Abstract
We studied the photocatalytic activity of Ti-montmorillonite. The highest activity was found for a Ti/bentonite ratio of 10 mmol/g, prepared using HCl and calcined by microwaves. This mixture is less active than TiO2 P-25 for 4-chlorophenol removal in water, but more active for methanol removal in air.
Similar content being viewed by others
References
Awate S V, Suzuki K (2001) Enhanced adsorption capacity and photocatalytic oxidative activity of dyes in aqueous medium by hydrothermally treated titania pillared clay. Adsorption 7:319–326
Ding Z, Zhu HY, Lu GQ, Greenfield PF (1999) Photocatalytic properties of titania pillared clays by different drying methods. J Coll Interface Sci 209:193–199
Ilisz I, Dombi A, Mogyorosi K, Farkas A, Dékany I (2002) Removal of 2-chlorophenol from water by adsorption combined with TiO2 photocatalysis. Appl Catal B 39:247–256
Ilisz I, Dombi A, Mogyorosi K, Dékany I (2004) Photocatalytic water treatment with different TiO2 nanoparticles and hydrophilic/hydrophobic layer silicate adsorbents. Coll Surf A 230:89–97
Khalaf H, Bouras O, Perrichon V (1997) Synthesis and characterization of Al-pillared and cationic surfactant modified Al-pillared algerian bentonite. Microporous Mater 8:141–150
Ooka C, Akta S, Ohashi OY, Horiuchi T, Suzuki K, Komai S, Yoshida H, Hattori T (1999) Crystallization of hydrothermally treated TiO2 pillars in pillared montmorillonite for improvement of the photocatalytic activity. J Mater Chem 9:2943–2952
Ooka C, Yoshida H, Horio M, Suzuki K, Hattori T (2003) Adsorptive and photocatalytic performance of TiO2 pillared montmorillonite in degradation of endocrine disruptors having different hydrophobicity. Appl Catal B 41:313–321
Pichat P (2003) Photocatalytic degradation of pollutants in water and air: basic concepts and applications. In: Tarr M A (ed) Chemical degradation methods for wastes and pollutants. Dekker, New York, pp 77–119
Rajeshkumar S, Anilkumar G M, Ananthakumar S, Warrier KGK (1998) Role of drying techniques on the development of porosity in silica gels. J Porous Mater 5:59–63
Zhao J, Yang X (2003) Photocatalytic oxidation for indoor air purification: a literature review. Build Environ 38:645–654
Acknowledgements
Financial support from “Comité Mixte d’Evaluation et de Prospective de Coopération Interuniversitaire Franco-algérienne” (C.M.E.P.; project 02 MDU 556) is gratefully acknowledged. In particular, it allowed the photocatalytic activity tests to be carried out in France by D.T., M.S. and M.H.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Pichat, P., Khalaf, H., Tabet, D. et al. Ti-montmorillonite as photocatalyst to remove 4-chlorophenol in water and methanol in air. Environ Chem Lett 2, 191–194 (2005). https://doi.org/10.1007/s10311-004-0090-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10311-004-0090-7