Abstract
India is considered as one of the major mercury emitters of the world. Coal combustion in power plants is the foremost source of mercury emissions. Coal samples from South Eastern Coalfield (SECL) region, India were assessed for mercury content and its partition in a 500 MW boiler unit of a coal-fired power plant. Hg content in the runoff mine coal samples varied from 0.011 to 0.188 mg/kg. The Hg content in coal was positively correlated with ash and sulfur. In the power plant, about 65% of the Hg present in the feed coal was emitted through stack, whereas the rest were associated with the fine fly ash (33%), bottom ash (1.9%), and mill rejects (0.1%).The concentration of total Hg in the stack gas varied from 8.5 to 13.7 μg/Nm3, wherein Hg0 (74–81%) was much higher than Hg2+ (19–26%). The estimated mercury emission factor was 1.0–3.2 mg/GJ, which is comparatively higher due to the use of high ash coal and the lack of flue gas desulphurisation system. Hg portioning along the flue gas hoppers were also investigated which indicates relationship between Hg adsorption and carbon/sulfur content of the fly ash.
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References
Selin NE (2009) Global biogeochemical cycling of mercury: a review. Annu Rev Environ Resour 34:43–63
Agarwalla H, Mahajan PS, Sahu D, Taye N, Ganguly B, Mhaske SB, Chattopadhyay S, Das A (2016) A switch-on NIR probe for specific detection of Hg2+ ion in aqueous medium and in mitochondria. Inorg Chem 55(22):12052–12060
Mahato P, Saha S, Das P, Agarwalla H, Das A (2014) An overview of the recent developments on Hg2+ recognition. RSC Adv 4:36140–36174
McKelvey W, Oken E (2012) Mercury and public health: an assessment of human exposure. In: Bank MS (ed) Mercury in the environment: pattern and process. University of California Press, Berkeley, pp 267–288
UNEP (2008) The global atmospheric mercury assessment: sources emissions and transport. UNEP, Geneva
Takaoka M (2015) Mercury and mercury-containing waste management in Japan. J Mater Cycles Waste Manag 17:665–672
Wang S, Luo K (2017) Atmospheric emission of mercury due to combustion of steam coal and domestic coal in China. Atmos Environ 162:45–54
Zhao S, Pudasainee D, Duan Y, Gupta R, Liu M, Lu J (2019) A review on mercury in coal combustion process: content and occurrence forms in coal, transformation, sampling methods, emission and control technologies. Prog Energy Combust Sci 73:26–64
Wu Z, Ye H, Shan Y, Chen B, Li J (2020) A city-level inventory for atmospheric mercury emissions from coal combustion in China. Atmos Environ 223:117245
Chen Q, Chen L, Li J, Guo Y, Wang Y, Wei W, Liu C, Wu J, Tou F, Wang X, Yang Y (2022) Increasing mercury risk of fly ash generated from coal-fired power plants in China. J Hazard Mater 429:128296
Chakraborty BL, Qureshi A, Vadenbo C, Hellweg S (2013) Anthropogenic mercury flows in India and impacts of emission controls. Environ Sci Technol 47(15):8105–8113
Das TB, Senapati RN, Agarwalla H (2020) Mercury in Indian thermal coals. Bull Environ Contam Toxicol 105(3):502–512
UNEP (2014) Characterization of the coal fired power sector in India, assessment of the mercury contents in coal fed to power plants and calculation of mercury emissions from the sector. UNEP Chemicals Branch, Geneva
Tewalt SJ, Bragg LJ, Finkelman RB (2001) Mercury in U.S. Coal—Abundance, Distribution, and Modes of Occurrence. USGS Fact Sheet FS-095–01. https://pubs.usgs.gov/fs/fs095-01/fs095-01.html
Yang JP, Zhao YC, Ma SM, Zhu BB, Zhang JY, Zhang CG (2016) Mercury removal by magnetic biochar derived from simultaneous activation and magnetization of sawdust. Environ Sci Technol 50:12040–12047
Zhao S, Duan Y, Chen L, Li Y, Yao T, Liu S, Liu M, Lu J (2017) Study on emission of hazardous trace elements in a 350MW coal-fired power plant. Part 1. Mercury Environ Pollut 229:863–870
Park KS, Seo YC, Lee SJ, Lee J (2008) Emission and speciation of mercury from various combustion sources. Powder Technol 180:151–156
US Environmental Protection Agency (USEPA) (2002) ICR data. Online available at: http://www.epa.gov/ttn/atw/combust/utiltox/icrdata.xls.
Noda N, Ito S (2018) Mercury partitioning in coal-fired power plants in Japan. J Jpn Inst Energy 97(11):342–347
Yokoyama T, Asakura K, Matsuda H, Ito S, Noda N (2000) Mercury emissions from a coal-fired power plant in Japan. Sci Total Environ 259:97–103
Wang X, Chen P, Jiang X, Wu Q, Liu Y, Yan J, Ma P (2017) Mercury emission characteristics of flue gases from two coal-fired power plants in Xinjiang China. Energy Sour Part A 39(2):240–245
Zhao S, Duan Y, Yao T, Liu M, Lu J, Tan H, Wang X, Wu L (2017) Study on the mercury emission and transformation in an ultra-low emission coal-fired power plant. Fuel 199:653–661
Agarwalla H, Senapati RN, Das TB (2021) Mercury emissions and partitioning from Indian coal-fired power plants. J Environ Sci 100:28–33
Qureshi A (2022) Mercury in the environment around industrially impacted locations in India: a mini-review. Bull Environ Contam Toxicol. https://doi.org/10.1007/s00128-022-03548-w
Joy A, Qureshi A (2022) Reducing mercury emissions from coal-fired power plants in India: possibilities and challenges. Ambio. https://doi.org/10.1007/s13280-022-01773-5
Kumar P, Nandi BK (2023) Assessment of combustion characteristics of high ash Indian coal, petroleum coke and their blends for cement industry using TGA. Clean Chem Eng. https://doi.org/10.1016/j.clce.2022.100091
Saini MK, Srivastava PK (2017) Effect of coal cleaning on ash composition and its fusion characteristics for a high-ash non-coking coal of India. Int J Coal prep Util 37(1):1–11
Burmistrz P, Kogut K, Marczak M, Dziok T, Górecki J (2018) Mercury in polish coking bituminous coals. Energy Fuels 32(5):5677–5683
Ghosh SB, Das MC, Roy RR, Banerjee NN (1994) Mercury in Indian coal. Indian J Chem Technol 1:237
Zajusz-Zubek E, Konieczyński J (2014) Coal cleaning versus the reduction of mercury and other trace elements’ emissions from coal combustion processes. Arch Environ Prot 40(1):115–127
Yudovich YE, Ketris MP (2005) Mercury in coal: a review: part 1. Geochem Int J Coal Geol 62(3):107–134
Zheng L, Liu G, Chou CL (2008) Abundance and modes of occurrence of mercury in some low-sulfur coals from China. Int J Coal Geol 73(1):19–26
Su Y, Liu X, Teng Y, Zhang K (2021) A preliminary study on dependence of mercury distribution on the degree of coalification in Ningwu Coalfield, Shanxi. China Energies 14(11):3119
Yudovich YE, Ketris MP (2006) Chlorine in coal: a review. Int J Coal Geol 67(1–2):127–144
Das TB, Choudhury A, Senapati RN (2015) Mercury emissions from coal fired power plants of India—case study. Int J Energy Sustain Environ Eng 2(1):21–24
Dunham GE, DeWall RA, Senior CL (2003) Fixed-bed studies of the interactions between mercury and coal combustion fly ash. Fuel Process Technol 82(2–3):197–213
Serre SD, Silcox GD (2000) Adsorption of elemental mercury on the residual carbon in coal fly ash. Ind Eng Chem Res 39(6):1723–1730
Fu B, Sun R, Yao H, Hower JC, Yuan J, Luo G, Hu H, Mardon SM, Tang Q (2021) Mercury stable isotope fractionation during gaseous elemental mercury adsorption onto coal fly ash particles: experimental and field observations. J Hazard Mater 405:124280
Hower JC, Fu B, Dai S (2020) Geochemical partitioning from pulverized coal to fly ash and bottom ash. Fuel 279:118542. https://doi.org/10.1016/j.fuel.2020.118542
Mukherjee AB, Zevenhoven R (2006) Mercury in coal ash and its fate in the Indian subcontinent: a synoptic review. Sci Total Environ 368(1):384–392
Clarke LE, Sloss LL (1992) Trace elements emissions from coal combustion and gasification. IEA Coal Res 49:110
Meij R, Vredenbregt LHJ, Winkel HT (2002) The fate and behaviour of mercury in coal-fired power plants. J Air Waste Manage 52(8):912–917
Bhangare RC, Ajmal PY, Sahu SK, Pandit GG, Puranik VD (2011) Distribution of trace elements in coal and combustion residues from five thermal power plants in India. Int J Coal Geol 86:349–356
Zhao S, Duan Y, Lu J, Liu S, Pudasainee D, Gupta R, Liu M, Lu J (2018) Enrichment characteristics, thermal stability and volatility of hazardous trace elements in fly ash from a coal-fired power plant. Fuel 225:490–498
Lopez-Anton MA, Díaz-Somoano M, Gonzalez ROM, Tarazona RM (2011) Distribution of trace elements from a coal burned in two different spanish power stations. Ind Eng Chem Res 50:12208–12216
Hower JC, Robl TL, Anderson C, Thomas GA, Sakulpitakphon T, Mardon SM, Clark WL (2005) Characteristics of coal utilization products (CUBs) from Kentucky power plants, with emphasis on mercury content. Fuel 84:1338–1350
Kostova IJ, Hower JC, Mastalerz M, Vassilev SV (2011) Mercury capture by selected Bulgarian fly ashes: influence of coal rank and fly ash carbon pore structure on carbon efficiency. Appl Geo chem 26:18–27
Hower JC, Sakulpitakphon T, Trimble AS, Thomas GA, Schram WH (2006) Major and minor element distribution in fly ash from a coal-fired utility boiler in kentucky. Energy Sour Part A 28:79–95
Li Y, Lee C, Gullett B (2002) The effect of activated carbon surface moisture on low temperature mercury adsorption. Carbon 40:65–72
Zhuang Y, Thompson JS, Zygarlicke CJ (2004) Development of a mercury transformation model in coal combustion flue gas. Environ Sci Technol 38(21):5803–5808
Chou CP, Chiu CH, Chang TC, Hsi HC (2021) Mercury speciation and mass distribution of coal-fired power plants in Taiwan using different air pollution control processes. J Air Waste Manag Assoc 71(5):553–563
Wang SX, Zhang L, Li GH, Wu Y, Hao JM, Pirrone N, Sprovieri F, Ancora MP (2010) Mercury emission and speciation of coal-fired power plants in China. Atmos Chem Phys 10(3):1183–1192
Wang Y, Duan Y, Yang L, Zhao C, Shen X, Zhang M, Zhuo Y, Chen C (2009) Experimental study on mercury transformation and removal in coal-fired boiler flue gases. Fuel Process Technol 90:643–651
Galbreath KC, Zygarlicke CJ (1996) Mercury speciation in coal combustion and gasification flue gases. Environ Sci Technol 30(8):2421–2426
Meij R, Winkel HT (2006) Mercury emissions from coal-fired power stations: the current state of the art in the Netherlands. Sci Total Environ 368(1):393–396
Zerizghi T, Guo Q, Zhao C, Okoli CP (2022) Sulfur, lead, and mercury characteristics in South Africa coals and emissions from the coal-fired power plants. Environ Earth Sci 8(4):1–15
Wang Q, Shen W, Ma Z (2000) Estimation of mercury emission from coal combustion in China. Environ Sci Technol 34(13):2711–2713
Dabrowski JM, Ashton PJ, Murray K, Leaner JJ, Mason RP (2008) Anthropogenic mercury emissions in South Africa: coal combustion in power plants. Atmos Environ 42(27):6620–6626
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Authors thankfully acknowledge Director, CSIR-Central Institute of Mining and Fuel Research, Dhanbad for his constant encouragement and support.
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HA and TBD conceived the idea, designed experiments, and drafted the manuscript. HA, RNS, MG participated in collection and analysis of samples. HA, REM, MK, VS participated in interpretation of results and final correction. All authors read and approved the final manuscript.
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Agarwalla, H., Das, T.B., Senapati, R. et al. Mercury in coal from south eastern coalfield and mercury partitioning at sub-critical coal-fired power plant. J Mater Cycles Waste Manag 25, 2632–2641 (2023). https://doi.org/10.1007/s10163-023-01679-8
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DOI: https://doi.org/10.1007/s10163-023-01679-8