Abstract
It is difficult to meet the increasingly stringent environmental regulations by the application of conventional precipitation processes treating complex heavy metal wastewaters. We studied the potential of a new method for removing heavy metals from metal–EDTA wastewater by Fenton reaction followed by hydroxide precipitation. This process is referred to as Fenton reaction-hydroxide precipitation (FR-HP) process. This study investigated the use of FR-HP and ultrasonic/FR-HP processes for the removal of Ni(II) from Ni–EDTA wastewater. The results indicate that ultrasonic/FR-HP process is more effective for the removal of nickel ions than FR-HP process.
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Chen R, Pignatello JJ (1997) Role of quinone intermediates as electron shuttles in Fenton and photoassisted Fenton oxidations of aromatic compounds. Environ Sci Technol 31:2399–2406. doi:10.1021/es9610646
De Laat J, Gallard H (1999) Catalytic decomposition of hydrogen peroxide by Fe(III) in homogeneous aqueous solution: mechanism and kinetic modeling. Environ Sci Technol 33:2726–2732. doi:10.1021/es981171v
Fu FL, Chen RM, Xiong Y (2006) Application of a novel strategy—coordination polymerization precipitation to the treatment of Cu2+-containing wastewaters. Sep Purif Technol 52:388–393. doi:10.1016/j.seppur.2006.05.017
Fu FL, Zeng HY, Cai QH, Qiu RL, Yu J, Xiong Y (2007) Effective removal of coordinated copper from wastewater using a new dithiocarbamate-type supramolecular heavy metal precipitant. Chemosphere 69:1783–1789. doi:10.1016/j.chemosphere.2007.05.063
Gallard H, De Laat J, Legube B (1999) Spectrophotometric study of the formation of iron(III)-hydroperoxy complexes in homogeneous aqueous solutions. Water Res 33:2929–2936. doi:10.1016/S0043-1354(99)00007-X
Ghiselli G, Jardim WF, Litter MI, Mansilla HD (2004) Destruction of EDTA using Fenton and photo-Fenton-like reactions under UV-A irradiation. J Photochem Photobiol 167:59–67. doi:10.1016/j.jphotochem.2004.02.005
Guo Z, Zheng Z, Zheng S, Hu W, Feng R (2005) Effect of various sono-oxidation parameters on the removal of aqueous 2, 4-dinitrophenol. Ultrason Sonochem 12:461–465. doi:10.1016/j.ultsonch.2004.07.006
Joseph JM, Destaillats H, Hung HM, Hoffmann MR (2000) The sonochemical degradation of azobenzene and related azo dyes: rate enhancements via Fenton’s reactions. J Phys Chem A 104:301–307. doi:10.1021/jp992354m
Liang J, Komarov S, Hayashi N, Kasai E (2007) Improvement in sonochemical degradation of 4-chlorophenol by combined use of Fenton-like reagents. Ultrason Sonochem 14:201–207. doi:10.1016/j.ultsonch.2006.05.002
Ma J, Song W, Chen C, Ma W, Zhao J, Tang Y (2005) Fenton degradation of organic compounds promoted by dyes under visible irradiation. Environ Sci Technol 39:5810–5815. doi:10.1021/es050001x
Madden TH, Datye AK, Fulton M (1997) Oxidation of metal–EDTA complexes by TiO2 photocatalysis. Environ Sci Technol 31:3475–3481
Mason TJ, Pétrier C (2004) Ultrasound processes. In: Parson S (ed) Advanced oxidation processes for water and wastewater treatment. IWA Publishing, London, pp 185–208
Neppolian B, Jung H, Choi H, Lee JH, Kang JW (2002) Sonolytic degradation of methyl tert-butyl ether: the role of coupled fenton process and persulphate ion. Water Res 36:4699–4708. doi:10.1016/S0043-1354(02)00211-7
Neyens E, Baeyens J (2003) A review of classic Fenton’s peroxidation as an advanced oxidation technique. J Hazard Mater 98:33–50. doi:10.1016/S0304-3894(02)00282-0
Pakalapati SNR, Popov BN, White RE (1996) Anodic oxidation of ethylenediaminetetraacetic acid on platinum electrode in alkaline medium. J Electrochem Soc 143:1636–1643. doi:10.1149/1.1836691
Pera-Titus M, García-Molina V, Baños MA, Giménez J, Esplugas S (2004) Degradation of chlorophenols by means of advanced oxidation processes: a general review. Appl Catal B Environ 47:219–256. doi:10.1016/j.apcatb.2003.09.010
Prairie MR, Majumdar SA, Stange BM (1997) Oxidation of metal-EDTA complexes by TiO2 photocatalysis. Environ Sci Technol 31:3475–3481. doi:10.1021/es970226a
Ramirez JH, Duarte FM, Martins FG, Costa CA, Madeira LM (2009) Modelling of the synthetic dye Orange II degradation using Fenton’s reagent: from batch to continuous reactor operation. Chem Eng J 148:394–404
Sabhi S, Kiwi J (2001) Degradation of 2, 4-dichlorophenol by immobilized iron catalysts. Water Res 35:1994–2002. doi:10.1016/S0043-1354(00)00460-7
Siedlecka EM, Mrozik W, Kaczyński Z, Stepnowski P (2008) Degradation of 1-butyl-3-methylimidazolium chloride ionic liquid in a Fenton-like system. J Hazard Mater 154:893–900. doi:10.1016/j.jhazmat.2007.10.104
Sundstrom DW, Allen JS, Fenton SS, Salimi FE, Walsh KJ (1996) Treatment of chelated iron and copper wastes by chemical oxidation. J Environ Sci Health A 31:1215–1235. doi:10.1080/10934529609376418
Torres RA, Abdelmalek F, Combet E, Pétrier C, Pulgarin C (2007) A comparative study of ultrasonic cavitation and Fenton’s reagent for bisphenol A degradation in deionised and natural waters. J Hazard Mater 146:546–551. doi:10.1016/j.jhazmat.2007.04.056
Wang SB (2008) A comparative study of Fenton and Fenton-like reaction kinetics in decolourisation of wastewater. Dyes Pigments 76:714–720. doi:10.1016/j.dyepig.2007.01.012
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The authors thank the financial supports from Doctor Foundation of Guangdong University of Technology (No. 083013).
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Fu, F., Tang, B., Wang, Q. et al. Degradation of Ni–EDTA complex by Fenton reaction and ultrasonic treatment for the removal of Ni2+ ions. Environ Chem Lett 8, 317–322 (2010). https://doi.org/10.1007/s10311-009-0226-x
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DOI: https://doi.org/10.1007/s10311-009-0226-x