Environmental Chemistry Letters

, Volume 16, Issue 3, pp 1089–1093 | Cite as

Easier removal of nonylphenol and naphthalene pollutants in wet weather revealed by Markov chains modeling

  • Mo Zhou
  • Jiquan Zhang
  • Caiyun Sun
Original Paper


The distribution and fate of organic pollutants determines pollution control strategies and definition of environmental standards. So far, few models predict accurately the fate of organic pollutants. Therefore, here we tested the Markov chains model to simulate the distribution and fate of nonylphenol and naphthalene in the aquatic environment. Results show that the removal of nonylphenol and naphthalene from the water/sediment system is higher in the wet season and lower in the dry season. Due to its hydrophilic hydroxyl group, nonylphenol remains in water, whereas naphthalene, being more hydrophobic, accumulates in the sediment. Results of Markov chains modeling perfectly matched results from microcosm experiments.


Persistent organic pollutants Aquatic environment Seasonality Fate Markov chains 



This work was supported by the National Major Program of Water Pollution Control and Treatment Technology of China [2014ZX07201011] and the Fundamental Research Funds for the Central Universities [No. 2412016KJ046] and the Program of Introducing Talents of Discipline to Universities [B16011].


  1. Abbas I, Badran G, Verdin A et al (2018) Polycyclic aromatic hydrocarbon derivatives in airborne particulate matter: sources, analysis and toxicity. Environ Chem Lett 9:1–37. Google Scholar
  2. Achman DR, Hornbuckle KC, Eisenreich SJ (1993) Volatilization of polychlorinated biphenyls from Green Bay, Lake Michigan. Environ Sci Technol 27:99–123. CrossRefGoogle Scholar
  3. Bakir A, Rowlandb SJ, Thompson RC (2014) Transport of persistent organic pollutants by microplastics in estuarine conditions. Estuar Coast Shelf Sci 140:14–21. CrossRefGoogle Scholar
  4. Daniels WM, House WA, Rae JE, Parker A (2000) The distribution of micro-organic contaminants in river bed-sediment cores. Sci Total Environ 253:81–92. CrossRefGoogle Scholar
  5. Din I, Rashid A, Mahmood T, Khalid A (2013) Effect of land use activities on PAH contamination in urban soils of Rawalpindi and Islamabad, Pakistan. Environ Monit Assess 185:8685–8694. CrossRefGoogle Scholar
  6. Golding CJ, Smernik RJ, Birch GF (2005) Investigation of the role of structural domains identified in sedimentary organic matter in the sorption of hydrophobic organic compounds. Environ Sci Technol 39:3925–3932. CrossRefGoogle Scholar
  7. Hogarh JN, Seike N, Kobara Y, Masunaga S (2013) Seasonal variation of atmospheric polychlorinated biphenyls and polychlorinated naphthalenes in Japan. Atmos Environ 80:275–280. CrossRefGoogle Scholar
  8. Kasiotis K, Emmanouil C (2015) Advanced PAH pollution monitoring by bivalves. Environ Chem Lett 13(4):395–411. CrossRefGoogle Scholar
  9. Lau YL, Liu DLS, Pacepavicius GJ, Maguire RJ (1995) Volatilization of metolachlor from water. J Environ Sci Health Part B 30:605–620. CrossRefGoogle Scholar
  10. Meng J, Hong S, Wang T, Li Q, Yoon SJ, Lu Y, Giesy JP, Khim JS (2017) Traditional and new POPs in environments along the Bohai and Yellow Seas: an overview of China and South Korea. Chemosphere 169:503–515. CrossRefGoogle Scholar
  11. Navarro A, Endo S, Gocht T, Barth JA, Lacorte S (2009) Sorption of alkylphenols on Ebro River sediments: comparing isotherms with field observations in river water and sediments. Environ Pollut 157:698–703. CrossRefGoogle Scholar
  12. Núñez L, Turiel E, Tadeo JL (2007) Determination of nonylphenol and nonylphenolethoxylates in environmental solid samples by ultrasonic-assisted extraction and high performance liquid chromatography-fluorescence detection. J Chromatogr A 1146:157–163. CrossRefGoogle Scholar
  13. Patrick R, Jan S, Andreas S, Timm K, Burkhard S (2011) First evidence for a stereoselective incorporation of nonylphenol diastereomers in soil-derived organo-clay complexes. Environ Chem Lett 9(2):293–299. CrossRefGoogle Scholar
  14. Riefer P, Klausmeyer T et al (2011) Rapid incorporation and short-term distribution of a nonylphenol isomer and the herbicide MCPA in soil-derived organo-clay complexes. Environ Chem Lett 9(3):411–415. CrossRefGoogle Scholar
  15. Shanker U, Rani M, Jassal V (2017) Degradation of hazardous organic dyes in water by nanomaterials. Environ Chem Lett 15(1):1–20. CrossRefGoogle Scholar
  16. Sun C, Ma Q, Zhang J, Zhou M, Chen Y (2016) Predicting seasonal fate of Phenanthrene in aquatic environment with Markov chain. Environ Sci Pollut Res 23:16661–16670. CrossRefGoogle Scholar
  17. Tai C, Zhang S et al (2017) Solar-induced generation of singlet oxygen and hydroxyl radical in sewage wastewaters. Environ Chem Lett. Google Scholar
  18. Tijani J, Fatoba O, Babajide O, Petrik L (2015) Pharmaceuticals, endocrine disruptors, personal care products, nanomaterials and perfluorinated pollutants: a review. Environ Chem Lett 14(1):27–49. CrossRefGoogle Scholar
  19. Wang J, Li L, Liu J, Ti B (2017) Distribution mode and environmental risk of POP pesticides such as endosulfan under the agricultural practice of straw incorporating. Environ Pollut 220:1394–1399. CrossRefGoogle Scholar
  20. Wei Z, Spinney R (2016) Effect of pH on the sonochemical degradation of organic pollutants. Environ Chem Lett 14(2):163–182. CrossRefGoogle Scholar
  21. Zhang L, Dai S (2007) Application of Markov model to environmental fate of phenanthrene in Lanzhou Reach of Yellow River. Chemosphere 67:1296–1299. CrossRefGoogle Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Institute of Natural Disaster Research, School of EnvironmentNortheast Normal UniversityChangchunPeople’s Republic of China
  2. 2.Key Laboratory for Vegetation EcologyMinistry of EducationChangchunPeople’s Republic of China
  3. 3.State Environmental Protection Key Laboratory of Wetland Ecology and Vegetation RestorationNortheast Normal UniversityChangchunPeople’s Republic of China
  4. 4.School of Resources and Environmental EngineeringJilin Institute of Chemical TechnologyJilinPeople’s Republic of China

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