Abstract
Thermolysis of Waste Engine oil (WEO) was performed in a semi-batch reactor in the temperature range of 450–575 °C. The highest yield of pyrolytic oil was obtained (76.73%) at 550 °C temperature. The comparative study between the thermogravimetric analysis (TGA) and pyrolysis experiment disclosed that the conversion of WEO was 99.34% in TGA and 98.23% in pyrolysis experiment. The fuel properties such as density (795 g cc−1), calorific value (42.40 MJ kg−1), and flash point (33 °C) of the pyrolytic oil were less compared to petrol. The decrease in the concentration of Ca, Fe, Mg, Ni, Pb, As, Mn, Zn, and Cu in the pyrolytic oil compared to WEO was perceived. The transformation in the chemical compositions in the pyrolytic oil during the course of pyrolysis was noticed. The pyrolytic oil had a composition of 38% aromatics, 32.97% alkanes, 7.97% cyclo-alkanes, 11.9% alkenes, and 4.78% poly-aromatic hydrocarbons compounds was lower than that of WEO. The WEO pyrolytic oil was containing 65% of gasoline ranged hydrocarbon compounds (C9–C12) along with 24.53% of kerosene (C11–C15), 7.47% of diesel (C15–C19), and 15.32% of heavy fuel oil (˃ C19).
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Julius I, Sunny I, Michael OD, Peter O, Izak JVDW, Samuel EO (2018) Pyrolytic conversion of used tyres to liquid fuel: characterization and effect of operating conditions. J Mater Cycles Waste Manag 20:1273–1285. https://doi.org/10.1007/s10163-017-0690-5
Sakai S, Noma Y, Kida A (2007) End-of-life vehicle recycling and automobile shredder residue management in Japan. J Mater Cycles Waste Manag 9:151–158. https://doi.org/10.1007/s10163-007-0180-2
Arora N, Kapur Bakshi S, Bhattacharjya S (2019) Framework for sustainable management of end-of-life vehicles management in India. J Mater Cycles Waste Manag 21:79–97. https://doi.org/10.1007/s10163-018-0771-0
Ni F, Chen M (2015) Research on ASR in China and its energy recycling with pyrolysis method. J Mater Cycles Waste Manag 17:107–117. https://doi.org/10.1007/s10163-014-0232-3
Joung HT, Cho SJ, Seo YC, Kim WH (2007) Status of recycling end-of-life vehicles and efforts to reduce automobile shredder residues in Korea. J Mater Cycles Waste Manag 9:159–166. https://doi.org/10.1007/s10163-007-0181-1
Osman DI, Attia SK, Taman AF (2018) Recycling of used engine oil by different solvent. Egypt J Pet 27:221–225. https://doi.org/10.1016/j.ejpe.2017.05.010
Hamad D, Al-zubaidy E, Fayed ME (2005) Used lubricating oil recycling using hydrocarbon solvent. J Environ Manag 74:153–159. https://doi.org/10.1016/j.jenvman.2004.09.002
Abdel-Jabbar NM, Al Zubaidy EAH, Mehrvar M (2010) Waste lubricating oil treatment by adsorption process using different adsorbents. World Acad Sci Eng Technol 14:24–28
Danane F, Ahmia A, Bakiri A, Lalaoui N (2014) Experimental regeneration process of used motor oils. Rev Energ Renouv 17:345–351
Kupareva A, Arvela PM, Murzin DY (2013) Technology for re-refining used lube oils applied in Europe: a review. J Chem Technol Biotechnol 88:1780–1793. https://doi.org/10.1002/jctb.4137
Durrani HA (2014) Re-refining recovery methods of used lubricating oil. I J Eng Sci Rec Tech 3:1216–1220 (ISSN: 2277-9655)
Arpa O, Yumrutas R, Demirbas A (2010) Desulfurization of diesel-like fuel produced from waste lubrication oil and its utilization on engine performance and exhaust emission. Appl Eng 87:122–127. https://doi.org/10.1016/j.applthermaleng.2013.04.035
Arpa O, Yumrutas R, Kaska O (2013) Production of diesel-like fuel from waste engine oil by pyrolytic distillation. Appl Therm Eng 58:374–381. https://doi.org/10.1016/j.apenergy.2009.05.042
Lam SS, Russell AD, Lee CC, Chase HA (2012) Microwave-heated pyrolysis of waste automotive engine oil: influence of operation parameters on the yield, composition, and fuel properties of pyrolysis oil. Fuel 92:327–339. https://doi.org/10.1016/j.fuel.2011.07.027
Nerın C, Domeno C, Moliner R, Lazaro MJ, Valderrama J (2000) Behaviour of different industrial waste oils in a pyrolysis process: metals distribution and valuable products. J Anal Appl Pyrol 55:171–183. https://doi.org/10.1016/S0165-2370(99)00097-2
Kim SS, Kim SH (2000) Pyrolysis kinetics of waste automobile lubricating oil. Fuel 79:1943–1949. https://doi.org/10.1016/S0016-2361(00)00028-4
Kim SS, Chunb BH, Kim SH (2003) Non-isothermal pyrolysis of waste automobile lubricating oil in a stirred batch reactor. Chem Eng J93:225–231. https://doi.org/10.1016/S1385-8947(02)00262-0
Shadangi KP, Mohanty K (2014) Kinetic Study and thermal analysis of the pyrolysis of non-edible seed powders by thermogravimetric and differential scanning calorimetric analysis. Renew Energy 64:337–344. https://doi.org/10.1016/j.renene.2013.09.039
Gomez-Rico MF, Martrin-Gullon I, Fullana A, Conesa JA, Font R (2003) Pyrolysis and combustion kinetics and emissions of waste lube oils. J Anal Appl Pyrolysis 68:527–546. https://doi.org/10.1016/S0165-2370(03)00030-5
Singh RK, Shadangi KP (2011) Liquid fuel from castor seeds by pyrolysis. Fuel 90:2538–2544. https://doi.org/10.1016/j.fuel.2011.03.015
Lin J, Sun S, Ma R, Fang L, Zhang P, Qu J, Zhang X, Geng H, Huang X (2018) Characteristics and reaction mechanism of sludge-derived bio-oil produced through microwave pyrolysis at different temperatures. Energy Convers Manag 160:403–410. https://doi.org/10.1016/j.enconman.2018.01.060
Kutowy O, Tweddle TA, Hazlett JD (1989) Method for the molecular filtration of predominantly aliphatic liquids, US Patent 4,814,088, assigned to National Research Council of Canada
Acid value (2019). https://en.wikipedia.org/wiki/Acid_value. Accessed 8 Jan 2019
Bunt JR, Waanders FB (2010) Trace element behavior in the Sasol-Lurgi fixed-bed dry-bottom gasifier. Part 3—The non-volatile elements: Ba Co, Cr, Mn, and V. Fuel 89:537–548. https://doi.org/10.1016/j.fuel.2009.04.018
Bunt JR, Waanders FB (2009) Trace element behavior in the Sasol-Lurgi MK IV FBDB gasifier. Part 2—The semi-volatile elements: Cu, Mo, Ni and Zn. Fuel 88:961–969. https://doi.org/10.1016/j.fuel.2008.10.041
Tafur-Marinos JA, Ginepro M, Pastero L, Torazzo A, Paschetta E, Fabbri D, Zelano V (2014) Comparison of inorganic constituents in bottom and fly residues from pelletised wood pyrogasification. Fuel 119:157–162. https://doi.org/10.1016/j.fuel.2013.11.042
Jiang Y, Ameh A, Lei M, Duan L, Longhurst P (2016) Solid–gaseous phase transformation of elemental contaminants during the gasification of biomass. Sci Total Environ 563:724–730. https://doi.org/10.1016/j.scitotenv.2015.11.017
Cui H, Turn SQ, Keffer V, Evans D, Tran T, Foley M (2013) Study on the fate of metal elements from biomass in a bench-scale fluidized bed gasifier. Fuel 108:1–12. https://doi.org/10.1016/j.fuel.2011.07.029
Lam SS, Liew RK, Cheng CK, Chase HA (2015) Catalytic microwave pyrolysis of waste engine oil using metallic pyrolysis char. Appl Catal B 176–177:601–617. https://doi.org/10.1016/j.apcatb.2015.04.014
Lam SS, Russell AD, Lee CL, Lam SK, Chase HA (2012) Production of hydrogen and light hydrocarbons as a potential gaseous fuel from microwave-heated pyrolysis of waste automotive engine oil. Int J Hydrog Energy 37:5011–5021. https://doi.org/10.1016/j.ijhydene.2011.12.016
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Patel, N., Shadangi, K.P. Thermochemical conversion of waste engine oil (WEO) to gasoline-rich crude oil. J Mater Cycles Waste Manag 22, 536–546 (2020). https://doi.org/10.1007/s10163-019-00948-9
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DOI: https://doi.org/10.1007/s10163-019-00948-9