Skip to main content
SpringerLink
Log in

Investigation of the Separation Efficiency of Tube Radial Distribution Chromatography with Stationary Outer Phase Using the van Deemter Equation

  • Short Communication
  • Published:
Chromatographia Aims and scope Submit manuscript

Abstract

The outer phase in tube radial distribution chromatography (TRDC) operated as a stationary phase in chromatographic separation. Chromatographic peak information from model analytes 1-naphthol, 1-naphthalenesulfonic acid, 2,6-naphthalenedisulfonic acid, and 1,3,6-naphthalenetrisulfonic acid was examined using TRDC at various flow rates, using a fused-silica capillary tube (inner diameter, 75 μm; length, 120 cm; effective length, 100 cm) as the separation column and water/acetonitrile/ethyl acetate (3:8:4, v/v/v) as eluent. From the data, the relationships between average linear velocities and values of height equivalent to one theoretical plate of the analytes were investigated, and the separation efficiency by TRDC, comprising an inner phase (mobile phase) and outer phase (stationary phase) in an open-tubular capillary tube, was examined using the van Deemter equation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

References

  1. Rocco A, Donati E, Touloupakis E, Aturki Z (2018) TrAC, Trends in Anal. Chem. 103:156–183

    CAS  Google Scholar 

  2. Cui X, Xu S, Jin C, Ji Y (2018) Anal Chim Acta 1033:35–48

    Article  CAS  Google Scholar 

  3. Tarongoy FM Jr, Haddad PR, Quirino JP (2018) Electrophoresis 39:34–52

    Article  CAS  Google Scholar 

  4. Ahmed MA, Felisilda BMB, Quirino JP (2019) Anal Chim Acta 1088:2014–2018

    Article  Google Scholar 

  5. Lam SC, Sanz Rodriguez E, Haddad PR, Paull B (2019) Analyst 144:3464–3482

    Article  CAS  Google Scholar 

  6. Harada M, Kido T, Masudo T, Okada T (2005) Anal Sci 21:491–496

    Article  CAS  Google Scholar 

  7. Adrover A, Cerbelli S, Garofalo F, Giona M (2009) Anal Chem 81:8009–8014

    Article  CAS  Google Scholar 

  8. El Deeb S, Dawwas HA, Gust R (2013) Electrophoresis 34:1295–1303

    Article  Google Scholar 

  9. Krizek T, Kubickova A (2012) Anal Bioanal Chem 403:2185–2195

    Article  CAS  Google Scholar 

  10. Quirino JP, Tarongoy FM (2018) Green Chem 20:2486–2493

    Article  CAS  Google Scholar 

  11. Xiang P, Yang Y, Zhao Z, Chen M, Liu S (2019) Anal Chem 91:10738–10743

    Article  CAS  Google Scholar 

  12. Jinno N, Murakami M, Mizohata K, Hashimoto M, Tsukagoshi K (2011) Analyst 136:927–932

    Article  CAS  Google Scholar 

  13. Tsukagoshi K (2014) Anal Sci 30:65–73 (and references cited therein)

    Article  CAS  Google Scholar 

  14. Tsukagoshi K (2015) J Flow Inj Anal 32:89–95 (and references cited therein)

    CAS  Google Scholar 

  15. Yamada K, Kan H, Tsukagoshi K (2018) Talanta 183:89–93

    Article  CAS  Google Scholar 

  16. Kan H, Yamada K, Sanada N, Tsukagoshi K (2018) Anal Sci 34:239–241

    Article  CAS  Google Scholar 

  17. Gusev I, Huang X, Horvath C (1999) J Chromatogr A 855:273–290

    Article  CAS  Google Scholar 

  18. Cintron JM, Colon LA (2006) J Chromatogr A 1106:131–138

    Article  CAS  Google Scholar 

  19. Palonen S, Jussila M, Porras SP, Hyotylainen T, Riekkola ML (2001) J Chromatogr A 916:89–99

    Article  CAS  Google Scholar 

  20. Jinno N, Murakami M, Mizohata K, Hashimoto M, Tsukagoshi K (2012) J Liq Chromatogr Relat Technol 35:1750–1766

    Article  CAS  Google Scholar 

  21. Jinno N, Murakami M, Hashimoto M, Tsukagoshi K (2010) Anal Sci 26:737–742

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by a Grant-in-Aid for Scientific Research (B) from the Ministry of Education, Culture, Sports, Science, and Technology, Japan (MEXT, No. 17H03083).

Funding

This study was partially funded by a Grant-in-Aid for Scientific Research (B) from the Ministry of Education, Culture, Sports, Science, and Technology, Japan (grant number MEXT, No. 17H03083).

Author information

Authors and Affiliations

  1. Applied Chemistry, Graduate School of Science and Engineering, Doshisha University, Kyotanabe, Kyoto, 610-0321, Japan

    Chihiro Matsushita, Kazuhiko Tsukagoshi & Katsumi Tsuchiya

  2. Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 807-1 Shuku-machi, Tosu, Saga, 841-0052, Japan

    Kenichi Yamashita

  3. Department of Advanced Medical Initiatives, Faculty of Medical Sciences, Kyushu University, 3-1-1 Maidashi, Higashi-ku, Fukuoka, 812-8582, Japan

    Masaharu Murata

Authors
  1. Chihiro Matsushita
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kazuhiko Tsukagoshi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Katsumi Tsuchiya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kenichi Yamashita
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Masaharu Murata
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Kazuhiko Tsukagoshi.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Ethical approval

This article does not contain any studies with human participants or animals performed by any of the authors.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Matsushita, C., Tsukagoshi, K., Tsuchiya, K. et al. Investigation of the Separation Efficiency of Tube Radial Distribution Chromatography with Stationary Outer Phase Using the van Deemter Equation. Chromatographia 83, 287–292 (2020). https://doi.org/10.1007/s10337-019-03837-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10337-019-03837-3

Keywords

Search

Navigation