Abstract
Three methods were developed for analysis of benzene, toluene, p-xylene, m-xylene and o-xylene (BTX) in a solid-liquid mixing paint. These methods were based on solid phase extraction-thermal desorption-gas chromatography with a flame ionization detector (SPE-TD-GC-FID), ultra performance liquid chromatography-photodiode array detector (UPLC-PDA) and gas chromatography-mass spectrometry (GC-MS). At their optimum conditions of operation, the developed methods were compared in terms of recovery, sensitivity, selectivity and universality. Although the time required for GC-MS analysis was shorter than for GC-FID and UPLC-PDA, it offered relatively poorer recoveries and suffered from matrix interferences. All of the mentioned methods were proven to be ideal for the analysis of targeted analytes; SPE-TD-GC-FID was particularly fit for the determination of trace level BTX residues present in the complex matrix. As one of the sample pretreatment techniques, the novel SPE also showed some selectivity towards BTX and was found to be superior to the conventional SPE.
References
Mangani F, Lattanzi L, Rezai MA, Cecchetti G (2000) Chromatographia 52:217–220
Florez Menéndez JC, Fernández Sánchez ML, Sánchez Urıa JE, Fernández Martınez EF, Sanz-Medel A (2000) Anal Chim Acta 415:9–20
Zhang S, Zhao TB, Xu X, Wang HW, Miao C (2010) Chromatographia 71:1131–1135
Pandey SK, Kim KH (2007) J Chromatogr A 1216:5436–5444
Kim KH, Pal R (2010) Environ Monit Assess 161:295–299
Campos-Candel A, Llobat-Estellés M, Mauri-Aucejo A (2009) Talanta 78:1286–1292
Djozan D, Assadi Y (1997) Chromatographia 45:183–189
Mangani G, Berloni A, Maione M (2003) Chromatographia 58:115–117
Prikryl P, Kubinec R, Jurdáková H, Sevcík J, Ostrovsky I, Sliák L, Berezkin V (2006) Chromatographia 64:65–70
Wang ST, Wang Y, You H, Yao J (2006) Chromatographia 63:365–371
Sarafraz-Yazdi A, Amiri AH, Es’haghi Z (2008) Chemosphere 71:671–676
Sarafraz-Yazdi A, Amiri AH, Es’haghi Z (2009) Talanta 78:936–941
Sieg K, Fries E, Püttmann W (2008) J Chromatogr A 1178:178–186
Godoi AFL, Sawada EY, Marchi MRR, Grieken RV, Godoi RHM (2009) Water Air Soil Pollut Focus 9:163–169
Waters Corporation (2004) Ultra performance LC by design. Waters Corporation USA, 720000880EN:LL. &LW-UL
Wu T, Wang C, Wang X, Xiao HQ, Ma Q, Zhang Q (2008) Chromatographia 68:803–806
Güvenc A, Satir E, Coskum M (2007) Chromatographia 68:S141–S145
Li X, Xiong Z, Ying X, Cui L, Zhu W, Li F (2006) Anal Chem Acta 580:170–180
Guan J, Lai CM, Li SP (2007) J Pharm Biomed Anal 44:996–1000
Qin LX, Chao J, Wei Y, Yum L, Li YM, Gang CX (2008) Chromatographia 68:57–63
Rivasseau C, Caude M (1995) Chromatographia 41:462–470
Magdic S, Pawliszyn J (1996) J Chromatogr A 723:111–122
Dettmer K, Engewald W (2002) Anal Bioanal Chem 373:490–500
Yang KL, Lo JG (1997) Chromatographia 44:405–410
Sakodynskii K, Panina L, Klinskaya N (1974) Chromatographia 7:339–344
Agelopoulos NY, Pickett JA (1998) J Chemical Ecology 24:1161–1172
Briand O, Millet M, Bertrand F, Clément M, Seux R (2002) Anal Bioanal Chem 374:848–857
Zhao DY, Pignatello JJ (2004) Environ Toxicol Chem 23:1592–1599
Liu JF, Li N, Jiang GB, Liu JM, Jonsson JA, Wen MJ (2005) J Chromatogr A 1066:27–32
Carrion CC, Lucena R, Cárdenas S, Valcárcel M (2007) J Chromatogr A 1171:1–7
Acknowledgments
The authors would like to thank the China 111 project no. B07012 and the National Natural Science Funds no. 20973022 for supporting the research.
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Zhang, S., Zhao, T., Wang, H. et al. Comparison of SPE-TD-GC-FID with UPLC-PDA and GC-MS Methods for Analysis of Benzene, Toluene and Xylene Isomers in Solid-Liquid Mixing Paints. Chromatographia 74, 163–169 (2011). https://doi.org/10.1007/s10337-011-2029-z
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DOI: https://doi.org/10.1007/s10337-011-2029-z