Abstract
A ferric sulphate solution was produced from pyritic coal tailings for potential use as a coagulant for water and wastewater treatment. Laboratory-scale leaching experiments were carried out with four tailings with different concentrations of pyrite. The tailings were characterized for: total sulphur, pyritic sulphur, sulphate sulphur, organic sulphur, and elemental analysis of carbon, hydrogen, and nitrogen. X-ray diffraction analyses were also conducted to assess the mineral composition of the samples. The leaching was carried out using a laboratory column constructed as a packed bed reactor with a closed-circuit sprinkling system. After 4 weeks of leaching, the liquor was filtered and evaporated to reach an iron concentration of about 12% w/w, which is typical of most commercial FS coagulants in Brazil.
抽象
含黄铁矿的煤矿尾矿获取的硫酸铁溶液可用作废水处理凝结剂。用含有不同黄铁矿的四种煤矿尾矿进行室内试验。用以下指标描述尾矿特征:总硫、黄铁矿形态硫、硫酸盐形态硫、有机硫和碳、氢、氮元素含量。X荧光衍射(XRD)用以评价岩样的矿物成分。室内淋滤柱为闭流循环喷水的充填床式反应器。四星期淋滤之后,滤液经过滤和蒸发浓缩至铁浓度12 % w/w,获取巴西典型的商业硫酸铁(FS)凝结剂
Zusammenfassung
Aus Pyrit-haltigen Kohlerückständen wurde eine Eisen(III)-Sulfat-Lösung für den möglichen Einsatz als Koagulationsmittel zur Wasser- und Abwasserbehandlung hergestellt. Im Labormaßstab wurden Extraktionsversuche mit vier Rückstandsproben durchgeführt, die unterschiedliche Pyritkonzentrationen aufwiesen. Die Rückstandsproben wurden untersucht auf ihren Gehalt an Gesamtschwefel, Disulfid-Schwefel, Sulfat-Schwefel, organischem Schwefel sowie mit Elementaranalyse bezüglich der Gehalte an Kohlenstoff, Wasserstoff und Stickstoff. Außerdem wurde der Mineralienbestand der Proben mit Röntgendiffraktometrie festgestellt. Die Extraktionsversuche wurden mit einer Laborsäule durchgeführt, die als Festbettreaktor mit Berieselungsanlage im geschlossenen Kreislauf konstruiert war. Nach vier Wochen Extraktionsdauer wurde der Extrakt filtriert und eingedampft, um eine Eisenkonzentration mit einem Masseanteil von ungefähr 12 % zu erreichen, welche typisch ist für die meisten kommerziell in Brasilien erhältlichen Koagulationsmittel aus Eisen(III)-Sulfat.
Resumen
Una solución de sulfato férrico fue producida a partir de relaves de carbón pirítico para su potencial uso como coagulante para agua y para tratamiento de aguas residuales. Los experimentos de lixiviación a escala de laboratorio fueron realizados con cuatro relaves con diferentes concentraciones de pirita. Los relaves fueron caracterizados por: azufre total, azufre pirítico, sulfato, azufre orgánico y análisis elemental de carbón, hidrógeno y nitrógeno. Se realizaron análisis de difracción de rayos X para conocer la composición mineralógica de las muestras. La lixiviación se realizó en una columna de laboratorio construida como un reactor de lecho compacto con un sistema de aspersión en circuito cerrado. Después de cuatro semanas de lixiviación, el lixiviado fue filtrado y evaporado hasta alcanzar una concentración de alrededor de 12% w/w, que es típico de la mayoría de los coagulantes FS en Brasil.
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The authors thank the CNPq and the Brazilian Coal Net for their financial support.
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Menezes, J.C.C.C., Colling, A.V., Silva, R.A.S. et al. Ferric Sulphate Coagulant Obtained by Leaching from Coal Tailings. Mine Water Environ 36, 457–460 (2017). https://doi.org/10.1007/s10230-017-0453-5
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DOI: https://doi.org/10.1007/s10230-017-0453-5