes, carbon onions, and nanodiamonds for their application as reinforcement phase in nickel metal matrix composites. RSC Adv. https://doi.org/10.1039/c5ra14310a
Rejvani M, Saedodin S, Vahedi SM et al (2019) Experimental investigation of hybrid nano-lubricant for rheological and thermal engineering applications. J Therm Anal Calorim. https://doi.org/10.1007/s10973-019-08225-5
Riahi A, Khamlich S, Balghouthi M et al (2020) Study of thermal conductivity of synthesized Al2O3-water nanofluid by pulsed laser ablation in liquid. J Mol Liq. https://doi.org/10.1016/j.molliq.2020.112694
Sadri R, Ahmadi G, Togun H et al (2014) An experimental study on thermal conductivity and viscosity of nanofluids containing carbon nanotubes. Nanoscale Res Lett. https://doi.org/10.1186/1556-276X-9-151
Sarkar J, Ghosh P, Adil A (2015) A review on hybrid nanofluids: Recent research, development and applications. Renew Sustain Energy Rev 43:164–177
Selvam C, Mohan Lal D, Harish S (2016) Thermophysical properties of ethylene glycol-water mixture containing silver nanoparticles. J Mech Sci Technol. https://doi.org/10.1007/s12206-016-0231-5
Shah TR, Koten H, Ali HM (2020) Performance effecting parameters of hybrid nanofluids. INC, New Delhi
Shahsavar A, Ali HM, Mahani RB, Talebizadehsardari P (2020) Numerical study of melting and solidification in a wavy double-pipe latent heat thermal energy storage system. J Therm Anal Calorim 141:1785–1799. https://doi.org/10.1007/s10973-020-09864-9
Sharma B, Sharma SK, Gupta SM, Kumar A (2018) Modified two-step method to prepare long-term stable CNT nanofluids for heat transfer applications. Arab J Sci Eng. https://doi.org/10.1007/s13369-018-3345-5
Singh K, Sharma SK, Gupta SM (2020) Preparation of long duration stable CNT nanofluid using SDS. Integr Ferroelectr. https://doi.org/10.1080/10584587.2019.1674981
Sonawane SS, Khedkar RS, Wasewar KL (2015) Effect of sonication time on enhancement of effective thermal conductivity of nano TiO2–water, ethylene glycol, and paraffin oil nanofluids and models comparisons. J Exp Nanosci. https://doi.org/10.1080/17458080.2013.832421
Sriharan G, Harikrishnan S, Ali HM (2020) Experimental investigation on the effectiveness of MHTHS using different metal oxide-based nanofluids. J Therm Anal Calorim. https://doi.org/10.1007/s10973-020-09779-5
Sun B, Zhang Y, Yang D, Li H (2019) Experimental study on heat transfer characteristics of hybrid nanofluid impinging jets. Appl Therm Eng. https://doi.org/10.1016/j.applthermaleng.2019.01.111
Sundar LS, Singh MK, Sousa ACM (2014) Enhanced heat transfer and friction factor of MWCNT-Fe3O4/water hybrid nanofluids. Int Commun Heat Mass Transf. https://doi.org/10.1016/j.icheatmasstransfer.2014.01.012
Suresh S, Venkitaraj KP, Selvakumar P, Chandrasekar M (2011) Synthesis of Al2O3-Cu/water hybrid nanofluids using two step method and its thermo physical properties. Colloids Surfaces A Physicochem Eng Asp. https://doi.org/10.1016/j.colsurfa.2011.08.005
Suresh S, Venkitaraj KP, Selvakumar P, Chandrasekar M (2012) Effect of Al 2O 3-Cu/water hybrid nanofluid in heat transfer. Exp Therm Fluid Sci 38:54–60. https://doi.org/10.1016/j.expthermflusci.2011.11.007
Tariq HA, Anwar M, Malik A, Ali HM (2020) Hydro-thermal performance of normal-channel facile heat sink using TiO2-H2O mixture (Rutile–Anatase) nanofluids for microprocessor cooling. J Therm Anal Calorim. https://doi.org/10.1007/s10973-020-09838-x
Tian R, Wang X, Li M et al (2008) An efficient route to functionalize singe-walled carbon nanotubes using alcohols. Appl Surf Sci. https://doi.org/10.1016/j.apsusc.2008.09.040
Toghraie D, Chaharsoghi VA, Afrand M (2016) Measurement of thermal conductivity of ZnO–TiO2/EG hybrid nanofluid. J Therm Anal Calorim. https://doi.org/10.1007/s10973-016-5436-4
Verma SK, Tiwari AK, Tiwari S, Chauhan DS (2018) Performance analysis of hybrid nanofluids in flat plate solar collector as an advanced working fluid. Sol Energy. https://doi.org/10.1016/j.solener.2018.04.017
Walvekar R, Siddiqui MK, Ong SS, Ismail AF (2016) Application of CNT nanofluids in a turbulent flow heat exchanger. J Exp Nanosci. https://doi.org/10.1080/17458080.2015.1015461
Xie H, Yu W, Li Y, Chen L (2011) Discussion on the thermal conductivity enhancement of nanofluids. Nanosc Res Lett. https://doi.org/10.1186/1556-276X-6-124
Xing M, Yu J, Wang R (2015) Experimental study on the thermal conductivity enhancement of water based nanofluids using different types of carbon nanotubes. Int J Heat Mass Transf. https://doi.org/10.1016/j.ijheatmasstransfer.2015.05.005
Xu Y, Wang X, Tian R et al (2008) Microwave-induced electrophilic addition of single-walled carbon nanotubes with alkylhalides. Appl Surf Sci. https://doi.org/10.1016/j.apsusc.2007.09.081
Xuan Y, Li Q, Hu W (2003) Aggregation structure and thermal conductivity of nanofluids. AIChE J. https://doi.org/10.1002/aic.690490420
Yang K, Yi ZL, Jing QF et al (2013) Sonication-assisted dispersion of carbon nanotubes in aqueous solutions of the anionic surfactant SDBS: The role of sonication energy. Chin Sci Bull. https://doi.org/10.1007/s11434-013-5697-2
Yu W, Xie H (2012) A review on nanofluids: preparation, stability mechanisms, and applications. J Nanomater 2012:17
Zhao M, Lv W, Li Y et al (2018) A study on preparation and stabilizing mechanism of hydrophobic silica nanofluids. Materials (Basel). https://doi.org/10.3390/ma11081385
Zhu H, Zhang C, Liu S et al (2006) Effects of nanoparticle clustering and alignment on thermal conductivities of Fe3O4 aqueous nanofluids. Appl Phys Lett. https://doi.org/10.1063/1.2221905
Zhu D, Li X, Wang N et al (2009) Dispersion behavior and thermal conductivity characteristics of Al2O3-H2O nanofluids. Curr Appl Phys. https://doi.org/10.1016/j.cap.2007.12.008
Acknowledgements
This study is financially supported under FRGS by GGSIP University, New Delhi, India. The authors are thankful to Dr. Surinder Singh faculty of Dr. SSBUICET, Panjab University, Chandigarh, India, for thermal conductivity measurement.
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Gupta, N., Gupta, S.M. & Sharma, S.K. Synthesis, characterization and dispersion stability of water-based Cu–CNT hybrid nanofluid without surfactant. Microfluid Nanofluid 25, 14 (2021). https://doi.org/10.1007/s10404-021-02421-2
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DOI: https://doi.org/10.1007/s10404-021-02421-2