Skip to main content
SpringerLink
Log in

A New Method for the Determination of Phosphorus and Iodine in Phosphate Rock by Ion Chromatography After Continuous Acid Digestion and Distillation

  • Original
  • Published:
Chromatographia Aims and scope Submit manuscript

Abstract

A new method was developed for the determination of phosphorus (P) and iodine (I) in phosphate rock. First, the phosphate rock was digested with HCl solution to generate H3PO4, then the remaining HCl was evaporated by distillation, the generated H3PO4 reacted with NaAc to generate HAc, and HAc was evaporated by distillation finally. The processes were conducted continuously in the same apparatus; the escaping gases including HI, I2, HCl and HAc were absorbed by a diluted solution of NaOH and Na2SO3. Cl−, Ac− and I− in the absorption solution were determined by ion chromatography (IC) and the content of P in phosphate rock was confirmed according to the Ac− determination. The results showed that the optimal operating parameters were, respectively, 4.0 mol L−1 HCl, 50 ℃ and 35 min for the acid digestion of phosphate rock, 160 ℃ and 40 min for HCl evaporation, and 140 ℃ and 40 min for H3PO4 reaction and HAc evaporation (HRHE). The correlation coefficients of P and I in this method were good (R2 > 0.999), the relative standard deviations (RSDs) of the measured values and the recoveries of P and I ranged from 1.28 to 7.21% and from 91.90 to 98.62%, respectively; the measured values of P and I were in good agreement with the certified reference values (CRVs) of the certified reference materials (CRMs). This method exhibits suitable accuracy and precision, with simple and mild operating conditions and is good for determining P and I in phosphate rock.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Zhou F, Yang L, Zhang L, Cao J, Zhang H (2019) Hydrometallurgy 188:174–181

    Article  CAS  Google Scholar 

  2. Peng B, Li X, Qi Y (2021) Environ Pollut 270:116321

    Article  CAS  Google Scholar 

  3. Zhang H, Lei X (2011) Phosph Com Fert 26:76–78 (in Chinese)

    CAS  Google Scholar 

  4. Wang H, Zuang M, Li X, Qin L, Jiang Y, Feng Y (2020) Metall Anal 40(11):32–37 (in Chinese)

    Google Scholar 

  5. Chao J, Chuang C, Chou W, Kuo C, Chang F, Chiang A (2021) Appl Radia Isotopes 176:109762

    Article  CAS  Google Scholar 

  6. Vivekchandra GM, Uday KT, Dipti JS, Neeraj KG, Subbiah J, Bhupendra ST, Karanam LR (2015) Anal Chem 87:10728–10733

    Article  Google Scholar 

  7. Fletcher ND, Manard BT, Bostick DA, Bostick WD, Hexel CR (2021) Talanta 221:121573

    Article  CAS  Google Scholar 

  8. Fuentes-Soriano P, Bellido-Milla D, García-Guzmán JJ, Hernández-Artiga MP, Espada-Bellido E (2019) Talanta 204:57–62

    Article  CAS  Google Scholar 

  9. Diogo LR, Novo RMP, Vanize CC, Carla AH, Marcia FM (2018) Food Chem 246:422–427

    Article  Google Scholar 

  10. Wu D, Deng H, Wang W, Xiao H (2007) Anal Chim Acta 601(2):183–188

    Article  CAS  Google Scholar 

  11. Sun M, Gao Y, Gao YW, Wu X (2010) Talanta 81(1–2):473–476

    Article  CAS  Google Scholar 

  12. Márcia FM, Paola AM, Cezar AB, Valderi LD, Guenter K, Érico MMF (2010) Anal Bioanal Chem 398:1125–1131

    Article  Google Scholar 

  13. Lehner AF, Zyskowski J, Johnson M, Buchweitz JP (2021) Anim Feed Sci Tech 272:114781

    Article  CAS  Google Scholar 

  14. Gong Z, Yang R, Sun C, Han W, Jiang X, Xu S, Wang Y (2019) Int J Mass Spectrom 445:116193

    Article  CAS  Google Scholar 

  15. Muhammad N, Zhang Y, Muhammad A, Muhammad FSK, Intisar A, Ye M, Subhani Q, Cui H, Zhu Y (2020) Microchem J 159:105593

    Article  CAS  Google Scholar 

  16. Muhammad N, Zhang Y, Subhani Q, Intisar A, Ye M, Cui H, Zhu Y (2020) Microchem J 158:105176

    Article  CAS  Google Scholar 

  17. Lou C, Guo D, Wang N, Wu S, Zhang P, Zhu Y (2017) J Chromatogra A 1500:145–152

    Article  CAS  Google Scholar 

  18. Xu S, Wang L, Wang Y, Liu C (2020) Geol Chem Miner 42(3):106–110 (in Chinese)

    Google Scholar 

  19. Sınırkaya MA, Özer AK, Gülaboglu MS (2011) Powder Technol 211:72–76

    Article  Google Scholar 

  20. He S, Chen Q, Ao X, Li C, Yu M, Zuo Y (2020) Hydrometallurgy 191:105208

    Article  CAS  Google Scholar 

  21. Wang Z, Wei C (2019) Indus Miner Process 10:50–55 (in Chinese)

    Google Scholar 

  22. Abdelouahed HB, Pant HJ, Thereska J, Abbes NE, Reguigui N (2018) Appl Radiat Isotopes 142:143–150

    Article  Google Scholar 

  23. Zheng D, Tang S, Lü L (2021) Inorg Chem Indus 2(53):81–84 (in Chinese)

    Google Scholar 

  24. Rochele SP, Michele SPE, Morgana D, Gabrielle DI, Fabio AD, Juliano SB, Francisco JK, Erico MMF (2019) Talanta 194:314–319

    Article  Google Scholar 

Download references

Acknowledgements

This work was sponsored by the National Natural Science Foundation of China (Grant no. 21966014) and the Postgraduate Innovation Fund project of Jiangxi Provincial Department of Education (YC2021-S301).

Author information

Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang, 330022, China

    Bingxian Peng, Zhen Ma, Yongbo Zhu, Baogen Bao & Wenjie Chen

Authors
  1. Bingxian Peng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhen Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yongbo Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Baogen Bao
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Wenjie Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Bingxian Peng.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Peng, B., Ma, Z., Zhu, Y. et al. A New Method for the Determination of Phosphorus and Iodine in Phosphate Rock by Ion Chromatography After Continuous Acid Digestion and Distillation. Chromatographia 85, 969–976 (2022). https://doi.org/10.1007/s10337-022-04197-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10337-022-04197-1

Keywords

Search

Navigation