Abstract
Zirconium was loaded onto orange waste, a cheap and available agricultural waste in Japan, to investigate the feasibility of its utilization for phosphorus recovery from secondary effluent and side-stream liquid, which contain 5.9 and 68.2 mg/dm3 phosphorus, respectively. The phosphorus removal from side-stream liquid by using zirconium-loaded saponified orange waste (Zr-SOW) gel increased with an increasing solid/liquid ratio, and it was found that Zr-SOW gel showed better performance than zirconium ferrite. The prepared adsorbent was effective for phosphorus removal and exhibited a reasonably high adsorption capacity, twice than that of zirconium ferrite. The secondary effluent was treated in a column packed with Zr-SOW gel, and an dynamic adsorption capacity of 1.3 mol-P/kg was attained. The adsorbed phosphorus from the column was successfully eluted as a concentrated form by using a small amount of 0.2 M NaOH. Throughout the elution process, zirconium was not leaked from the adsorption gel.
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References
Nowack B, Stone AT (2006) Competitive adsorption of phosphate and phosphonates onto goethite. Water Res 40:2201–2209
Kuroda A, Takiguchi N, Kato J, Ohtake H (2005) Development of technologies to conserve phosphorus resources in response to the phosphate crisis. J Environ Biotechnol 4:87–94 (in Japanese)
Shu L, Schneider P, Jegatheesan V, Johnson J (2006) An economic evaluation of phosphorus recovery as struvite from digester supernatant. Biores Technol 97:2211–2216
European Fertilizer Manufacturers Association (2000) Phosphorus essential element for food production. pp 9–10
Gong G, Ye S, Tian Y, Wang Q, Ni J, Chen Y (2009) Preparation of a new sorbent with hydrated lime and blast furnace slag for phosphorus removal from aqueous solution. J Hazard Mater 166:714–719
Ou E, Zhou J, Mao S, Wang J, Xia F, Min L (2007) Highly efficient removal of phosphate by lanthanum-doped mesoporous SiO2. Colloids Surf A Physicochem Eng Asp 308:47–53
Inoue A, Seike Y, Okumura M (2008) A simple determination of inorganic phosphorous compounds in environmental water based on their collection and separation using zirconium-loaded activated carbon. Bunseki Kagaku 57:599–604 (in Japanese)
Lugo-Lugo V, Hernández-López S, Barrera-Díaz C, Ureña-Núñez F, Bilyeu B (2009) A comparative study of natural, formaldehyde-treated and copolymer-grafted orange peel for Pb(II) adsorption under batch and continuous mode. J Hazard Mater 161:1255–1264
Biswas BK, Inoue K, Ghimire KN, Ohta S, Harada H, Ohto K, Kawakita H (2007) The adsorption of phosphate from an aquatic environment using metal-loaded orange waste. J Colloid Interf Sci 312:214–223
Cotton FA, Wilkinson G, Murillo CA, Bochmann M (1999) Advanced inorganic chemistry, 6th edn. Wiley, Singapore
Perin DD, Dempsy B (1975) Buffers for pH and metal ion control. Chapman & Hall, London
Duenas JF, Alonso JR, Rey AF, Ferrer AS (2003) Characterisation of phosphorous forms in wastewater treatment plants. J Hazard Mater 97:193–205
Medvidović NV, Perić J, Trgo M, Mužek MN (2007) Removal of lead ions by fixed bed of clinoptilolite—the effect of flow rate. Micropor Mesopor Mater 105:298–304
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This study was conducted with financial support from the Ministry of the Environment, Japan.
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Ohura, S., Harada, H., Biswas, B.K. et al. Phosphorus recovery from secondary effluent and side-stream liquid in a sewage treatment plant using zirconium-loaded saponified orange waste. J Mater Cycles Waste Manag 13, 293–297 (2011). https://doi.org/10.1007/s10163-011-0029-6
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DOI: https://doi.org/10.1007/s10163-011-0029-6