Abstract
Slow pyrolysis is characterized by a low heating rate and high reaction time. The products are bio-char, bio-oil and bio-gas. In bio-oil, there are a variety of chemical compounds. Leading aromatic chemicals such as furfural, creosol and catechol were a focus of this study. In non-catalytic conditions, the slow pyrolysis temperature was 350, 400, 450, 500, and 550 °C. The experiment was conducted in catalytic condition using ZSM-5 catalyst to produce more aromatic chemicals. In this research the slow pyrolysis experiment was conducted in non-catalytic and catalytic conditions. In non-catalytic condition, a large amount of bio-oil was produced at 500 °C. The peak area of furfural, which is a valuable organic chemical, was highest value at 400 °C. In the catalytic condition the temperature was fixed at 400, and 500 °C. The result analysis evaluated the mass yield of bio-oil and GC–MS data for quantitative and qualitative analysis.
Similar content being viewed by others
References
Kim B, Gulati I, Park J, Shin J (2012) Pretreatment of cellulosic waste sawdust into reducing sugars using mercerization and etherification. Bioresources 7:5152–5166
Park S, Lee M, Park J (2013) CO2 (Carbon dioxide) fixation by applying new chemical absorption-precipitation methods. Energy 59:737–742
French R, Czernik S (2010) Catalytic pyrolysis of biomass for biofuels production. Fuel Process Technol 91:25–32
Huber GW, Iborra S, Corma A (2006) Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. Chem Rev 106:4044–4098
Park J, Lee Y, Ryu C, Park Y (2014) Slow pyrolysis of rice straw: analysis of products properties, carbon and energy yields. Bioresour Technol 155:63–70
Bridgwater AV, Peacocke GVC (2000) Fast pyrolysis processes for biomass. Renew Sustain Energy Rev 4:1–73
Wannapeera J, Fungtammasan B, Worasuwannarak N (2011) Effects of temperature and holding time during torrefaction on the pyrolysis behaviors of woody biomass. J Anal Appl Pyrol 92:99–105
Jahirul MI, Rasul MG, Chowdbury AA, Ashwath N (2012) Biofuels production through biomass pyrolysis—a technological review. Energies 5:4952–5001
Putun E (2010) Catalytic pyrolysis of biomass: effects of pyrolysis temperature, sweeping gas flow rate and MgO catalyst. Energy 35:2761–2766
Vitolo S, Seggiani M, Frediani P, Ambrosini G, Politi L (1999) Catalytic upgrading of pyrolytic oils to fuel over different zeolites. Fuel 78:1147–1159
Xiang Z, Runge T (2014) Co-production of feed and furfural from dried distillers’ grains to improve corn ethanol profitability. Ind Crop Prod 55:207–216
Mansilla HD, Baeza J, Urzua S, Maturana G, Villasenor J, Duran N (1998) Acid-catalysed hydrolysis of rice hull: evaluation of furfural production. Bioresour Technol 66:189–193
Foster AJ, Jae J, Cheng Y, Huber GW, Lobo RF (2012) Optimizing the aromatic yield and distribution from catalytic fast pyrolysis of biomass over ZSM-5. Appl Catal A Gen 423–424:154–161
Tanabe K, Holderich WF (1999) Industrial application of solid acid-base catalysts. Appl Catal A Gen 181:399–434
Zhang H, Luo M, Xiao R, Shao S, Jin B, Xiao G, Zhao M, Liang J (2013) Catalytic conversion of biomass pyrolysis-derived compounds with chemical liquid deposition (CLD) modified ZSM-5. Bioresour Technol 155:57–62
Giannakopoulou K, Lukas M, Vasiliev A, Brunner C, Schnitzer H (2010) Conversion of rapeseed cake into bio-fuel in a batch reactor: effect of catalytic vapor upgrading. Microporous Mesoporous Mater 128:126–135
Jacobson K, Maheria KC, Dalai AK (2013) Bio-oil valorization: a review. Renew Sustain Energy Rev 23:91–106
Farneth WE, Gorte RJ (1995) Methods for characterizing zeolite acidity. Chem Rev 95:615–635
Lin T, Kuo C (2012) Study of products yield of bagasse and sawdust via slow pyrolysis and iron-catalyze. J Anal Appl Pyrol 96:203–209
Sınağ A, Uskan B, Gülbay S (2011) Detailed characterization of the pyrolytic liquids obtained by pyrolysis of sawdust. J Anal Appl Pyrol 90:48–52
Channiwala SA, Parikh PP (2002) A unified correlation for estimating HHV of solid, liquid and gaseous fuels. Fuel 81:1051–1063
Chaiwong K, Kiatsiriroat T, Vorayos N, Thararax C (2013) Study of bio-oil and bio-char production from algae by slow pyrolysis. Biomass Bioenergy 56:600–606
Smets K, Roukaerts A, Czech J, Reggers G, Schreurs S, Carleer R, Yperman J (2013) Slow catalytic pyrolysis of rapeseed cake: product yield and characterization of the pyrolysis liquid. Biomass Bioenergy 57:180–190
Wang Z, Cao J, Wang J (2009) Pyrolytic characteristics of pine wood in a slowly heating and gas sweeping fixed-bed reactor. J Anal Appl Pyrol 84:179–184
Yorgun S, Senoz S, Kockar OM (2001) Characterization of the pyrolysis oil produced in the slow pyrolysis of sunflower-extracted bagasse. Biomass Bioenergy 20:141–148
Cornelia V, Mihai B, Hristea D, Georgeta C (2010) Effect of some environmentally degradable materials on the pyrolysis of plastics II: influence of cellulose and lignin on the pyrolysis of complex mixtures. J Mater Cycles Waste Manag 12:147–153
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kim, E., Gil, H., Park, S. et al. Bio-oil production from pyrolysis of waste sawdust with catalyst ZSM-5. J Mater Cycles Waste Manag 19, 423–431 (2017). https://doi.org/10.1007/s10163-015-0438-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10163-015-0438-z