Skip to main content
SpringerLink
Log in

Barium Sulfate Nanoparticles as a Coating for Solid-Phase Microextraction of Polycyclic Aromatic Hydrocarbons in Aqueous Samples

  • Original
  • Published:
Chromatographia Aims and scope Submit manuscript

Abstract

Owing to the high toxicity of polycyclic aromatic hydrocarbons (PAHs) and their low content in the environment, the development of efficient analysis methods is very important. In this work, an extraction tube was developed through filling barium sulfate nanoparticle-coated basalt fibers (BFs) in a poly(ether ether ketone) (PEEK) tube. According to the characterization result by scanning electron microscopy, BFs were evenly covered with barium sulfate nanoparticles, and their diameter was about 11 µm. To sensitively determine PAHs, the extraction tube was connected to a high-performance liquid chromatography instrument with diode array detector for an online enrichment and detection method. By optimizing sampling volume, sampling rate, the content of methanol in sample and desorption time, the analysis method provided a wide linear range (0.30–20 µg L− 1) and high enrichment ratio (71–2095), and was useful for the efficient detection of PAHs in environmental aqueous samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Wenzl T, Simon R, Anklam E, Kleiner J (2006) Analytical methods for polycyclic aromatic hydrocarbons (PAHs) in food and the environment needed for new food legislation in the European Union. TrAC-Trend Anal Chem 25:716–725

    Article  CAS  Google Scholar 

  2. Cappelinia LT, Cordeiroa D, Brondib SH, Prieto KR, Vieira EM (2012) Development of methodology for determination of pesticides residue in water by SPE/HPLC/DAD. Environ Technol 33:2299–2304

    Article  CAS  Google Scholar 

  3. Portugal FCM, Pinto ML, Nogueira JMF (2008) Optimization of polyurethane foams for enhanced stir bar sorptive extraction of triazinic herbicides in water matrices. Talanta 77:765–773

    Article  CAS  Google Scholar 

  4. Lasartearagones G, Lucena R, Cardenas S, Valcarcel M (2015) Use of switchable hydrophilicity solvents for the homogeneous liquid-liquid microextraction of triazine herbicides from environmental water samples. J Sep Sci 38:990–995

    Article  CAS  Google Scholar 

  5. Hussain I, Ismail RA, Sanagi MM, Wan AWI (2014) Sol-gel coated poly-propylene hollow fiber-based liquid-phase microextraction of triazine herbicides in real water samples. Desalin Water Treat 55:1488–1500

    Article  CAS  Google Scholar 

  6. Kataoka H, Narimatsu S, Lord HL, Pawliszyn J (1999) Automated in-tube solid-phase micro extraction coupled with liquid chromatography electrospray ionization mass spectrometry for the determination of beta-blockers and metabolites in urine and serum samples. Anal Chem 71:4237–4244

    Article  CAS  PubMed  Google Scholar 

  7. Kumazawa T, Saeki K, Yanagisawa I, Uchigasaki S, Hasegawa C, Seno H, Suzuki O, Sato K (2009) Automated on-line in-tube solid-phase microextraction coupled with HPLC/MS/MS for the determination of butyrophenone derivatives in human plasma. Anal Bioanal Chem 394:1161–1170

    Article  CAS  PubMed  Google Scholar 

  8. Eisert R, Pawliszyn J (1997) Automated in-tube solid phase microextraction coupled to high performance liquid chromatography. Anal Chem 69:3140–3147

    Article  CAS  Google Scholar 

  9. Gonzalez-Toledo E, Prat MD, Alpendurada MF (2001) Solid-phase microextraction coupled to liquid chromatography for the analysis of phenolic compounds in water. J Chromatogr A 923:45–52

    Article  CAS  PubMed  Google Scholar 

  10. Liompart M, Lik FM (1999) Head space solid phase microextraction (HSSPME) for the determination of volatile and semivolatile pollutants in solis. Talanta 48:451–459

    Article  Google Scholar 

  11. Jia M, Zhang QH, Min DB (1999) Pulsed electric field processing effects on flavor compounds and microorganisms of orange juice. Food Chem 65:445–451

    Article  CAS  Google Scholar 

  12. Lee M-R, Song Y-S, Hwang B-H, Chou C-C (2000) Determination of amphetamine and methamphetamine in serum via headspace derivatization solid-phase microextraction-gas chromatography-mass spectrometry. J Chromatogr A 896:265–273

    Article  CAS  PubMed  Google Scholar 

  13. Feng J, Tian Y, Wang X, Luo C, Sun M (2018) Basalt fibers functionalized with gold nanoparticles for in-tube solid-phase microextraction. J Sep Sci 41:1149–1155

    Article  CAS  PubMed  Google Scholar 

  14. She X-K, Wang X, Zhou J-B, Zhao R-S (2015) Porous lead(II)-based metal organic nanotubes as an adsorbent for dispersive solid-phase extraction of polybrominated diphenyl ethers from environmental water samples. J Chromatogr A 1423:31–38

    Article  CAS  PubMed  Google Scholar 

  15. Wen C, Li M, Li W, Li Z, Duan W, Li Y, Zhou J, Li X, Zeng J (2017) Graphene deposited onto aligned zinc oxide nanorods as an efficient coating for headspace solid-phase microextraction of gasoline fractions from oil samples. J Chromatogr A 1530:45–50

    Article  CAS  PubMed  Google Scholar 

  16. Xu J, Zheng J, Tian J, Zhu F, Zeng F, Su C, Ouyang G (2013) New materials in solid phase microextraction. Trends Anal Chem 47:68–83

    Article  CAS  Google Scholar 

  17. Aziz-Zanjani MO, Mehdinia A (2014) A review on procedures for the preparation of coatings for solid phase microextraction. Microchim Acta 181:1169–1190

    Article  CAS  Google Scholar 

  18. Wang L, Hou X, Li J, Liu S, Guo Y (2015) Graphene oxide decorated with silver nanoparticles as a coating on a stainless-steel fiber for solid-phase microextraction. J Sep Sci 38:2439–2446

    Article  CAS  PubMed  Google Scholar 

Download references

Acknowledgements

This research work was financially supported by the National Natural Science Foundation of China (NSFC, Nos. 21777054 and 21405061) and the Shandong Provincial Natural Science Foundation of China (No. ZR2017MB043).

Author information

Authors and Affiliations

  1. Key Laboratory of Interfacial Reaction and Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022, People’s Republic of China

    Jiaqing Feng, Min Sun, Xiuqin Wang, Yu Tian, Chuannan Luo & Juanjuan Feng

Authors
  1. Jiaqing Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Min Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Xiuqin Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu Tian
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Chuannan Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Juanjuan Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Juanjuan Feng.

Ethics declarations

Conflict of Interest

The author declares that he has no conflict of interest.

Ethical approval

This article does not contain any studies with human participants or animals performed by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Feng, J., Sun, M., Wang, X. et al. Barium Sulfate Nanoparticles as a Coating for Solid-Phase Microextraction of Polycyclic Aromatic Hydrocarbons in Aqueous Samples. Chromatographia 81, 1287–1292 (2018). https://doi.org/10.1007/s10337-018-3568-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10337-018-3568-3

Keywords

Search

Navigation