Abstract
The development of cost-effective and eco-friendly alternatives of energy storage systems is needed to solve the actual energy crisis. Although technologies such as flywheels, supercapacitors, pumped hydropower and compressed air are efficient, they have shortcomings because they require long planning horizons to be cost-effective. Renewable energy storage systems such as redox flow batteries are actually of high interest for grid-level energy storage, in particular iron-based flow batteries. Here we review all-iron redox flow battery alternatives for storing renewable energies. The role of components such as electrolyte, electrode and membranes in the overall functioning of all-iron redox flow batteries is discussed. The effect of iron–ligand chemistry on the performance of battery is highlighted. Additionally, a brief contextual background and fundamentals of redox flow batteries are provided. The design aspects, progress in research, mathematical modeling, cost estimations and future prospects of using all-iron energy systems are discussed in the context of future grid-level energy storage.
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References
Alotto P, Guarnieri M, Moro F (2014) Redox flow batteries for the storage of renewable energy: a review. Renew Sustain Energy Rev 29:325–335. https://doi.org/10.1016/j.rser.2013.08.001
Appleby A, Jacquier M (1976) The CGE circulating zinc/air battery: a practical vehicle power source. J Power Sources 1(1):17–34. https://doi.org/10.1016/0378-7753(76)80003-1
Arenas L, Walsh F, de León CP (2015) 3D-printing of redox flow batteries for energy storage: a rapid prototype laboratory cell. ECS J Solid State Sci Technol 4(4):P3080–P3085. https://doi.org/10.1149/2.0141504jss
Bartolozzi M (1989) Development of redox flow batteries. A historical bibliography. J Power Sources 27(3):219–234. https://doi.org/10.1016/0378-7753(89)80037-0
Bolzan J, Arvia A (1963) Hydrolytic equilibria of metallic ions—II: the hydrolysis of Fe(II) ion in NaClO4 solutions. Electrochim Acta 8(5):375–385. https://doi.org/10.1016/0013-4686(63)80066-3
Bromberger K, Kaunert J, Smolinka T (2014) A model for all-vanadium redox flow batteries: introducing electrode-compression effects on voltage losses and hydraulics. Energy Technol 2(1):64–76. https://doi.org/10.1002/ente.201300114
Chang-Yong L, Cheng X-X, Chang-Shi L (2017) The application of 3D printing in lithium-ion batteries. DEStech Trans Eng Technol Res: 244–250. https://doi.org/10.12783/dtetr/icmeca2017/11940
Chen YWD, Santhanam K, Bard AJ (1981) Solution redox couples for electrochemical energy storage I. Iron (III)–iron (II) complexes with O-phenanthroline and related ligands. J Electrochem Soc 128(7):1460–1467. https://doi.org/10.1149/1.2127663
Duduta M, Ho B, Wood VC, Limthongkul P, Brunini VE, Carter WC, Chiang YM (2011) Semi-solid lithium rechargeable flow battery. Adv Energy Mater 1(4):511–516. https://doi.org/10.1002/aenm.201100152
Evans C, Song Y (2013) Internally manifolded flow cell for an all-iron hybrid flow battery, Google Patents
Evans CE, Song Y (2016) Method and system for rebalancing electrolytes in a redox flow battery system, Google Patents
Giner J, Swette L, Cahill K (1976) Screening of redox couples and electrode materials NASA CR-134705. Lewis Research Centre, Cleveland, pp 1–107
Gong K, Xu F, Grunewald JB, Ma X, Zhao Y, Gu S, Yan Y (2016) All-soluble all-iron aqueous redox-flow battery. ACS Energy Lett 1(1):89–93. https://doi.org/10.1021/acsenergylett.6b00049
Hagedorn NH (1984) Nasa redox storage system development project. Final Report. No. DOE/NASA/12726-24; NASA-TM-83677. National Aeronautics and Space Administration, Lewis Research Center, Cleveland, OH
Hawthorne KL (2014) Iron–ligand electrokinetics towards an all-iron hybrid redox flow battery. Case Western Reserve University, Cleveland
Hawthorne KL, Wainright JS, Savinell RF (2014a) Maximizing plating density and efficiency for a negative deposition reaction in a flow battery. J Power Sources 269:216–224. https://doi.org/10.1016/j.jpowsour.2014.06.125
Hawthorne KL, Wainright JS, Savinell RF (2014b) Studies of iron–ligand complexes for an all-iron flow battery application. J Electrochem Soc 161(10):A1662–A1671. https://doi.org/10.1149/2.0761410jes
Hawthorne KL, Petek TJ, Miller MA, Wainright JS, Savinell RF (2015) An investigation into factors affecting the iron plating reaction for an all-iron flow battery. J Electrochem Soc 162(1):A108–A113. https://doi.org/10.1149/2.0591501jes
Hruska L, Savinell R (1981) Investigation of factors affecting performance of the iron-redox battery. J Electrochem Soc 128(1):18–25. https://doi.org/10.1149/1.2127366
Ibanez JG, Choi CS, Becker RS (1987) Aqueous redox transition metal complexes for electrochemical applications as a function of pH. J Electrochem Soc 134(12):3083–3089. https://doi.org/10.1149/1.2100344
Knudsen J, Larsen E, Moreira J, Nielsen OF (1976) Characterization of decaaqua-μ-oxodiiron (iii) by moessbauer and vibrational spectroscopy. ChemInform 7(8):833–839
Marschewski J, Brenner L, Ebejer N, Ruch P, Michel B, Poulikakos D (2017) 3D-printed fluidic networks for high-power-density heat-managing miniaturized redox flow batteries. Energy Environ Sci 10(3):780–787. https://doi.org/10.1039/C6EE03192G
Mellentine J (2011) Performance characterization and cost assessment of an iron hybrid flow battery. Dr Diss 1–124
Modiba P, Matoetoe M, Crouch AM (2012) Electrochemical impedance spectroscopy study of Ce(IV) with aminopolycarboxylate ligands for redox flow batteries applications. J Power Sources 205:1–9. https://doi.org/10.1016/j.jpowsour.2012.01.004
Perez J, Lopez-Atalaya M, Codina G, Vazquez J (1991) Screening of advanced membranes for the Fe/Cr redox flow battery in separated reactant operation. Bull Electrochem 7:555
Perrin D (1959) 338. The stability of iron complexes. Part IV. Ferric complexes with aliphatic acids. J Chem Soc (Resumed): 1710–1717
Petek TJ (2015) Enhancing the capacity of all-iron flow batteries: understanding crossover and slurry electrodes. Case Western Reserve University, Cleveland
Petek TJ, Hoyt NC, Savinell RF, Wainright JS (2015) Slurry electrodes for iron plating in an all-iron flow battery. J Power Sources 294:620–626. https://doi.org/10.1016/j.jpowsour.2015.06.050
Petek TJ, Hoyt NC, Savinell RF, Wainright JS (2016) Characterizing slurry electrodes using electrochemical impedance spectroscopy. J Electrochem Soc 163(1):A5001–A5009. https://doi.org/10.1149/2.0011601jes
Reid MA, Gahn RF (1977) Factors affecting the open-circuit voltage and electrode kinetics of some iron/titanium redox flow cells. NASA Lewis Research Center, Cleveland, OH
Rychcik M, Skyllas-Kazacos M (1988) Characteristics of a new all-vanadium redox flow battery. J Power Sources 22(1):59–67. https://doi.org/10.1016/0378-7753(88)80005-3
Shah A, Tangirala R, Singh R, Wills R, Walsh F (2011) A dynamic unit cell model for the all-vanadium flow battery. J Electrochem Soc 158(6):A671–A677. https://doi.org/10.1149/1.3561426
Soloveichik GL (2015) Flow batteries: current status and trends. Chem Rev 115(20):11533–11558. https://doi.org/10.1021/cr500720t
Sum E, Skyllas-Kazacos M (1985) A study of the V (II)/V (III) redox couple for redox flow cell applications. J Power Sources 15(2–3):179–190. https://doi.org/10.1016/0378-7753(85)80071-9
Sum E, Rychcik M, Skyllas-Kazacos M (1985) Investigation of the V (V)/V (IV) system for use in the positive half-cell of a redox battery. J Power Sources 16(2):85–95. https://doi.org/10.1016/0378-7753(85)80082-3
Tanaka T, Sakamoto T, Mori N, Mizunami K, Shigematsu T (1990) Development of a redox flow battery. SEI Tech Rev 137:191
Tang A, Bao J, Skyllas-Kazacos M (2012a) Thermal modelling of battery configuration and self-discharge reactions in vanadium redox flow battery. J Power Sources 216:489–501. https://doi.org/10.1016/j.jpowsour.2012.06.052
Tang A, Ting S, Bao J, Skyllas-Kazacos M (2012b) Thermal modelling and simulation of the all-vanadium redox flow battery. J Power Sources 203:165–176. https://doi.org/10.1016/j.jpowsour.2011.11.079
Thaller L (1974) Electrically rechargeable redox flow cells. NASA-TM-X-71540, E-7922, NASA Lewis Research Center, Cleveland, OH
Thaller LH (1979) Recent advances in redox flow cell storage systems. NASA-TM-79186, DOE/NASA/1002-79/4, E-053, NASA Lewis Research Center, Cleveland, OH
Thaller L (1981) Performance mapping studies in redox flow cells. NASA-TM-82707, DOE/NASA/12726-13, NAS 1.15:82707, DE82-003288, NASA Lewis Research Center, Cleveland, OH
Tucker MC, Srinivasan V, Ross PN, Weber AZ (2013) Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts. J Appl Electrochem 43(7):637–644. https://doi.org/10.1007/s10800-013-0553-2
Tucker MC, Phillips A, Weber AZ (2015) All-iron redox flow battery tailored for off-grid portable applications. Chemsuschem 8(23):3996–4004. https://doi.org/10.1002/cssc.201500845
Viswanathan V, Crawford A, Stephenson D, Kim S, Wang W, Li B, Coffey G, Thomsen E, Graff G, Balducci P (2014) Cost and performance model for redox flow batteries. J Power Sources 247:1040–1051. https://doi.org/10.1016/j.jpowsour.2012.12.023
Wang W, Luo Q, Li B, Wei X, Li L, Yang Z (2013) Recent progress in redox flow battery research and development. Adv Func Mater 23(8):970–986. https://doi.org/10.1002/adfm.201200694
Weber AZ, Mench MM, Meyers JP, Ross PN, Gostick JT, Liu Q (2011) Redox flow batteries: a review. J Appl Electrochem 41(10):1137. https://doi.org/10.1007/s10800-011-0348-2
Wen Y, Zhang H, Qian P, Zhou H, Zhao P, Yi B, Yang Y (2006) A study of the Fe(III)/Fe(II)–triethanolamine complex redox couple for redox flow battery application. Electrochim Acta 51(18):3769–3775. https://doi.org/10.1016/j.electacta.2005.10.040
Wu S, Zhao Y, Li D, Xia Y, Si S (2015) An asymmetric Zn//Ag doped polyaniline microparticle suspension flow battery with high discharge capacity. J Power Sources 275:305–311. https://doi.org/10.1016/j.jpowsour.2014.11.012
Xu Q, Zhao T (2015) Fundamental models for flow batteries. Prog Energy Combust Sci 49:40–58. https://doi.org/10.1016/j.pecs.2015.02.001
Zhao Y, Si S, Wang L, Liao C, Tang P, Cao H (2014) Electrochemical study on polypyrrole microparticle suspension as flowing anode for manganese dioxide rechargeable flow battery. J Power Sources 248:962–968. https://doi.org/10.1016/j.jpowsour.2013.10.008
Zito R (1973) Rechargeable metal halide battery, Google Patents
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We gratefully thank the Department of Science and Technology (DST), India, for financial support under MES scheme, DST/TMD/MES/2K16/83.
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Dinesh, A., Olivera, S., Venkatesh, K. et al. Iron-based flow batteries to store renewable energies. Environ Chem Lett 16, 683–694 (2018). https://doi.org/10.1007/s10311-018-0709-8
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DOI: https://doi.org/10.1007/s10311-018-0709-8