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Simultaneous Determination of Deltamethrin and Permethrin in Water Samples Using Homogeneous Liquid–Liquid Microextraction via Flotation Assistance and GC-FID

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Abstract

A new method was developed for the simultaneous determination of deltamethrin and permethrin in water samples with homogeneous liquid–liquid microextraction via flotation assistance and gas chromatography–flame ionization detection. A special extraction cell was designed to facilitate collection of the low density solvent extracts. The sample solution was added into the extraction cell, which contained an appropriate mixture of n-hexane (as an extraction solvent) and acetone (as a homogeneous solvent). Air flotation allowed the extraction solvent to be collected from the top of the solution. Under the optimum conditions, good linearity was observed in the range of 1.0–200 μg L−1 with a correlation coefficient (r 2) greater than 0.9980 for both of the analytes. The limits of detection were 0.2 and 0.3 μg L−1 for deltamethrin and permethrin, respectively (S/N = 3). The developed method was successfully applied to determine the two pesticides in three different water samples.

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Acknowledgments

This work was supported by Shahrekord University through a research fund. The authors were also partially supported by the Center of Excellence for Mathematics, Shahrekord University.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Shahrekord University, P.O. Box 115, Shahrekord, Iran

    Hedayat Haddadi, Mahboube Shirani & Abolfazl Semnani

  2. Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, Atomic Energy Organization of Iran, P.O. Box 14395-836, Tehran, Iran

    Mohammad Rezaee

  3. Department of Chemistry, Tonekabon Branch, Islamic Azad University, Tonekabon, Iran

    Hossein Ali Mashayekhi

  4. Department of Engineering Science, College of Engineering, University of Tehran, P.O. Box 11365-4563, Tehran, Iran

    Akram Hosseinian

Authors
  1. Hedayat Haddadi
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  2. Mahboube Shirani
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  3. Abolfazl Semnani
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  4. Mohammad Rezaee
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  5. Hossein Ali Mashayekhi
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  6. Akram Hosseinian
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Correspondence to Hedayat Haddadi.

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Haddadi, H., Shirani, M., Semnani, A. et al. Simultaneous Determination of Deltamethrin and Permethrin in Water Samples Using Homogeneous Liquid–Liquid Microextraction via Flotation Assistance and GC-FID. Chromatographia 77, 715–721 (2014). https://doi.org/10.1007/s10337-014-2666-0

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  • DOI: https://doi.org/10.1007/s10337-014-2666-0

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