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Technological behaviour and leaching tests in ceramic tile bodies obtained by recycling of copper slag and MSW fly ash wastes

Abstract

The substitution of standard clays to residues, in this case copper smelter slag and fly ashes coming from the incineration process of MSW in traditional ceramics manufacturing, could suppose cost savings due to the use of recycling by-products as raw materials and reduce firing temperatures. However, these residues are considered a factor of air, soil and water contamination when its stabilization is not viable. The aim of this paper is to evaluate the feasibility of adding this residue in manufacturing of ceramic bricks, as well as tested the immobilization of Pb and As in ceramic tile bodies obtained. Water absorption, linear contraction, and bending strength have been accomplished. The decrease in water absorption with the increase of waste added was tested. The incorporation of these wastes gives rise to an increase in strength. The results showed the viability of replacing up to 40% of clay with these residues, with an improvement in the resistance of pieces compared to ceramics made without adding residues. The immobilization of As and Pb was also observed in the ceramic bodies obtained. Leaching tests show that immobilization of both elements (As and Pb) improves with increasing firing temperature.

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References

  1. 1.

    Tayibi H, Peña C, López FA, López-Delgado A (2006) Management of MSW in Spain and recovery of packaging steel scrap. Waste Manag 27:1655–1665

    Article  Google Scholar 

  2. 2.

    Costi P, Minciardi R, Robba M, Rovatti M, Sacile R (2004) An environmentally sustainable decision model for urban solid waste management. Waste Manag 24:277–295

    Article  Google Scholar 

  3. 3.

    Dondi M, Marsigli M, Fabbri B (1997) Recycling of industrial and urban wastes in brick production—a review. Tile Brick Int 1997(13):218–315

    Google Scholar 

  4. 4.

    Hernández-Crespo MS, Rincón JM (2001) New porcelainized stoneware materials obtained by recycling of MSW incinerator fly ashes and granite sawing residues. Ceram Int 27:713–720

    Article  Google Scholar 

  5. 5.

    Montero MA, Jordán MM, Hernández-Crespo MS, Sanfeliu T (2009) The use of sewage sludge and marble residues in the manufacture of ceramic tile bodies. Appl Clay Sci 46:404–408

    Article  Google Scholar 

  6. 6.

    Zhang L (2013) Production of bricks from waste materials: a review. Constr Build Mater 47:643–655

    Article  Google Scholar 

  7. 7.

    Nazer A, Payá J, Borrachero MV, Monzó J (2016) Caracterización de escorias de cobre en fundiciones chilenas. Revista de Metalurgia 52(4):e083

    Article  Google Scholar 

  8. 8.

    Shi C, Meyer C, Rivera M, Frias M, Martín F (2008) Utilization of copper slag in cement and concrete. Resour Conserv Recy 52(10):115–1120

    Article  Google Scholar 

  9. 9.

    Murari K, Sissique R, Jain KK (2015) Use of waste copper slag. A sustainable material. J Mater Cycles Wastes 17(1):13–26

    Article  Google Scholar 

  10. 10.

    Nazer A, Pavez O, Toledo I (2013) Effect of type of cement in the mechanical strength of copper slags mortars. Revista Escola de Minas 66(1):85–90

    Article  Google Scholar 

  11. 11.

    Thomas BS, Grupta RC (2013) Mechanical properties and durability chracteristics of concrete containing solid waste materials. J Clean Prod 1–6. https://doi.org/10.1016/j.jclepro.2013.11.019

  12. 12.

    Jun-wei S (2013) Study of the effect of copper slag admixtures to properties and structure of concrete. Inform Technol J 12(23):7396–7400

    Article  Google Scholar 

  13. 13.

    Piatak NM, Parsons MB, Seal RR II (2015) Characteristics and environmental aspects of slag: a review. Appl Geochem 57:236–266

    Article  Google Scholar 

  14. 14.

    Glasser FP (1997) Fundamental aspect on cement solidification and stabilization. J Hazard Mater 52:151–170

    Article  Google Scholar 

  15. 15.

    Conner JR, Goñi S, Guerrero A, Fernández E (1999) The history of stabilization/solidification technologies. Environ Sci Technol 28(4):325–396

    Article  Google Scholar 

  16. 16.

    Hauser A (2000) Abfallstoffe und ihre Möglichkeiten, Rohmaterialien in Kalksandsteinen zu ersetzen. Waste materials and the possible ways they can replace primary raw materials in sand-lime bricks. ZKG Int 53:534–543

    Google Scholar 

  17. 17.

    Dondi M, Ercolani G, Guarini G, Raimondo M (2002) Orimulsion fly ash in clay bricks. Part 1: composition and thermal behaviour of ash. J Eur Ceram Soc 22:1729–1735

    Article  Google Scholar 

  18. 18.

    Zweben C (1991) Ceramic matrix composites mechanical properties and test methods. Ceram Eng Sci Proc 12(1–2):409–503

    Google Scholar 

  19. 19.

    Jordán MM, Boix A, Sanfeliu T, de la Fuente C (1995) The mineralogy of Cretaceous clays in Castellon and their application in the ceramic industry. Int Ceram J 10:25–29

    Google Scholar 

  20. 20.

    González-García F, Romero-Acosta V, García Ramos G, González Rodríguez M (1990) Firing transformations of mixtures of clays containing illite, kaolinite and calcium carbonate used by ornamental tile industries. Appl Clay Sci 5:361–375

    Article  Google Scholar 

  21. 21.

    Jordán MM, Boix A, Sanfeliu T, de la Fuente C (1999) Firing transformations of cretaceous clays used in the manufacturing of ceramic tiles. Appl Clay Sci 14:225–234

    Article  Google Scholar 

  22. 22.

    Jordán MM, Almendro MB, Romero M, Rincón JM (2006) Application of sewage sludge in the manufacturing of ceramic tile bodies. Appl Clay Sci 30:219–224

    Article  Google Scholar 

  23. 23.

    Tay JH, Show KY (1992) Utilization of municipal wastewater sludge as building and construction materials. Resour Conserv Recycl 21:192–2004

    Google Scholar 

  24. 24.

    UNE-EN ISO 10545-3:2018. Ceramic tiles—part 3: determination of water absorption, apparent porosity, apparent relative density and bulk density (ISO 10545-3:2018)

  25. 25.

    UNE-ENVI 12506: 2001. Characterization of waste. Analysis of eluates. Determination of pH, As, Cd, Cr (VI), Cu, Ni, Pb, Zn, Cl; NO2, SO42−(ENV 13370:2001)

  26. 26.

    Weng CH, Lin DF, Chiang PC (2003) Utilization of sludge as brick materials. Adv Environ Res 7:679–685

    Article  Google Scholar 

  27. 27.

    Quijorna N, San Miguel G, Andres A (2011) Incorporation of Waelz slag into commercial ceramic bricks: a practical example of industrial ecology. Ind Eng Chem Res 50(9):5806–5814

    Article  Google Scholar 

  28. 28.

    VROM (1999) Dutch ministry of housing, spatial planning and the environment. Building materials decree. In: Building materials decree: an example of a Dutch regulation based on the potential impact of materials on the environment. Waste Management 21:295–302 (2001)

  29. 29.

    Commission Directive 2005/31/EU of 29 April 2005 amending Directive 84/500/EEC as regards a declaration of compliance and performance criteria of the analytical methods for ceramic articles intended to come in contacts with foodstuffs. https://eur-lex.europa.eu/legal-content/EN/TXT/?uri=celex:32005L0031&print=true

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Correspondence to Manuel Miguel Jordán.

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Jordán, M.M., Montero, M.A. & Pardo-Fabregat, F. Technological behaviour and leaching tests in ceramic tile bodies obtained by recycling of copper slag and MSW fly ash wastes. J Mater Cycles Waste Manag 23, 707–716 (2021). https://doi.org/10.1007/s10163-020-01162-8

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Keywords

  • Copper slag
  • Fly ashes
  • Leaching tests
  • Clays
  • Ceramic tiles
  • Recycling
  • Ceramic behaviour