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Microwave Converter for High-Quality Fuel Production Applying Biochar-Combustion Gas

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Abstract

It has been conducted to develop a microwave converter for producing high-quality gas fuel by carbon-CO2 gasifying using the carbon in biomass carbide and the CO2 in combustion exhaust gas, and obtained the following results. When gasification gas was applied as a simulated combustion gas, CO2 conversion, lower heating value, and H2/CO ratio all increased as the concentrations of each component such as the amount of CO2, O2, and water vapor was increased. The same trend was also observed when the Ni-SiC portion among biochar and gasification gas temperature were high. It was found that there is a good fuel value with CO2 conversion of 56% and lower heating value of 2.6 MJ/Nm3 when the percentage of CO2: N2: O2 is 20:70:10 and the amount of water vapor is 15 mL/min by simulating gasification gas as the combustion gas, and biomass carbide is used as the percentage of Ni-SiC among biochar of 70:30 in order to increase microwave receptive energy.

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References

  1. Bastian L, Yano J, Hirai Y, Sakai SI (2013) Greenhouse gas emissions from biogenic waste treatment: options and uncertainty. J Mater Cycles Waste Manag 15:49–60. https://doi.org/10.1007/s10163-012-0087-4

    Article  Google Scholar 

  2. Lahijani P, Mohammadi M, Zainal ZA, Mohamed AR (2015) Advances in CO2 gasification reactivity of biomass char through utilization of radio frequency irradiation. Energy 93:976–983. https://doi.org/10.1016/j.energy.2015.09.092

    Article  Google Scholar 

  3. Godin J, Liu W, Ren S, Xu CC (2021) Advances in recovery and utilization of carbon dioxide: a brief review. J Environ Chem Eng 9(4):10564. https://doi.org/10.1016/j.jece.2021.105644

    Article  Google Scholar 

  4. Hunt J, Ferrari A, Lita A, Crosswhite M, Ashley B, Stiegman AE (2013) Microwave specific enhancement of the carbon-carbon dioxide (Boudouard) reaction. J Phys Chem C 117:26871–26880. https://doi.org/10.1021/jp4076965

    Article  Google Scholar 

  5. Song HG, Chun YN (2020) Microwave gasification and oxy-steam combustion for using the biomass char. J Mater Cycles Waste Manag 22:176–186. https://doi.org/10.1007/s10163-019-00926-1

    Article  Google Scholar 

  6. Chun YN, An J (2021) Development of microwave-matrix partial oxidation reformer. Int J Energy Res 11(3):1421–1429. https://doi.org/10.20508/ijrer.v11i3.12272.g8277

    Article  Google Scholar 

  7. Girarad-Sahun F, Biondo O, Trenchev G, Rooij G, Bogaerts A (2022) Carbon bed post-plasma to enhance the CO2 conversion and remove O2 from the product stream. Chem Eng J 442:136268

    Article  Google Scholar 

  8. Zhang H, Tan Q, Huang Q, Wang K, Tu X, Zhao X, Wu C, Yan J, Li X (2022) Boosting the Conversion of CO2 with Biochar to Clean CO in an Atmospheric Plasmatron: A Synergy of Plasma Chemistry and Thermochemistry. ACS Sustain Chem Eng 10:7712–7725. https://doi.org/10.1021/acssuschemeng.2c01778

    Article  Google Scholar 

  9. Lim MS, Chun YN (2016) Carbon dioxide destruction with methane reforming by a novel plasma-catalytic converter. Plasma Chem Plasma Process 36:1211–1228. https://doi.org/10.1007/s11090-016-9727-0

    Article  Google Scholar 

  10. An J, Kim HJ, Chun YN (2021) Development of partial oxidation reformer in gliding arc plasma-matrix burner. Renew Energy 163:1711–1717. https://doi.org/10.1016/j.renene.2020.10.077

    Article  Google Scholar 

  11. Calo JM, Perkins MT (1987) A heterogeneous surface model for the “steady-state” kinetics of the Boudouard reaction. Carbon 25:395–407. https://doi.org/10.1016/0008-6223(87)90011-X

    Article  Google Scholar 

  12. Lee KW, Lww WC, Lee HJ, Dong JI (2014) Gasification characteristics of sewage sludge combined with wood biomass. J Mater Cycles Waste Manag 16:642–649. https://doi.org/10.1007/s10163-014-0270-x

    Article  Google Scholar 

  13. Weissermel K, Arpe HJ (2008) Industrial organic chemistry. Wiley, Newyork

    Google Scholar 

  14. Senneca O (2007) Kinetics of pyrolysis, combustion and gasification of three biomass fuels. Fuel Process Technol 88:87–97. https://doi.org/10.1016/j.fuproc.2006.09.002

    Article  Google Scholar 

  15. Li Y, Xu Q, Li Z (2022) Hydrogen-rich gas production from sorption-enhanced sludge gasification using CaO-based biochar derived from crab shell as a CO2 sorbent. J Mater Cycles Waste Manag 24:2353–2364. https://doi.org/10.1016/j.biombioe.2020.105607

    Article  Google Scholar 

  16. Park SW, Lee JS, Yang WS, Alam MT, Seo YC, Lee SY (2018) Gasification characteristics of biomass for tar removal by secondary oxidant injection. J Mater Cycles Waste Manag. https://doi.org/10.1007/s10163-017-0642-0

    Article  Google Scholar 

  17. Menendez JA, Arenillas A, Fidalgo B, Fernandez Y, Zubizarreta L, Calvo E, Bermúdez JM (2010) Microwave heating processes involving carbon materials. Fuel Process Technol 91:1–8. https://doi.org/10.1016/j.fuproc.2009.08.021

    Article  Google Scholar 

  18. Fidalgo B, Domínguez A, Pis JJ, Menéndez JA (2008) Microwave-assisted dry reforming of methane. Int J Hydrogen Energy 33:4337–4344. https://doi.org/10.1016/j.ijhydene.2008.05.056

    Article  Google Scholar 

  19. Kong Y, Cha CY (1996) Reduction of NOx adsorbed on char with microwave energy. Carbon 34:1035–1040. https://doi.org/10.1016/0008-6223(96)00051-6

    Article  Google Scholar 

  20. Menéndez JA, Juárez-Pérez EJ, Ruisánchez E, Bermúdez JM, Arenillas A (2011) Ball lightning plasma and plasma arc formation during the microwave heating of carbons. Carbon 49:346–349. https://doi.org/10.1016/j.carbon.2010.09.010

    Article  Google Scholar 

  21. Idris A, Khalid K, Omar W (2004) Drying of silica sludge using microwave heating. Appl Therm Eng 24:905–918. https://doi.org/10.1016/j.applthermaleng.2003.10.001

    Article  Google Scholar 

  22. Bermúdez JM, Ruisánchez E, Arenillas A, Moreno AH, Menéndez JA (2014) New concept for energy storage: microwave-induced carbon gasification with CO2. Energy Convers Manage 78:559–564. https://doi.org/10.1016/j.enconman.2013.11.021

    Article  Google Scholar 

  23. Matei-Rutkovska F, Postole G, Rotaru CG, Flore M, Parvulescu VI, Gelin P (2016) Synthesis of ceria nanopowders by microwave assisted hydrothermal method for dry reforming of methane. Int J Hydrog Energy 41:2512–2525. https://doi.org/10.1016/j.ijhydene.2015.12.097

    Article  Google Scholar 

  24. Fidalgo B, Domı´nguez A, Pis JJ, Mene´ndez JA, (2008) Microwave-assisted dry reforming of methane. Int J Hydrogen Energy 33:4337–4344

    Article  Google Scholar 

  25. Fidalgo B, Ferna´ndez Y, Domı´nguez A, Pis JJ, Mene´ndez JA (2008) Microwave-assisted pyrolysis of CH4/N2 mixtures over activated carbon. J Anal Appl Pyrolysis 82:158–162

    Article  Google Scholar 

  26. Chen X, Jiang J, Li K, Tian S, Ya F (2017) Energy-efficient biogas reforming process to produce syngas: the enhanced methane conversion by O2. Appl Energy 185:687–697. https://doi.org/10.1016/j.apenergy.2016.10.114

    Article  Google Scholar 

  27. Li L, Wang H, Jiang X, Song Z, Zhao X, Ma C (2016) Microwave-enhanced methane combined reforming by CO2 and H2O into syngas production on biomass-derived char. Fuel 185:692–700. https://doi.org/10.1016/j.fuel.2016.07.098

    Article  Google Scholar 

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Acknowledgements

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2018R1D1A1B07040326).

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Correspondence to Young Nam Chun.

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Chun, Y.N., An, J. Microwave Converter for High-Quality Fuel Production Applying Biochar-Combustion Gas. J Mater Cycles Waste Manag 25, 3395–3403 (2023). https://doi.org/10.1007/s10163-023-01764-y

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