Abstract
Ultrasound-assisted headspace solid-phase microextraction (UA-HS-SPME) coupled to gas chromatography–mass spectrometry (GC–MS) has been used for analysis of volatile compounds in dry Tagetes minuta L. The highest extraction efficiency was achieved with a 100-μm polydimethylsiloxane (PDMS) fiber. Different experimental conditions, for example, type of fiber coating, sonication time, extraction time and temperature, and desorption time, were investigated. Thirty compounds were identified by use of this UA-HS-SPME–GC–MS method. Comparison of the method with the commonly used hydrodistillation (HD) method showed that the proposed method is simpler, needs much less sample, requires shorter extraction time and lower temperature, has high trapping ability, and extracts more volatile and thermally sensitive compounds. The major components identified by use of the method were e-ocimenone (10.3%), cis-β-ocimene (4.8%), α-terpinolene (8.4%), trans-caryophyllene (19.7%), germacrene-d (10.0%), and camphor (3.6%).
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Babu KGD, Kaul VK (2007) Indust Crop Prod 26:241–251
Svetaz L, Zuljan F, Derita M, Petenatti E, Tamayo G, Cáceres A, Cechinel Filho V, Giménez A, Pinzón R, Zacchino SA, Gupta M (2010) J Ethnopharmacol 127:137–158. doi:10.1016/j.jep.2009.09.034
Vasudevan P, Kashyap S, Sharma S (1997) Bioresource Technol 62:29–36
Ruiz-Rodriguez A, Reglero G, Ibañez E (2009) J Pharm Biomed Anal 51:305–326. doi:10.1016/j.jpba.2009.05.012
Breme K, Tournayre P, Fernandez X, Meierhenrich UJ, Brevard H, Joulain D, Berdague JL (2009) J Agr Food Chem 57:8572–8580
Lima WP, Neto FC, Macoris MDD, Zuccari D, Dibo MR (2009) Rev Soc Bras Med Trop 42:638–641
López ML, Bonzani NE, Zygadlo JA (2008) Biochem Sys Ecol 36:882–890. doi:10.1016/j.bse.2008.11.003
Camm EL, Towers GHN, Mitchell JC (1975) Phytochemistry 14:2007–2011
Graham K, Graham EA, Towers GHN (1980) Can J Zool 58:1955–1958
Grainge M, Ahmed S (1988) Handbook of plants with pest-control properties. Wiley, New York
Jacobson M (1990) Glossary of plant-derived insect deterrents. CRC Press, Boca Raton
Hansch C, Sammes PG, Taylor JB (1990) Comprehensive medicinal chemistry: the rational design, mechanistic study & therapeutic application of chemical compounds. Pergamon Press, Oxford
Ranilla LG, Kwon Y-I, Apostolidis E, Shetty K (2010) Bioresource Technol 101:4676–4689. doi:10.1016/j.biortech.2010.01.093
Caceres A, Giron LM, Alvarado SR, Torres MF (1987) J Ethnopharmacol 20:223–237
Lawrence BM (2006) Mint: the genus Mentha. CRC Press, Boca Raton
Baser KHC, Malyer H (1996) J Ess Oil Res 8:337–338
Franz C, Novak J (2009) 3 Sources of essential oils. CRC Press, Boca Raton
Abbasi AM, Khan MA, Ahmad M, Zafar M, Jahan S, Sultana S (2010) J Ethnopharmacol 128:322–335. doi:10.1016/j.jep.2010.01.052
Mbosso EJT, Ngouela S, Nguedia JCA, Beng VP, Rohmer M, Tsamo E (2010) J Ethnopharmacol 128:476–481. doi:10.1016/j.jep.2010.01.017
Meshkatalsadat MH, Safaei-Ghomi J, Moharramipour S, Nasseri M (2010) Dig J Nanomater Biostruct 5:101–106
Verdeguer M, Blázquez MA, Boira H (2009) Biochem Sys Ecol 37:362–369. doi:10.1016/j.bse.2009.06.003
Gil A, Ghersa CM, Leicach S (2000) Biochem Sys Ecol 28:261–274
Ramaroson-Raonizafinimanana B, Ramanoelina PAR, Rasoarahona JRE, Gaydou EM (2009) J Ess Oil Res 21:390–392
Hashemi P, Shamizadeh M, Badiei A, Ghiasvand AR, Azizi K (2009) Chromatographia 70:1147–1151. doi:10.1365/s10337-009-1269-7
Pawliszyn J (1997) Solid phase microextraction: theory and practice. VCH, New York
Pawliszyn J (2002) Sampling and sample preparation for field and laboratory: fundamentals and new directions in sample preparation. Elsevier Science Ltd, Amsterdam
Burbank HM, Qian MC (2005) J Chromatogr A 1066:149–157
Wu S-F, Ding W-H (2010) J Chromatogr A 1217:2776–2781. doi:10.1016/j.chroma.2010.02.067
Bao M, Joza P, Rickert WS, Lauterbach JH (2010) Anal Chim Acta 663:49–54. doi:10.1016/j.aca.2010.01.036
Ridgway K, Lalljie SPD, Smith RM (2010) Anal Chim Acta 677:29–36. doi:10.1016/j.aca.2010.01.049
Poli D, Goldoni M, Corradi M, Acampa O, Carbognani P, Internullo E, Casalini A, Mutti A (2010) J Chromatogr B 878:2643–2651. doi:10.1016/j.jchromb.2010.01.022
Moller M, Aleksa K, Walasek P, Karaskov T, Koren G (2009) Forensic Sci Int 196:64–69. doi:10.1016/j.forsciint.2009.12.046
Mikuma T, Kaneko T (2010) Forensic Sci Int 198:79–84. doi:10.1016/j.forsciint.2010.01.005
López-Darias J, Pino V, Anderson JL, Graham CM, Afonso AM (2009) J Chromatogr A 1217:1236–1243. doi:10.1016/j.chroma.2009.12.041
Llop A, Pocurull E, Borrull F (2009) J Chromatogr A 1217:575–581. doi:10.1016/j.chroma.2009.11.087
Ghiasvand AR, Setkova L, Pawliszyn J (2007) Flav Frag J 22:377–391. doi:10.1002/ffj.1809
de Castro MDL, Capote FP (2007) Analytical applications of ultrasound. Elsevier Science Ltd, Amsterdam
Xu H, Liao Y, Yao J (2007) J Chromatogr A 1167:1–8. doi:10.1016/j.chroma.2007.08.022
Farsizadeh S (2007) MSc Thesis. Lorestan University, Khoramabad, Iran
Guo FQ, Huang LF, Zhou SY, Zhang TM, Liang YZ (2006) Anal Chim Acta 570:73–78
Cao J, Qi M, Fang L, Zhou S, Fu R, Zhang P (2006) J Pharm Biomed Anal 40:552–558. doi:10.1016/j.jpba.2005.07.050
Karami AR, Yamini Y, Ghiasvand AR, Sharghi H, Shamsipur M (2001) J Chem Eng Data 46:1371–1374. doi:10.1021/je0101045
Jennings W, Shibamoto T (1980) Qualitative analysis of flavor and fragrance volatiles by glass capillary gas chromatography. Academic Press, New York
Lawrence BM (1985) Perfum Flav 10:73–82
Moghaddam M, Omidbiagi R, Sefidkon F (2007) J Ess Oil Res 19:18–20
Craveiro AA, Matos FJA, Machado MIL, Alencar JW (1988) Perfum Flav 13:35–36
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Ghiasvand, A.R., Nasseri, M., Farsizaeh, S. et al. Chemical Characterization of Cultivated Tagetes minuta L. by Use of Ultrasound-Assisted Head Space SPME and GC–MS. Chromatographia 73, 1031–1035 (2011). https://doi.org/10.1007/s10337-011-1955-0
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DOI: https://doi.org/10.1007/s10337-011-1955-0