Water quality monitoring and multivariate statistical analysis for rural streams in South Korea

Abstract

South Korea is located in the Asian monsoon region, and paddy rice farming is one of the important agricultural activities, which may contribute to the non-point source pollution of inland water bodies along with rainfall runoff. The status of water quality in rural streams located throughout South Korea was examined in this study by water quality monitoring and statistical analysis. Totally six surveys were conducted in 2003 and 2005 to monitor 300 streams located in rural subwatersheds; these streams are affected by agricultural activities and water supply for agricultural practices. The monitoring was performed at the terminal point of each subwatershed. In each study year, the streams were monitored in the three hydrological periods (April, July, and October) to observe differences in the impacts of agricultural activity and rainfall pattern. During the surveys, 15 water quality parameters were measured and interpreted using multivariate statistical methods including factor analysis and cluster analysis. Results show that the water quality of the rural streams monitored in this study appeared to meet the Korean water quality criteria for agricultural use, which are 8.0 and 100 mg/L for biochemical oxygen demand and suspended solids, respectively. In terms of organic contamination and suspended solids, the best stream water quality was observed in October compared to other periods. This can be attributed to the fact that October follows the rice-harvesting period and has low rainfall; thus the streams are probably less affected by agricultural activities and surface runoff. The three hydrological periods did not show much variation in the nitrogen and phosphorus parameters related to stream water nutrient conditions. Factor analysis indicates that the first five factors for April explained about 67% of the total sample variance. In July, the first four factors explained about 60% of the total variance, while the first four factors for October explained about 65%. Cluster analysis reveals that the streams could be divided into four groups in April and October and five groups in July. The box-and-whisker plots of the physicochemical variables indicate that Group A had the best water quality among the groups. This study demonstrates that the rural stream water quality of South Korea in the Asian monsoon region can be greatly affected by agricultural activities such as paddy rice farming and rainfall patterns.