Abstract
The present study has numerically investigated two-dimensional electroosmotic flows in a microchannel with dielectric walls of rectangle-waved surface roughness to understand the roughness effect. For the study, numerical simulations are performed by employing the Nernst–Planck equation for the ionic species and the Poisson equation for the electric potential, together with the traditional Navier–Stokes equation. Results show that the steady electroosmotic flow and ionic-species transport in a microscale channel are well predicted by the Poisson–Nernst–Planck model and depend significantly on the shape of surface roughness such as the amplitude and periodic length of wall wave. It is found that the fluid flows along the surface of waved wall without involving any flow separation because of the very strong normal component of EDL (electric double layer) electric field. The flow rate decreases exponentially with the amplitude of wall wave, whereas it increases linearly with the periodic length. It is mainly due to the fact that the external electric-potential distribution plays a crucial role in driving the electroosmotic flow through a microscale channel with surface roughness. Finally, the present results using the Poisson–Nernst–Planck model are compared with those using the traditional Poisson–Boltzmann model which may be valid in these scales.
Similar content being viewed by others
Abbreviations
- C p , C m :
-
nondimensional concentrations
- C 0 :
-
molar ionic concentration in the bulk region (mol/m3)
- D p , D m , D :
-
ionic diffusion coefficients (m2/s)
- E i :
-
nondimensional total electric field component
- E ϕ,i :
-
nondimensional external electric field component
- E ψ,i :
-
nondimensional EDL electric field component
- E 0 :
-
mean external streamwise electric field (V/m)
- F :
-
Faraday constant (=96,485.338,3 C/mol)
- F e,i :
-
nondimensional total electric force component
- F e,ϕ,i :
-
nondimensional external electric force component
- F e,ψ,i :
-
nondimensional EDL electric force component
- H :
-
channel half-width (m)
- h :
-
nondimensional amplitude of wall wave
- L :
-
nondimensional periodic length of wall wave
- Pe :
-
Peclet number (=U eo H/D)
- p :
-
nondimensional pressure
- Q :
-
nondimensional flow rate
- Q * :
-
real flow rate (m3/s)
- R :
-
gas constant (=8.314 J K−1 mol−1)
- Re :
-
Reynolds number (=U eo H/ν)
- Sc :
-
Schmidt number (=ν/D)
- T :
-
absolute temperature (K)
- t :
-
nondimensional time
- U eo :
-
electroosmotic velocity (=ɛζ0 E 0/ρν, m/s)
- u i :
-
nondimensional velocity components
- x i :
-
nondimensional Cartesian coordinates
- z p , z m , z :
-
ionic valences
- β:
-
nondimensional parameter (=PeΩ)
- Δ:
-
increment
- ɛ:
-
fluid permittivity (C V−1 m−1 )
- ζ0 :
-
reference zeta potential (V)
- ζ *0 :
-
nondimensional reference zeta potential (=−zFζ0/RT)
- κ:
-
nondimensional EDL thickness (=λ/H)
- λ:
-
EDL thickness [=(ɛRT/2F 2 z 2 C 0)1/2, m]
- ν:
-
fluid kinematic viscosity (m2/s)
- ρ:
-
fluid density (kg/m3)
- ρ e :
-
nondimensional volumetric electric-charge density
- σ0 :
-
surface electric-charge density (C/m2)
- Φ:
-
nondimensional total electric potential
- ϕ:
-
nondimensional external electric potential
- ψ:
-
nondimensional EDL electric potential
- Ω:
-
nondimensional parameter (=ζ0/E 0 H)
- i, j :
-
coordinate indices (1,2)
- m :
-
anions
- n :
-
wall-normal direction
- p :
-
cations
- t :
-
wall-tangential direction
References
Fu L-M, Lin J-Y, Yang R-J (2003) Analysis of electroosmotic flow with step change in zeta potential. J Colloid Interface Sci 258:266–275
Hlushkou D, Kandhai D, Tallarek U (2004) Coupled lattice-Boltzmann and finite-difference simulation of electroosmosis in microfluidic channels. Int J Numer Methods Fluids 46:507–532
Hu L, Harrison JD, Masliyah JH (1999) Numerical model of electrokinetic flow for capillary electrophoresis. J Colloid Interface Sci 215:300–312
Hu Y, Werner C, Li D (2003) Electrokinetic transport through rough microchannels. Anal Chem 75:5747–5758
Hu Y, Werner C, Li D (2004) Influence of the three-dimensional heterogeneous roughness on electrokinetic transport in microchannels. J Colloid Interface Sci 280:527–536
Hu Y, Xuan X, Werner C, Li D (2007) Electroosmotic flow in microchannels with prismatic elements. Microfluid Nanofluid 3:151–160
Kang S, Suh YK (2006) Unsteady electroosmotic channel flows with the nonoverlapped and overlapped electric double layers. J Mech Sci Technol 20:2250–2264
Keh HJ, Tseng HC (2001) Transient electrokinetic flow in fine capillaries. J Colloid Interface Sci 242:450–459
Kim D, Darve E (2006) Molecular dynamics simulation of electro-osmotic flows in rough wall nanochannels. Phys Rev E 73:051203
Kwak HS, Hasselbrink EF Jr (2005) Timescales for relaxation to Boltzmann equilibrium in nanopores. J Colloid Interface Sci 284:753–758
Li D (2004) Electrokinetics in microfluidics. Elsevier, London
Lin JY, Fu LM, Yang RJ (2002) Numerical simulation of electrokinetic focusing in microfluidic chips. J Micromech Microeng 12:955–961
Lin H, Storey BD, Oddy MH, Chen C-H, Santiago JG (2004) Instability of electrokinetic microchannel flows with conductivity gradients. Phys Fluids 16:1922–1935
Park HM, Lee JS, Kim TW (2007) Comparison of the Nernst–Planck model and the Poisson–Boltzmann model for electroosmotic flows in microchannels. J Colloid Interface Sci 315:731–739
Patankar NA, Hu HH (1998) Numerical simulation of electroosmotic flow. Anal Chem 70:1870–1881
Qian S, Bau HH (2005) Theoretical investigation of electro-osmotic flows and chaotic stirring in rectangular cavities. Appl Math Model 29:726–753
Qiao R (2007) Effects of molecular level surface roughness on electroosmotic flow. Microfluid Nanofluid 3:33–38
Qu W, Li D (2000) A model for overlapped EDL fields. J Colloid Interface Sci 224:397–407
Wang M, Chen S (2007) Electroosmosis in homogeneously charged micro- and nanoscale random porous media. J Colloid Interface Sci 314:264–273
Wang M, Wang J, Chen S (2007) Roughness and cavitations effects on electro-osmotic flows in rough microchannels using the lattice Poisson–Boltzmann methods. J Comput Phys 226:836–851
Wang M, Wang J, Chen S (2008) On applicability of Poisson–Boltzmann equation for micro- and nanoscale electroosmotic flows. Commun Comput Phys 3:1087–1099
Yang R-J, Fu L-M, Hwang C-C (2001a) Electroosmotic entry flow in a microchannel. J Colloid Interface Sci 244:173–179
Yang R-J, Fu L-M, Lin Y-C (2001b) Electroosmotic flow in microchannels. J Colloid Interface Sci 239:98–105
Acknowledgments
This work has been supported by the NRL (National Research Laboratory) Program of the Ministry of Education, Science and Technology, Korea.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kang, S., Suh, Y.K. Numerical analysis on electroosmotic flows in a microchannel with rectangle-waved surface roughness using the Poisson–Nernst–Planck model. Microfluid Nanofluid 6, 461–477 (2009). https://doi.org/10.1007/s10404-008-0321-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10404-008-0321-5