Skip to main content
SpringerLink
Log in

Characterization of Calixarene/Ionic Liquid Mixture as Gas Chromatographic Stationary Phase through Thermodynamic Parameters and LSER

  • Original
  • Published:
Chromatographia Aims and scope Submit manuscript

Abstract

A mixture of 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetraethoxycarbonylmethyloxy calix[4]arene (C[4]TECM) and 1-octyl-3-methylimidazolium tetrafluoroborate ionic liquid (OmI +m BF4 −) has been employed as stationary phases in capillary gas chromatography. Its properties have been characterized through thermodynamic parameters and linear solvation energy relationship. The experimental results showed that C[4]TECM–OmI +m BF4 − mixture as gas chromatographic stationary phase has high column efficiency and peak symmetry, which were evaluated using naphthalene and n-octanol, respectively. It was demonstrated that the interaction forces between the probe molecules and the stationary phase did not change over the entire temperature range studied due to an excellent linear relationship between lnk and 1/T, the retentions of the probe molecules on the C[4]TECM–OmI +m BF4 − stationary phase are enthalpy-driven processes, and the interactions of the probe molecules with C[4]TECM–OmI +m BF4 − stationary phase mainly include hydrogen bonding interaction, dipole–dipole interaction and dispersive interaction. However, the contribution of each interaction is in the order of A > L > S for the C[4]TECM–OmI +m BF4 − stationary phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Mokhtari B, Pourabdollah K, Dalali N (2011) Chromatographia 73:829–847. doi:10.1007/s10337-011-1954-1

    Article  CAS  Google Scholar 

  2. Li H, Zhang Y, Wang X, Xiong D, Bai Y (2007) Mater Lett 61:1474–1477. doi:10.1016/j.matlet.2006.07.064

    Article  CAS  Google Scholar 

  3. Mokhtari B, Pourabdollah K, Dalali N (2011) J Incl Phenom Macrocycl Chem 69:1–55. doi:10.1007/s10847-010-9848-7

    Article  CAS  Google Scholar 

  4. Ludwig R (2005) Microchim Acta 152:1–19. doi:10.1007/s00604-005-0422-8

    Article  CAS  Google Scholar 

  5. Mangia A, Pochini A, Ungaro Ŕ, Andreetti GD (1983) Anal Lett 16:1027–1036. doi:10.1080/00032718308067960

    Article  CAS  Google Scholar 

  6. Mňuk P, Feltl L, Schurig V (1996) J Chromatogr A 732:63–74. doi:10.1016/0021-9673(95)01142-0

    Article  Google Scholar 

  7. Lin L, Wu CY, Yan ZQ, Yan XQ, Su XL, Han HM (1998) Chromatographia 47:689–694. doi:10.1007/BF02467455

    Article  CAS  Google Scholar 

  8. Yu XD, Fang H, Lin L, Han HM, Wu CY (2001) Chromatographia 53:519–523. doi:10.1007/BF02491615

    Article  CAS  Google Scholar 

  9. Lai XH, Lin L, Wu CY (1999) Chromatographia 50:82–88. doi:10.1007/BF02493622

    Article  CAS  Google Scholar 

  10. Pfeiffer J, Schurig V (1999) J Chromatogr A 840:145–150. doi:10.1016/S0021-9673(99)00224-1

    Article  CAS  Google Scholar 

  11. Zeng ZR, Guan N, Tang XH, Lu XR (2000) Analyst 125:843–848. doi:10.1039/a909625f

    Article  CAS  Google Scholar 

  12. Zhang HB, Dai RJ, Ling Y, Wen YX, Zhang S, Fu RN, Gu JL (1997) J Chromatogr A 787:161–169. doi:10.1016/S0021-9673(97)00613-4

    Article  CAS  Google Scholar 

  13. Lim HJ, Lee HS, Kim IW, Park JH (1998) Chromatographia 48:422–426. doi:10.1007/BF02467714

    Article  CAS  Google Scholar 

  14. Suh JK, Kim IW, Chang SH et al (2001) Bull Korean Chem Soc 22(4):409–412

    CAS  Google Scholar 

  15. Baker GA, Baker SN, Pandey S, Bright FV (2005) Analyst 130:800–808. doi:10.1039/b500865b

    Article  CAS  Google Scholar 

  16. Welton T (1999) Chem Rev 99:2071–2083. doi:10.1021/cr980032t

    Article  CAS  Google Scholar 

  17. Sun P, Armsrong DW (2010) Anal Chim Acta 661:1–16. doi:10.1016/j.aca.2009.12.007

    Article  CAS  Google Scholar 

  18. Buszewski B, Studzińska S (2008) Chromatographia 68:1–10. doi:10.1365/s10337-008-0662-y

    Article  CAS  Google Scholar 

  19. Huang K, Zhang XT, Armstrong DW (2010) J Chromatogr A 1217:5261–5273. doi:10.1016/j.chroma.2010.06.025

    Article  CAS  Google Scholar 

  20. Qiu HD, Takafuji M, Liu X, Jiang SX, Ihara H (2010) J Chromatogr A 1217:5190–5196. doi:10.1016/j.chroma.2010.06.013

    Article  CAS  Google Scholar 

  21. Breitbach ZS, Armstrong DW (2008) Anal Biomanal Chem 390:1605–1617. doi:10.1007/s00216-008-1877-3

    Article  CAS  Google Scholar 

  22. Baltazar QQ, Leininger SK, Anderson JL (2007) J Chromatogr A 1182:119–127. doi:10.1016/j.chroma.2007.12.075

    Google Scholar 

  23. Arnaud-Neu F, Collins EM, Deasy M, Ferguson G et al (1989) J Am Chem Soc 111:8681–8691. doi:10.1021/ja00205a018

    Article  CAS  Google Scholar 

  24. Knoblauch S, Falana OM, Nam J, Roundhill DM et al (2000) Inorg Chim Acta 300:328–332. doi:10.1016/S0020-1693(99)00577-0

    Article  Google Scholar 

  25. Shi JH, Ding ZJ, Hu Y (2011) Chromatographia 74:319–325. doi:10.1007/s10337-011-2069-4

    Article  CAS  Google Scholar 

  26. Li JJ, Carr PW (1994) J Chromatogr A 670:105–116. doi:10.1016/0021-9673(94)80285-8

    Article  CAS  Google Scholar 

  27. Shi JH, Jin D, Xiao KK (2009) Chin J Anal Chem 37:30–34

    CAS  Google Scholar 

  28. Abraham MH (1993) Chem Soc Rev 22:73–83. doi:10.1039/CS9932200073

    Article  CAS  Google Scholar 

  29. Poole CF, Atapattu SN, Poole SK, Bell AK (2009) Anal Chim Acta 652:32–53. doi:10.1016/j.aca.2009.04.038

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou, 310032, China

    Jie-hua Shi, Qian-qian Jia & Shui-xing Xu

  2. State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou, 310032, China

    Jie-hua Shi

Authors
  1. Jie-hua Shi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Qian-qian Jia
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Shui-xing Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jie-hua Shi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shi, Jh., Jia, Qq. & Xu, Sx. Characterization of Calixarene/Ionic Liquid Mixture as Gas Chromatographic Stationary Phase through Thermodynamic Parameters and LSER. Chromatographia 75, 779–787 (2012). https://doi.org/10.1007/s10337-012-2256-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10337-012-2256-y

Keywords

Search

Navigation