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Natural bitumens versus oil pollution in the Vlasina lake peat

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Abstract

Free and associated bitumens were isolated by sequential extraction from Vlasina lake peat (SE Serbia) and were investigated in order to differentiate between oil pollution and natural bitumens. Four peat samples were collected at different depths, on a peat island. Gas chromatographic (GC) and gas chromatography/mass spectrometry (GC/MS) analysis revealed the presence of three markedly different bitumen fractions. Here we show that the free bitumens are representing the native peat bitumens. The two associated bitumens are mainly the products of bacterial rework of organic substance, which were then trapped by two differing mechanisms. The bitumens characteristics and association features exclude a contribution of oil pollution.

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References

  • Cranwell PA (1981) Diagenesis of free and bound lipids in terrestrial detritus deposited in a lacustrine sediment. Org Geochem 3:79–89

    Article  CAS  Google Scholar 

  • Ficken KJ, Li B, Swain DL, Eglinton G (2000) An n-alkane proxy for the sedimentary input of submerged/floating freshwater aquatic macrophytes. Org Geochem 31:745–749

    Article  CAS  Google Scholar 

  • Grimalt J, Albaigés J (1987) Sources and occurrence of C12-C22 n-alkane distributions with even carbon-number preference in sedimentary environments. Geochim Cosmochim Acta 51:1379–1384

    Article  CAS  Google Scholar 

  • IHSS, International Humic Substances Society (1983) Outline of extraction procedures. In Proc 1st Int Humic Subst Soc Conf, Estes Park, Colorado USA. IHSS press

  • Jovančićević B, Vitorović D, Šaban M, Wehner H (1992) Evaluation of the effects of native minerals on the organic matter of Aleksinac oil shale based on the composition of free and bound bitumens. Org Geochem 18:511–519

    Article  Google Scholar 

  • Kaiser K, Guggenberger G (2000) The role of DOM sorption to mineral surfaces in the preservation of organic matter in soils. Org Geochem 31: 711–725

    Article  CAS  Google Scholar 

  • Khan SU, Schnitzer M (1972) The retention of hydrophobic organic compounds by humic acid. Geochim Cosmochim Acta 36:745–754

    Article  CAS  Google Scholar 

  • Lehtonen K, Ketola M (1993) Solvent-extractable lipids of Sphagnum, Carex, Bryales and Carex-Bryales peats: content and compositional features vs peat humification. Org Geochem 20:363–380

    Article  CAS  Google Scholar 

  • Lehtonen K, Hänninen K, Ketola M (2001) Structurally bound lipids in peat humic acids. Org Geochem 32:33–43

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We wish to thank to Alexander von Humboldt-Stiftung for providing GC/MS analyses. The authors gratefully acknowledge the Ministry of Sciences, Technology and Development of Republic of Serbia for supporting this research

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Correspondence to D. Đurka.

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Selected article from the Regional Symposium on Chemistry and Environment Krusevac, Serbia, June 2003, organised by Dr. Branimir Jovancicevic.

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Đurka, D., Pfendt, P., Jovančićević, B. et al. Natural bitumens versus oil pollution in the Vlasina lake peat. Environ Chem Lett 3, 39–42 (2005). https://doi.org/10.1007/s10311-005-0110-2

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  • DOI: https://doi.org/10.1007/s10311-005-0110-2

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