Abstract
Rising air pollution by surface ozone (O3) in China has induced extensive efforts to control ozone generation in major urban and industrial areas, yet mechanisms ruling the ozone production and loss are not well understood. In particular, ozone levels are strongly influenced by meteorological factors such as relative humidity, but this has been explored only in local situations, and the effect of relative humidity on ozone levels in warm seasons on a large scale in China is still unknown. Here we studied surface ozone, relative humidity, temperature, and other meteorological variables in 74 major cities in China during 2017–2018, focusing on the warm seasons in seven regions. Results show that ozone levels decrease with increasing relative humidity in all cities, with an average correlation coefficient of − 0.58, ranging from − 0.17 in Zhangjiakou to − 0.84 in Hengshui. At high relative humidity levels, above 75%, average ozone levels ranged from 44.6 to 122.5 μg m−3, which is lower than Chinese quality threshold of hourly average ozone level of 200 μg m−3. The decreases of ozone with relative humidity were more pronounced at high temperature, above 30 °C, than below 25 °C. The increases of ozone with temperature were more pronounced at low relative humidity, below 40%. Overall, our findings reveal that mechanisms ruling surface ozone levels are similar on a large scale. This is promising to design common methods of climate engineering to protect human health.
Similar content being viewed by others
References
Bell ML, Dominici F, Samet JM (2005) A meta-analysis of time-series studies of ozone and mortality with comparison to the national morbidity, mortality, and air pollution study. Epidemiology 16:436–445
Booker F, Muntifering R, Mcgrath M et al (2009) The ozone component of global change: Potential effects on agricultural and horticultural plant yield, product quality and interactions with invasive species. J Integr Plant Biol 51:337–351
Camalier L, Cox W, Dolwick P (2007) The effects of meteorology on ozone in urban areas and their use in assessing ozone trends. Atmos Environ 41:7127–7137. https://doi.org/10.1016/j.atmosenv.2007.04.061
Chai F, Gao J, Chen Z et al (2014) Spatial and temporal variation of particulate matter and gaseous pollutants in 26 cities in China. J Environ Sci (china) 26:75–82. https://doi.org/10.1016/S1001-0742(13)60383-6
Chen X, Situ S, Zhang Q et al (2019a) The synergetic control of NO2 and O3 concentrations in a manufacturing city of southern China. Atmos Environ 201:402–416. https://doi.org/10.1016/j.atmosenv.2018.12.021
Chen Z, Zhuang Y, Xie X et al (2019b) Understanding long-term variations of meteorological influences on ground ozone concentrations in Beijing during 2006–2016. Environ Pollut 245:29–37. https://doi.org/10.1016/j.envpol.2018.10.117
Cheng L, Wang S, Gong Z et al (2018) Regionalization based on spatial and seasonal variation in ground-level ozone concentrations across China. J Environ Sci China 67:179–190. https://doi.org/10.1016/j.jes.2017.08.011
Davis J, Cox W, Reff A, Dolwick P (2011) A comparison of CMAQ-based and observation-based statistical models relating ozone to meteorological parameters. Atmos Environ 45:3481–3487. https://doi.org/10.1016/j.atmosenv.2010.12.060
Deng J, Wang T, Liu L, Jiang F (2010) Modeling heterogeneous chemical processes on aerosol surface. Particuology 8:308–318. https://doi.org/10.1016/j.partic.2009.12.003
Doherty RM, Wild O, Shindell DT et al (2013) Impacts of climate change on surface ozone and intercontinental ozone pollution: a multi-model study. J Geophys Res Atmos 118:3744–3763. https://doi.org/10.1002/jgrd.502662013
Dueas C, Fernández MC, Caete S et al (2002) Assessment of ozone variations and meteorological effects in an urban area in the Mediterranean Coast. Sci Total Environ 299:97–113. https://doi.org/10.1016/S0048-9697(02)00251-6
Elminir HK (2005) Dependence of urban air pollutants on meteorology. Sci Total Environ 350:225–237. https://doi.org/10.1016/j.scitotenv.2005.01.043
Gaur A, Tripathi SN, Kanawade VP et al (2014) Four-year measurements of trace gases (SO2, NOx, CO, and O3) at an urban location, Kanpur, in Northern India. J Atmos Chem 71:283–301. https://doi.org/10.1007/s10874-014-9295-8
Gong C, Yue X, Liao H, Ma Y (2021) A humidity-based exposure index representing ozone damage effects on vegetation. Environ Res Lett 16:44030. https://doi.org/10.1088/1748-9326/abecbb
Han H, Liu J, Shu L et al (2020) Local and synoptic meteorological influences on daily variability in summertime surface ozone in eastern China. Atmos Chem Phys 20:203–222. https://doi.org/10.5194/acp-20-203-2020
Han Y, Gong Z, Ye J et al (2019) Quantifying the role of the relative humidity-dependent physical state of organic particulate matter in the uptake of semivolatile organic molecules. Environ Sci Technol 53:13209–13218. https://doi.org/10.1021/acs.est.9b05354
He X, Leng C, Pang S, Zhang Y (2017a) Kinetics study of heterogeneous reactions of ozone with unsaturated fatty acid single droplets using micro-FTIR spectroscopy. RSC Adv 7:3204–3213. https://doi.org/10.1039/C6RA25255A
He X, Pang S, Ma J, Zhang Y (2017b) Influence of relative humidity on heterogeneous reactions of O3 and O3/SO2 with soot particles: potential for environmental and health effects. Atmos Environ 165:198–206. https://doi.org/10.1016/j.atmosenv.2017.06.049
Jia L, Xu Y (2015) Ozone and secondary organic aerosol formation from ethylene–NOx–NaCl irradiations under different relative humidity conditions. J Atmos Chem 73:81–100. https://doi.org/10.1007/s10874-015-9317-1
Johnson CE, Stevenson DS, Collins WJ, Derwent RG (2001) Role of climate feedback on methane and ozone studied with a coupled ocean-atmosphere-chemistry model. Geophys Res Lett 28:1723–1726. https://doi.org/10.1029/2000GL011996
Kavassalis SC, Murphy JG (2017) Understanding ozone-meteorology correlations: a role for dry deposition. Geophys Res Lett 44:2922–2931. https://doi.org/10.1002/2016GL071791
Kotelnikov SN, Stepanov EV (2019) Role of aqueous aerosols in ozone decomposition in the near-surface atmosphere. Bull Lebedev Phys Inst 46:284–288. https://doi.org/10.3103/S1068335619090045
Leu MT, Timonen RS, Keyser LF, Yung YL (1995) Heterogeneous reactions of HNO3(g)+NaCl(s).fwdarw. HCl(g)+NaNO3(s) and N2O5(g)+NaCl(s).fwdarw. ClNO2(g)+NaNO3(s). J Phys Chem 99:13203–13212. https://doi.org/10.1021/j100035a026
Li R, Wang Z, Cui L et al (2019) Air pollution characteristics in China during 2015–2016: spatiotemporal variations and key meteorological factors. Sci Total Environ 648:902–915. https://doi.org/10.1016/j.scitotenv.2018.08.181
Liu PF, Zhao CS, Göbel T et al (2011) Hygroscopic properties of aerosol particles at high relative humidity and their diurnal variations in the north China plain. Atmos Chem Phys 11:3479–3494. https://doi.org/10.5194/acp-11-3479-2011
Lu X, Hong J, Zhang L et al (2018) Severe surface ozone pollution in China: a global perspective. Environ Sci Technol Lett 5:487–494. https://doi.org/10.1021/acs.estlett.8b00366
Manju A, Kalaiselvi K, Dhananjayan V et al (2018) Spatio-seasonal variation in ambient air pollutants and influence of meteorological factors in Coimbatore Southern India. Air Qual Atmos Heal 11:1179–1189. https://doi.org/10.1007/s11869-018-0617-x
Monks PS, Archibald AT, Colette A et al (2015) Tropospheric ozone and its precursors from the urban to the global scale from air quality to short-lived climate forcer. Atmos Chem Phys 15:8889–8973
Murazaki K, Hess P (2006) How does climate change contribute to surface ozone change over the United States? J Geophys Res 111:D05301. https://doi.org/10.1029/2005JD005873
Olszyna KJ, Luria M, Meagher JF (1997) The correlation of temperature and rural ozone levels in southeastern U.S.A. Atmos Environ 31:3011–3022. https://doi.org/10.1016/S1352-2310(97)00097-6
Ou J, Yuan Z, Zheng J et al (2016) Ambient ozone control in a photochemically active region: short-term despiking or long-term attainment? Environ Sci Technol 50:5720–5728. https://doi.org/10.1021/acs.est.6b00345
Ou J, Zheng J, Li R et al (2015) Speciated OVOC and VOC emission inventories and their implications for reactivity-based ozone control strategy in the pearl river delta region, China. Sci Total Environ 530–531:393–402. https://doi.org/10.1016/j.scitotenv.2015.05.062
Reddy PJ, Pfister GG (2016) Meteorological factors contributing to the interannual variability of midsummer surface ozone in Colorado, Utah, and other western U.S. states. J Geophys Res 121:2434–2456. https://doi.org/10.1002/2015JD023840
Reichert L, Andrés Hernández MD, Stöbener D et al (2003) Investigation of the effect of water complexes in the determination of peroxy radical ambient concentrations: implications for the atmosphere. J Geophys Res D Atmos. https://doi.org/10.1029/2002jd002152
Seinfeld JH, Pandis SN (2016) Atmospheric chemistry and physics: from air pollution to climate change, 2nd edn. Wiley, Hoboken, N.J.
Shao M, Tang X, Zhang Y, Li W (2006) City clusters in China: air and surface water pollution. Front Ecol Environ 4:353–361. https://doi.org/10.1890/1540-9295(2006)004[0353:CCICAA]2.0.CO;2
Shao M, Zhang Y, Zeng L et al (2009) Ground-level ozone in the pearl river delta and the roles of VOC and NOx in its production. J Environ Manag 90:512–518. https://doi.org/10.1016/j.jenvman.2007.12.008
Tai APK, Mickley LJ, Jacob DJ (2010) Correlations between fine particulate matter (PM2.5) and meteorological variables in the United States: implications for the sensitivity of PM2.5 to climate change. Atmos Environ 44:3976–3984. https://doi.org/10.1016/j.atmosenv.2010.06.060
Thompson AM, Stewart RW, Owens MA, Herwehe JA (1989) Sensitivity of tropospheric oxidants to global chemical and climate change. Atmos Environ 23:519–532. https://doi.org/10.1016/0004-6981(89)90001-2
Tu J, Xia ZG, Wang H, Li W (2007) Temporal variations in surface ozone and its precursors and meteorological effects at an urban site in China. Atmos Res 85:310–337. https://doi.org/10.1016/j.atmosres.2007.02.003
Wang T, Nie W, Gao J et al (2010a) Air quality during the 2008 Beijing Olympics: secondary pollutants and regional impact. Atmos Chem Phys 10:7603–7615. https://doi.org/10.5194/acp-10-7603-2010
Wang T, Xue L, Brimblecombe P et al (2017) Ozone pollution in China: a review of concentrations, meteorological influences, chemical precursors, and effects. Sci Total Environ 575:1582–1596. https://doi.org/10.1016/j.scitotenv.2016.10.081
Wang X, Zhang Y, Hu Y et al (2010b) Process analysis and sensitivity study of regional ozone formation over the Pearl river delta, China, during the PRIDE-PRD2004 campaign using the community multiscale air quality modeling system. Atmos Chem Phys 10:4423–4437. https://doi.org/10.5194/acp-10-4423-2010
Wang Y, Luo H, Jia L, Ge S (2016) Effect of particle water on ozone and secondary organic aerosol formation from benzene–NO2–NaCl irradiations. Atmos Environ 140:386–394. https://doi.org/10.1016/j.atmosenv.2016.06.022
Yang L, Luo H, Yuan Z et al (2019) Quantitative impacts of meteorology and precursor emission changes on the long-term trend of ambient ozone over the Pearl River Delta, China, and implications for ozone control strategy. Atmos Chem Phys 19:12901–12916. https://doi.org/10.5194/acp-19-12901-2019
Yu S (2019) Fog geoengineering to abate local ozone pollution at ground level by enhancing air moisture. Environ Chem Lett 17:565–580. https://doi.org/10.1007/s10311-018-0809-5
Yu S, Mathur R, Kang D et al (2006) Performance and diagnostic evaluation of ozone predictions by the eta-community multiscale air quality forecast system during the 2002 new England air quality study. J Air Waste Manag Assoc 56:1459–1471. https://doi.org/10.1080/10473289.2006.10464554
Zanobetti A, Schwartz J (2008) Mortality displacement in the association of ozone with mortality: an analysis of 48 cities in the United States. Am J Respir Crit Care Med 177:184–189. https://doi.org/10.1164/rccm.200706-823OC
Zhao B, Wang P, Ma JZ et al (2012) A high-resolution emission inventory of primary pollutants for the Huabei region, China. Atmos Chem Phys 12:481–501. https://doi.org/10.5194/acp-12-481-2012
Acknowledgements
This work was supported in part by the Department of Science and Technology of China (No. 2016YFC0202702, 2018YFC0213506, and 2018YFC0213503), National Research Program for Key Issues in Air Pollution Control in China (No. DQGG0107), and National Natural Science Foundation of China (No. 21577126 and 41561144004). Part of this work was also supported by the “Zhejiang 1000 Talent Plan” and Research Center for Air Pollution and Health in Zhejiang University. Pengfei Li is supported by National Natural Science Foundation of China (No. 22006030), Initiation Fund for Introducing Talents of Hebei Agricultural University (412201904), and Hebei Youth Top Fund (BJ2020032).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Li, M., Yu, S., Chen, X. et al. Large scale control of surface ozone by relative humidity observed during warm seasons in China. Environ Chem Lett 19, 3981–3989 (2021). https://doi.org/10.1007/s10311-021-01265-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10311-021-01265-0