Abstract
Pyrite flotation separation and encapsulation in tailings dams is proposed as a viable way to chemically stabilize tailings. Characterization of potential acid mine generation in tailings led to an innovative process in which acid-generating pyrite is separated by flotation from the coarse tailings and incorporated into the slime zone. This creates pyrite-free neutral tailings acceptable for placement in the dyke and permanently avoids acid generation.
Zusammenfassung
Die Abtrennung und Einkapselung von Pyrit Flotationsmitteln in Schlammteichen wird als praktikabler Weg zur chemischen Stabilisierung von Abgängen vorgeschlagen. Aus der Charakterisierung der potentiellen Säurebildung in Schlammteichen führte zu einem innovativen Verfahren, bei dem säurebildender Pyrit durch Flotation aus den groben Fraktionen der Abgänge abgetrennt und in die Schlammzone eingekapselt wird. Dadurch entstehen pyritfreie, neutrale Tailings, die für die Einbringung in den Schlammteich akzeptabel sind und die Säurebildung dauerhaft unterbinden.
Resumen
La separación por flotación y el encapsulación de la pirita en las presas de colas se propone como una forma viable de estabilización química de las colas. La caracterización del potencial de generación de drenaje ácido en los relaves condujo a un proceso innovador, en el que la pirita generadora de ácido se separa por flotación de los relaves gruesos, y se incorpora a la zona de limos. Esto crea relaves neutros sin pirita aceptables para su colocación en el dique y evita permanentemente la generación de ácido.
抽象
提出一种尾矿坝内黄铁矿浮选分离并封存的化学方式稳定尾矿的可行方法。在尾矿潜在产酸特征评价之后,提出了一种新型尾矿处理方法 ,即通过浮选将产酸的黄铁矿从粗尾矿中分离再混入污泥区封存。处理后的可接受尾矿不含黄铁矿,呈中性,可永久避免产酸。
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References
ASTM D4513-11 (2017) Standard test method for particle size distribution of catalytic materials by sieving. ASTM International, West Conshohocken. http://www.astm.org
Calla-Choque D (2012) Tratamiento de los residuos del proceso Jarosita de la industria metalúrgica del zinc, con la finalidad de mitigar este pasivo ambiental. MC Thesis, National Univ of Engineering-Lima, Perú
Clesceri LS, Greenberg AE, Eaton AD (1999) Standard methods for the examination of water and wastewater. 20th edition, American Public Health Assoc, American Water Works Assoc, Water Environment Federation
Fairgray ME, Webster-Brown JG, Pope J (2019) Testing geochemical predictions of trace element toxicity and bioavailability at a rehabilitated mine site. Mine Water Environ. https://doi.org/10.1007/s10230-019-00644-y
Gabarrón M, Zornoza R, Acosta JA, Faz Á, Martínez-Martínez S (2019) Mining environments. In: Pereira P (ed) Ch 5, Advances in chemical pollution, environmental management and protection, vol 4. Elsevier, Oxford, pp 157–205
Kottek M, Grieser J, Beck C, Rudolf B, Rubel F (2006) World map of the Köppen-Geiger climate classification updated. Meteorol Z 15(3):259–263. https://doi.org/10.1127/0941-2948/2006/0130
Lottermoser BG (2010) Sulfidic mine wastes. In: Mine wastes. Springer, Berlin. https://doi.org/10.1007/978-3-642-12419-8_2
Mazzeo D, Matera N, De Luca P, Baglivo C, Maria Congedo P, Oliveti G (2020) Worldwide geographical mapping and optimization of stand-alone and grid-connected hybrid renewable system techno-economic performance across Köppen–Geiger climates. Appl Energy 276:115507.
Mongil-Manso J, Díaz-Gutiérrez V, Navarro-Hevia J, Espina M, San Segundo L (2019) The role of check dams in retaining organic carbon and nutrients. A study case in the Sierra de Ávila mountain range (Central Spain). Sci Total Environ 657:1030–1040. https://doi.org/10.1016/j.scitotenv.2018.12.087
Moslemi H, Gharabaghi M (2017) A review on electrochemical behavior of pyrite in the froth flotation process. J Ind Eng Chem 47:1–18. https://doi.org/10.1016/j.jiec.2016.12.012
Olías M, Nieto JM, Pérez-López R, Cánovas CR, Macías F, Sarmiento AM, Galván L (2016) Controls on acid mine water composition from the Iberian Pyrite Belt (SW Spain). CATENA 137:12–23. https://doi.org/10.1016/j.catena.2015.08.018
Romero FM, Armienta MA, González-Hernández G (2007) Solid-phase control on the mobility of potentially toxic elements in an abandoned lead/zinc mine tailings impoundment, Taxco, Mexico. Appl Geochem 22(1):109–127. https://doi.org/10.1016/j.apgeochem.2006.07.017
Santander M, Valderrama L (2019) Recovery of pyrite from copper tailings by flotation. J Mater Res Tech 8(5):4312–4317. https://doi.org/10.1016/j.jmrt.2019.07.041
Santos Jallath JE, Romero FM, Iturbe Argüelles R, Cervantes Macedo A, Goslinga Arenas J (2018) Acid drainage neutralization and trace metals removal by a two-step system with carbonated rocks, Estado de Mexico, Mexico. Environ Earth Sci 77(3):86. https://doi.org/10.1007/s12665-018-7248-2
Vergouw JM, Difeo A, Xu Z, Finch JA (1998) An agglomeration study of sulphide minerals using zeta-potential and settling rate. Part 1: pyrite and galena. Miner Eng 11(2):159–169. https://doi.org/10.1016/s0892-6875(97)00148-9
Wang X-H, Forssberg KSE (1991) Mechanisms of pyrite flotation with xanthates. Int J Miner Process 33(1):275–290. https://doi.org/10.1016/0301-7516(91)90058-Q
Wang L, Ji B, Hu Y, Liu R, Sun W (2017) A review on in situ phytoremediation of mine tailings. Chemosphere 184:594–600. https://doi.org/10.1016/j.chemosphere.2017.06.025
Younger PL, Banwart SA, Hedin RS (2002) Mine water hydrology, pollution, remediation. Kluwer Academic Publishers, Dordrecht
Acknowledgements
The authors thank Consulcont S.A.C. for their interest and access to their facilities and Dr. G. T. Lapidus (Universidad Autónoma Metropolitana-Iztapalapa, México) for review and enrichment of this article.
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Camero-Hermoza, P., Calla-Choque, D., Rojas-Montes, J.C. et al. Pyrite Flotation Separation and Encapsulation: A Synchronized Remediation System for Tailings Dams. Mine Water Environ 40, 74–82 (2021). https://doi.org/10.1007/s10230-021-00753-7
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DOI: https://doi.org/10.1007/s10230-021-00753-7