Skip to main content

Advertisement

SpringerLink
Log in

Modelling the formation of biogenic iodine in marine aerosols

  • Original Paper
  • Published:
Environmental Chemistry Letters Aims and scope Submit manuscript

Abstract

Models for the formation of biogenic iodine in marine aerosols have been proposed in the literature. Here, we analyse the possible species and reactions that could occur in the proposed models. We calculate the enthalpies of formation for the species and the enthalpies of corresponding reactions. We propose a modified model using iodous acid (HOIO) and reactions that are particularly suited to humid conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

References

  • Bedjanian Y, Le Bras G, Poulet G (1997) Kinetics and mechanism of the IO + ClO reaction. J Phys Chem A 101:4088–4096

    Article  CAS  Google Scholar 

  • Begović N, Marković Z, Anić S, Kolar-Anić Lj (2004) Computational investigation of HIO and HIO2 isomers. J Phys Chem A 108:651–657

    Article  Google Scholar 

  • Cox JD, Wagman DD, Medvedev VA (1989) CODATA key values for thermodynamics. Hemisphere, New York

  • Gurvich LV, Veyts IV, Alcock CB (1989) Thermodynamic properties of individual substances, 4th edn. Hemisphere, New York

  • Jimenez JL, Cocker DR, Bahreini R, Zhuang H, Varutbangkul V, Flagan RC, Seinfeld JH, O’Dowd C, Hoffmann T (2003) New particle formation from photooxidation of diiodomethane (CH2I2). J Geophys Res–Atmos 108(D10):4318

    Google Scholar 

  • Láňová B, Vřešt’ál J (2002) Study of the Bray-Liebhafsky reaction by on-line mass spectrometry. J Phys Chem A 106:1228–1232

    Article  Google Scholar 

  • Mäkelä JM, Hoffmann T, Holzke C, Väkevä M, Suni T, Mattila T, Aalto PP, Tapper U, Kaupinen E, O’Dowd C (2002) Biogenic iodine emissions and identification of end-products in coastal ultrafine particles during nucleation bursts. J Geophys Res 107(D19):8110

    Google Scholar 

  • O’Dowd CD, Jimenez JL, Bahreini R, Flagan CR, Seinfeld HJ, Hämeri K, Pirjola L, Kulmala M, Jennings SG, Hoffmann T (2002) Marine aerosol formation from biogenic iodine emissions. Nature 417:632–636

    Article  CAS  PubMed  Google Scholar 

  • Ruscic B, Wagner AF, Harding LB, Asher RL, Feller D, Dixon DA, Peterson KA, Song Y, Qian X, Ng C-Y, Liu J, Chen W, Schwenke DW (2002) On the enthalpy of formation of hydroxyl radical and gas-phase bond dissociation energies of water and hydroxyl. J Phys Chem A 106:2727–2747

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The present investigations are included in the project no. 1448 “Physical chemistry of dynamic states and structures of non-equilibrium systems – self organization, multistability and oscillatority”. They are partially supported by the Ministry of Sciences, Technologies and Development of Serbia.

Author information

Authors and Affiliations

  1. Institute of General and Physical Chemistry, University of Belgrade, Studentski trg 12–16, P.O. Box 551, 11000, Belgrade, Yugoslavia

    Nebojša Begović

  2. Faculty of Science, Department of Chemistry, University of Kragujevac, Radoja Domanovi’ca 12, P.O. Box 60, 34000 , Kragujevac, Yugoslavia

    Zoran Marković

  3. University of Belgrade, Studentski trg 12–16, P.O. Box 137, 11000, Belgrade, Yugoslavia

    Slobodan Anić & Ljiljana Kolar-Anić

Authors
  1. Nebojša Begović
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zoran Marković
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Slobodan Anić
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ljiljana Kolar-Anić
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Nebojša Begović.

Additional information

Selected article from the Regional Symposium on Chemistry and Environment, Krusevac, Serbia, June 2003, organised by Dr. Branimir Jovancicevic

Rights and permissions

Reprints and permissions

About this article

Cite this article

Begović, N., Marković, Z., Anić, S. et al. Modelling the formation of biogenic iodine in marine aerosols. Environ Chem Lett 2, 65–69 (2004). https://doi.org/10.1007/s10311-004-0077-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10311-004-0077-4

Keywords

Search

Navigation