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Phosphorus recovery from secondary effluent and side-stream liquid in a sewage treatment plant using zirconium-loaded saponified orange waste

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Abstract

Zirconium was loaded onto orange waste, a cheap and available agricultural waste in Japan, to investigate the feasibility of its utilization for phosphorus recovery from secondary effluent and side-stream liquid, which contain 5.9 and 68.2 mg/dm3 phosphorus, respectively. The phosphorus removal from side-stream liquid by using zirconium-loaded saponified orange waste (Zr-SOW) gel increased with an increasing solid/liquid ratio, and it was found that Zr-SOW gel showed better performance than zirconium ferrite. The prepared adsorbent was effective for phosphorus removal and exhibited a reasonably high adsorption capacity, twice than that of zirconium ferrite. The secondary effluent was treated in a column packed with Zr-SOW gel, and an dynamic adsorption capacity of 1.3 mol-P/kg was attained. The adsorbed phosphorus from the column was successfully eluted as a concentrated form by using a small amount of 0.2 M NaOH. Throughout the elution process, zirconium was not leaked from the adsorption gel.

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Acknowledgments

This study was conducted with financial support from the Ministry of the Environment, Japan.

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Correspondence to Hiroyuki Harada.

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Ohura, S., Harada, H., Biswas, B.K. et al. Phosphorus recovery from secondary effluent and side-stream liquid in a sewage treatment plant using zirconium-loaded saponified orange waste. J Mater Cycles Waste Manag 13, 293–297 (2011). https://doi.org/10.1007/s10163-011-0029-6

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  • DOI: https://doi.org/10.1007/s10163-011-0029-6

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