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Recycling of printed circuit board e-wastes: a combined study of pyrolysis characteristics, kinetics and evolved gas analyses at various particle sizes

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Abstract

The current study aimed to determine the characteristics and kinetic parameters for the pyrolysis of printed circuit board (PCB) wastes including the analysis of evolved gases during the processes at different particle sizes. First, PCB wastes were examined using SEM–EDS, SEM-Mapping and FTIR to gain a better understanding of their structures. Then, non-isothermal TG-FTIR analyses of PCB wastes were conducted from ambient temperature to 800 °C under N2 atmosphere. The thermal decomposition of PCB wastes occurred in four stages. The second stage was determined as the main pyrolysis stage. The average apparent activation energies (Ea) of main pyrolysis stage calculated using the isoconversional methods (Friedman, Flynn–Wall–Ozawa, Kissinger–Akahira–Sunose and Starink) were in the ranges of 205–240, 144–158 and 147–161 kJ mol−1 ranges for the studied particle sizes of PCB-2 (180 μm–1.18 mm), PCB-3 (90–180 μm) and PCB-4 (63–90 μm), respectively, which pointed out an effect of particle size on Ea value conversely to a previously reported literature study. Moreover, Coats-Redfern and Criado methods confirmed each other and revealed the reaction mechanism of main pyrolysis stage as F2-2.5. Based on the evolved gas analyses, the most common emission of PCB wastes was CO2 associated with plastic, brominated compounds, polycarbonate, and epoxy resins decomposition.

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References

  1. dos Santos DM, Buzzi DC, Botelho Junior AB et al (2022) Recycling of printed circuit boards: ultrasound-assisted comminution and leaching for metals recovery. J Mater Cycles Waste Manag 24:1991–2001

    Article  Google Scholar 

  2. Ghimire H, Ariya PA (2020) E-wastes: bridging the knowledge gaps in global production budgets, composition, recycling and sustainability implications. Sustain Chem 1(2):154–182

    Article  Google Scholar 

  3. Du N, Ma H, Zhang H, Yang F, Li Z (2019) Simulation study on the heat transfer characteristics of a single printed circuit board particle in the pyrolysis process. Fuel Process Technol 192:45–56

    Article  Google Scholar 

  4. Khanna R, Ikram-Ul-Haq M, Cayumil R, Rajarao R, Sahajwalla V (2015) Novel carbon micro fibers and foams from waste printed circuit boards. Fuel Process Technol 134:473–479

    Article  Google Scholar 

  5. Stenvall E, Tostar S, Boldizar A, Foreman MRS, Möller K (2013) An analysis of the composition and metal contamination of plastics from waste electrical and electronic equipment (WEEE). Waste Manag 33:915–922

    Article  Google Scholar 

  6. Tunali M, Tunali MM, Yenigun O (2021) Characterization of different types of electronic waste: heavy metal, precious metal and rare earth element content by comparing different digestıon methods. J Mater Cycles Waste Manag 23:149–157

    Article  Google Scholar 

  7. Tuncuk A, Stazi V, Akcil A, Yazici EY, Deveci H (2012) Aqueous metal recovery techniques from e-scrap: hydrometallurgy in recycling. Miner Eng 25:28–37

    Article  Google Scholar 

  8. Jie G, Ying-Shun L, Mai-Xi L (2008) Product characterization of waste printed circuit board by pyrolysis. J Anal Appl Pyrolysis 83(2):185–189

    Article  Google Scholar 

  9. Hao J, Wang H, Chen S, Cai B, Ge L, Xia W (2014) Pyrolysis characteristics of the mixture of printed circuit board scraps and coal powder. Waste Manag 34(10):1763–1769

    Article  Google Scholar 

  10. Utetiwabo W, Yang L, Tufail MK, Zhou L, Chen R, Lian Y et al (2020) Electrode materials derived from plastic wastes and other industrial wastes for supercapacitors. Chin Chem Lett 31(6):1474–1489

    Article  Google Scholar 

  11. Liu W, Xu J, Han J, Jiao F, Qin W, Li Z (2019) Kinetic and mechanism studies on pyrolysis of printed circuit boards in the absence and presence of copper. ACS Sustain Chem Eng 7(2):1879–1889

    Article  Google Scholar 

  12. Alenezi RA, Al-Fadhli FM (2018) Thermal degradation kinetics of waste printed circuit boards. Chem Eng Res Des 130:87–94

    Article  Google Scholar 

  13. Evangelopoulos P, Kantarelis E, Yang W (2017) Experimental investigation of printed circuit boards for energy and materials recovery under nitrogen and steam atmosphere. Energy Procedia 105:986–991

    Article  Google Scholar 

  14. Zhan Z, Qiu K (2011) Pyrolysis kinetics and TG-FTIR analysis of waste epoxy printed circuit boards. J Cent South Univ Technol 18:331–336

    Article  Google Scholar 

  15. Quan C, Li A, Gao N (2009) Thermogravimetric analysis and kinetic study on large particles of printed circuit board wastes. Waste Manag 29:2353–2360

    Article  Google Scholar 

  16. Soria-Verdugo A, Morgano MT, Mätzing H, Goos E, Leibold H, Merz D, Riedel U, Stapf D (2020) Comparison of wood pyrolysis kinetics data derived from thermogravimetric experiments by model-fitting and model-free methods. Energy Convers Manag 212:112818

    Article  Google Scholar 

  17. Miura K (2002) A new and simple method to estimate f(E) and k0(E) in the distributed activation energy model from three sets of experimental data. Energy Fuels 9(2):302–307

    Article  Google Scholar 

  18. Sun J, Wang W, Liu Z, Ma Q, Zhao C, Ma C (2012) Kinetic study of the pyrolysis of waste printed circuit boards subject to conventional and microwave heating. Energies 5:3295–3306

    Article  Google Scholar 

  19. Yao Z, Xiong J, Yu S, Su W, Wu W, Tang J, Wu D (2020) Kinetic study on the slow pyrolysis of non-metal fraction of waste printed circuit boards (NMF-WPCBs). Waste Manag Res 38(8):903–910

    Article  Google Scholar 

  20. Tao R, Xing P, Li H, Cun Z, Wang C, Ma S, Sun Z (2023) Kinetics study and recycling strategies in different stages of full-component pyrolysis of spent LiNixCoyMnzO2 lithium-ion batteries. Waste Manag 155:8–18

    Article  Google Scholar 

  21. Ali L, Mousa HA, Al-Harahsheh M, Al-Zuhair S, Abu-Jdayil B, Al-Marzouqi M, Altarawneh M (2022) Removal of bromine from the non-metallic fraction in printed circuit board via its co-pyrolysis with alumina. Waste Manag 137:283–293

    Article  Google Scholar 

  22. Açıkalın K (2021) Determination of kinetic triplet, thermal degradation behaviour and thermodynamic properties for pyrolysis of a lignocellulosic biomass. Bioresour Technol 337:125438

    Article  Google Scholar 

  23. Jiang Q, Wang H, Liu J et al (2022) Nonisothermal pyrolysis kinetics of waste printed circuit boards and product characterization using TG–MS. J Mater Cycles Waste Manag 24:2151–2161

    Article  Google Scholar 

  24. Sun Y, Zhang H, Zhang F, Tao J, Cheng Z, Yan B, Chen G (2022) Pyrolysis properties and kinetics of photocured waste from photopolymerization-based 3D printing: a TG-FTIR/GC–MS study. Waste Manag 150:151–160

    Article  Google Scholar 

  25. Mao R, Shao J, Wang G, Wang F, Wang C (2022) Thermal behavior and kinetics analysis of co-combustion of petroleum coke and paper sludge-derived hydrochar. Waste Manag 153:405–414

    Article  Google Scholar 

  26. Singh V, Srivastava VC (2022) Insight into the thermal kinetics and thermodynamics of sulfuric acid plant sludge for efficient recovery of sulphur. Waste Manag 140:233–244

    Article  Google Scholar 

  27. Zhang Z, Xu G, Wang Q, Cui Z, Wang L (2019) Pyrolysis characteristics, kinetics, and evolved gas determination of chrome-tanned sludge by thermogravimetry–Fourier-transform infrared spectroscopy and pyrolysis gas chromatography-mass spectrometry. Waste Manag 93:103–137

    Article  Google Scholar 

  28. Marco I, Caballero BM, Chomón MJ, Laresgoiti MF, Torres A, Fernández G, Arnaiz S (2008) Pyrolysis of electrical and electronic wastes. J Anal Appl Pyrolysis 82:179–183

    Article  Google Scholar 

  29. Szalatkiewicz J (2014) Metal content in printed circuit board waste. Pol J Environ Stud 23(6):2365–2369

    Google Scholar 

  30. Li J, Duan H, Yu K, Liu L, Wang S (2010) Characteristic of low-temperature pyrolysis of printed circuit boards subjected to various atmosphere. Resour Conserv Recycl 54:810–815

    Article  Google Scholar 

  31. Kim YM, Kim S, Lee JY, Park YK (2013) Pyrolysis reaction pathways of waste epoxy-printed circuit board. Environ Eng Sci 30(11):706–712

    Article  Google Scholar 

  32. Gao R, Zhan L, Guo J, Xu Z (2020) Research of the thermal decomposition mechanism and pyrolysis pathways from macromonomer to small molecule of waste printed circuit board. J Hazard Mater 383:121234

    Article  Google Scholar 

  33. Yousef S, Elmontas J, Striūgas N, Zakarauskas K, Praspaliauskas M, Abdelnaby MA (2020) Pyrolysis kinetic behaviour and TG-FTIR-GC-MS analysis of metallised food packaging plastics. Fuel 282:118737

    Article  Google Scholar 

  34. Hong L, Wang B, Zhou Q (2014) Thermogravimetric analysis and kinetic study of waste printed circuit board in various atmospheres. Adv Mater Res 864–867:1929–1932

    Google Scholar 

  35. Ng CH, Salmiaton A, Hizam H (2014) Catalytic pyrolysis and a pyrolysis kinetic study of shredded printed circuit board for fuel recovery. Bull Chem React Eng Catal 9(3):224–240

    Google Scholar 

  36. Vyazovkin S, Burnham AK, Criado JM, Pérez-Maqueda LA, Popescu C, Sbirrazzuoli N (2011) ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data. Thermochim Acta 520:1–19

    Article  Google Scholar 

  37. Chiang HL, Lin KH, Lai MH, Chen TC, Ma SY (2007) Pyrolysis characteristics of integrated circuit boards at various particle sizes and temperature. J Hazard Mater 149:151–159

    Article  Google Scholar 

  38. Hao J, Wang H, Chen S, Cai B, Ge L, Xia W (2014) Pyrolysis characteristics of the mixture of printed circuit board scraps and coal powder. Waste Manag 34:1763–1769

    Article  Google Scholar 

  39. Kantarelis E, Yang W, Blasiak W, Forsgren C, Zabaniotou A (2011) Thermochemical treatment of E-waste from small household appliances using highly pre-heated nitrogen-thermogravimetric investigation and pyrolysis kinetics. Appl Energy 88:922–929

    Article  Google Scholar 

  40. Sahajwalla V, Cayumil R, Khanna R, Ikram-Ul-Haq M, Rajarao R, Mukherjee PS, Hill A (2015) Recycling polymer-rich waste printed circuit boards at high temperatures: recovery of value-added carbon resources. J Sustain Metall 1:75–84

    Article  Google Scholar 

  41. Quan C, Li A, Gao N (2012) Research on pyrolsis of PCB waste with TG-FTIR and Py-GC/MS. J Therm Anal Calorim 110:1463–1470

    Article  Google Scholar 

  42. Bi H, Wang C, Lin Q, Jiang X, Jiang C, Bao L (2021) Pyrolysis characteristics, artificial neural network modeling and environmental impact of coal gangue and biomass by TG-FTIR. Sci Total Environ 751:142293

    Article  Google Scholar 

  43. Guo Q, Yue X, Wang M, Liu Y (2010) Pyrolysis of scrap printed circuit board plastic particles in a fluidized bed. Powder Technol 198(3):422

    Article  Google Scholar 

  44. Ma C, Kumagai S, Saito Y, Kameda T, Yoshioka T (2021) Enhanced production of phenol and debromination by co-pyrolysis of the non-metallic fraction of printed circuit boards and waste tires. Green Chem 23(17):6392–6404

    Article  Google Scholar 

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Acknowledgements

This work was supported by Yıldız Technical University Scientific Research Projects Coordinator's project numbered FBA-2021-4087.

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Authors and Affiliations

  1. Department of Chemical Engineering, Yıldız Technical University, 34220, Istanbul, Turkey

    Havva Hande Cebeci & Aysel Kantürk Figen

  2. Department of Energy Systems Engineering, Yalova University, 77200, Yalova, Turkey

    Korkut Açıkalın

  3. Clean Energy Technologies Institute, Yıldız Technical University, 34220, Istanbul, Turkey

    Aysel Kantürk Figen

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  1. Havva Hande Cebeci
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  2. Korkut Açıkalın
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HHC: investigation, writing—original draft. KA: conceptualization, methodology, validation, formal analysis, writing—original draft, writing—review and editing, revision. AKF: conceptualization, resources, writing—review and editing, supervision, funding acquisition, revision.

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Correspondence to Aysel Kantürk Figen.

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Cebeci, H.H., Açıkalın, K. & Figen, A.K. Recycling of printed circuit board e-wastes: a combined study of pyrolysis characteristics, kinetics and evolved gas analyses at various particle sizes. J Mater Cycles Waste Manag 25, 2205–2221 (2023). https://doi.org/10.1007/s10163-023-01673-0

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