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Water-assisted synthesis of shape-specific BiOCl nanoflowers with enhanced adsorption and photosensitized degradation of rhodamine B

  • Xianlong Zhang
  • Long Yuan
  • Fengbing Liang
  • Dong An
  • Zhen Chen
  • Dexin FengEmail author
  • Mo Xian
Original Paper
  • 54 Downloads

Abstract

Semiconductor photocatalysis is a sustainable and advanced method for depollution and energy shortage, yet efficient photocatalysts have to be synthesized. For instance, BiOCl is a promising photocatalyst, but its efficiency is largely dependent on morphology. In particular, there is a need for simple synthesis procedures and easily controllable facet exposure. Here, nanosheet-assembled BiOCl nanoflowers with exposed {001} facets were prepared by a rapid, efficient, water-assisted synthesis. BiOCl nanoflowers exhibited 3.3 times better adsorption and 3.5 times superior photosensitized degradation of rhodamine B under visible light irradiation, compared with BiOCl nanosheets. These improvements are attributed to the higher exposition of the {001} facet and 3D hierarchical structure. This work offers new insights to better understand the photosensitized degradation and rational design of highly active photocatalysts.

Keywords

Adsorption BiOCl (001) Nanoparticles Photocatalysis Rhodamine B Semiconductor 

Notes

Acknowledgements

The authors would like to thank the National Natural Science Foundation (21406252), DNL Cooperation Fund CAS (DNL180309), Youth Innovation Promotion Association CAS (2012170), Taishan Scholars (ts201712076), and Taishan Scholars Climbing Program (tspd20150210) of Shandong for the financial support of this investigation.

Supplementary material

10311_2019_929_MOESM1_ESM.docx (1.9 mb)
Supplementary file1 (DOCX 1921 kb)

References

  1. Bello MM, Raman AA (2019) Synergy of adsorption and advanced oxidation processes in recalcitrant wastewater treatment. Environ Chem Lett 17:1125–1142.  https://doi.org/10.1007/s10311-018-00842-0 CrossRefGoogle Scholar
  2. Cai Y, Li D, Sun J, Chen M, Li Y, Zou Z, Zhang H, Xu H, Xia D (2018) Synthesis of BiOCl nanosheets with oxygen vacancies for the improved photocatalytic properties. Appl Surf Sci 439:697–704.  https://doi.org/10.1016/j.apsusc.2018.01.089 CrossRefGoogle Scholar
  3. Chen L, Yin SF, Huang R, Zhou Y, Luo SL, Au CT (2012) Facile synthesis of BiOCl nano-flowers of narrow band gap and their visible-light-induced photocatalytic property. Catal Commun 23:54–57.  https://doi.org/10.1016/j.catcom.2012.03.001 CrossRefGoogle Scholar
  4. Chen H, Yu X, Zhu Y, Fu X, Zhang Y (2016) Controlled synthesis of {001} facets-dominated dye-sensitized BiOCl with high photocatalytic efficiency under visible-light irradiation. J Nanopart Res 18:225.  https://doi.org/10.1007/s11051-016-3529-4 CrossRefGoogle Scholar
  5. Chen Y, Zhou Y, Dong Q, Ding H (2018) One-step in situ synthesis of BiOCl/(BiO)2CO3 composite photocatalysts with exposed high-energy {001} facets. Cryst Eng Commun 20:7838–7850.  https://doi.org/10.1039/C8CE01608A CrossRefGoogle Scholar
  6. Ding L, Wei R, Chen H, Hu J, Li J (2015) Controllable synthesis of highly active BiOCl hierarchical microsphere self-assembled by nanosheets with tunable thickness. Appl Catal B-Environ 172–173:91–99.  https://doi.org/10.1016/j.apcatb.2015.02.019 Google Scholar
  7. Haider Z, Zheng JY, Kang YS (2016) Surfactant free fabrication and improved charge carrier separation induced enhanced photocatalytic activity of {001} facet exposed unique octagonal BiOCl nanosheets. Phys Chem Chem Phys 18:19595–19604.  https://doi.org/10.1039/c6cp01740a CrossRefGoogle Scholar
  8. He J, Wang J, Liu Y, Mirza ZA, Zhao C, Xiao W (2015) Microwave-assisted synthesis of BiOCl and its adsorption and photocatalytic activity. Ceram Int 41:8028–8033.  https://doi.org/10.1016/j.ceramint.2015.02.152 CrossRefGoogle Scholar
  9. Hu J, Fan W, Ye W, Huang C, Qiu X (2014) Insights into the photosensitivity activity of BiOCl under visible light irradiation. Appl Catal B-Environ 158:182–189.  https://doi.org/10.1016/j.apcatb.2014.04.019 CrossRefGoogle Scholar
  10. Jiang J, Zhao K, Xiao X, Zhang L (2012) Synthesis and facet-dependent photoreactivity of BiOCl single-crystalline nanosheets. J Am Chem Soc 134:4473–4476.  https://doi.org/10.1021/ja210484t CrossRefGoogle Scholar
  11. Khin MM, Nair AS, Babu VJ, Murugan R, Ramakrishna S (2012) A review on nanomaterials for environmental remediation. Energy Environ Sci 5:8075–8109.  https://doi.org/10.1039/C2EE21818F CrossRefGoogle Scholar
  12. Li H, Shang J, Zhu H, Yang Z, Ai Z, Zhang L (2016a) Oxygen vacancy structure associated photocatalytic water oxidation of BiOCl. ACS Catal 6:8276–8285.  https://doi.org/10.1021/acscatal6b02613 CrossRefGoogle Scholar
  13. Li Y, Tian Y, Zhang R, Ma L, Zhou C, Tian X (2016b) Hierarchical BiOCl microspheres with narrow band gap as visible light active photocatalysts. Inorg Chim Acta 439:123–129.  https://doi.org/10.1016/j.ica.2015.10.014 CrossRefGoogle Scholar
  14. Li K, Liang Y, Yang J, Gao Q, Zhu Y, Liu S, Wu X (2017) Controllable synthesis of {001} facet dependent foursquare BiOCl nanosheets: a high efficiency photocatalyst for degradation of methyl orange. J Alloys Compd 695:238–249.  https://doi.org/10.1016/j.jallcom.2016.10.204 CrossRefGoogle Scholar
  15. Li H, Li J, Ai Z, Jia F, Zhang L (2018a) Oxygen vacancy-mediated photocatalysis of BiOCl: reactivity selectivity and perspectives. Angew Chem Int Edit 57:122–138.  https://doi.org/10.1002/anie.201705628 CrossRefGoogle Scholar
  16. Li Y, Zhao Y, Wu G, Ma H, Zhao J (2018b) Bi superlattice nanopolygons at BiOCl (001) nanosheet assembled architectures for visible-light photocatalysis. Mater Res Bull 101:39–47.  https://doi.org/10.1016/j.materresbull.2017.12.041 CrossRefGoogle Scholar
  17. Liu J, Chen L, Zhang S, Zhao H (2018) Visible-light photoactive BiOCl nanosheets prepared by a solution chemistry method. Mater Lett 233:174–176.  https://doi.org/10.1016/j.matlet.2018.08.156 CrossRefGoogle Scholar
  18. Osman H, Su Z, Ma X (2017) Efficient photocatalytic degradation of Rhodamine B dye using ZnO/graphitic C3N4 nanocomposites synthesized by microwave. Environ Chem Lett 15:435–441.  https://doi.org/10.1007/s10311-017-0604-8 CrossRefGoogle Scholar
  19. Patil SB, Basavarajappa PS, Ganganagappa N, Jyothi MS, Raghu AV, Reddy KR (2019) Recent advances in non-metals-doped TiO2 nanostructured photocatalysts for visible-light driven hydrogen production, CO2 reduction and air purification. Int J Hydrogen Energy 44:13022–13039.  https://doi.org/10.1016/j.ijhydene.2019.03.164 CrossRefGoogle Scholar
  20. Peng Y, Wang D, Zhou H, Xu A (2015) Controlled synthesis of thin BiOCl nanosheets with exposed {001} facets and enhanced photocatalytic activities. CrystEngComm 17:3845–3851.  https://doi.org/10.1039/c5ce00289c CrossRefGoogle Scholar
  21. Saeed M, Ahmad A, Boddula R, Inamuddin, ul Haq A, Azhar A (2018) Ag@MnxOy: an effective catalyst for photo-degradation of rhodamine B dye. Environ Chem Lett 16:287–294.  https://doi.org/10.1007/s10311-017-0661-z CrossRefGoogle Scholar
  22. Seddigi ZS, Gondal MA, Baig U, Ahmed SA, Abdulaziz MA, Danish EY, Lais A (2017) Facile synthesis of light harvesting semiconductor bismuth oxychloride nano photo-catalysts for efficient removal of hazardous organic pollutants. PLoS ONE 12:e0172218.  https://doi.org/10.1371/journal.pone.0172218 CrossRefGoogle Scholar
  23. Shwetharani R, Chandan H, Balakrishna GR, Reddy KR, Raghu AV (2019) Photocatalytic semiconductor thin films for hydrogen production and environmental applications. Int J Hydrogen Energ.  https://doi.org/10.1016/j.ijhydene.2019.03.149 Google Scholar
  24. Song J, Fan Q, Zhu W, Wang R, Dong Z (2016) Preparation of BiOCl with high specific surface area and excellent visible light photocatalytic activity. Mater Lett 165:14–18.  https://doi.org/10.1016/j.matlet.2015.11.093 CrossRefGoogle Scholar
  25. Tarkwa JB, Oturan N, Acayanka E, Laminsi S, Oturan MA (2019) Photo-Fenton oxidation of Orange G azo dye: process optimization and mineralization mechanism. Environ Chem Lett 17:473–479.  https://doi.org/10.1007/s10311-018-0773-0 CrossRefGoogle Scholar
  26. Wang DH, Gao GQ, Zhang YW, Zhou LS, Xu AW, Chen W (2012) Nanosheet-constructed porous BiOCl with dominant {001} facets for superior photosensitized degradation. Nanoscale 4:7780–7785.  https://doi.org/10.1039/C2NR32533K CrossRefGoogle Scholar
  27. Xu K, Fu X, Peng Z (2018) Facile synthesis and photocatalytic activity of La-doped BiOCl hierarchical flower-like nano-/micro-structures. Mater Res Bull 98:103–110.  https://doi.org/10.1016/j.materresbull.2017.10.013 CrossRefGoogle Scholar
  28. Ye L, Zan L, Tian L, Peng T, Zhang J (2011) The {001} facets-dependent high photoactivity of BiOCl nanosheets. Chem Commun 47:6951–6953.  https://doi.org/10.1039/c1cc11015b CrossRefGoogle Scholar
  29. Zhang X, An D, Feng D, Liang F, Chen Z, Liu W, Yang Z, Xian M (2019) In situ surfactant-free synthesis of ultrathin BiOCl/g–C3N4 nanosheets for enhanced visible-light photodegradation of rhodamine B. Appl Surf Sci 476:706–715.  https://doi.org/10.1016/j.apsusc.2019.01.147 CrossRefGoogle Scholar
  30. Zhao K, Zhang L, Wang J, Li Q, He W, Yin JJ (2013) Surface structure-dependent molecular oxygen activation of BiOCl single-crystalline nanosheets. J Am Chem Soc 135:15750–15753.  https://doi.org/10.1021/ja4092903 CrossRefGoogle Scholar
  31. Zhao S, Zhang Y, Zhou Y, Zhang C, Sheng X, Fang J, Zhang M (2017) Reactable polyelectrolyte-assisted synthesis of BiOCl with enhanced photocatalytic activity. ACS Sustain Chem Eng 5:1416–1424.  https://doi.org/10.1021/acssuschemeng.6b01987 CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  1. 1.CAS Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess TechnologyChinese Academy of SciencesQingdaoChina
  2. 2.Dalian National Laboratory for Clean EnergyDalianChina
  3. 3.Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of EducationJilin Normal UniversityChangchunChina

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