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Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates

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Abstract

The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN), poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution, -the PANI-PSAN films, however, maintain the stability for 20 min in the same condition because the solubility of PSAN in alkali solutions is much higher than that of PCAN. The electrochemical properties of the SA films are determined, and the film-CdS composites formed in situ are also reported.

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Authors and Affiliations

  1. College of Chemical Engineering & Materials Science, Beijing Institute of Technology, Beijing, 100081, China

    Miao-miao Xiao, Bin Tong, Wei Zhao, Jian-bing Shi, Yue-xiu Pan, Jin-bo Shen & Yu-ping Dong  (董宇平)

  2. College of Science, Beijing Institute of Technology, Beijing, 100081, China

    Jun-ge Zhi

Authors
  1. Miao-miao Xiao
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  2. Bin Tong
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  3. Wei Zhao
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  4. Jian-bing Shi
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  5. Yue-xiu Pan
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  6. Jin-bo Shen
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  7. Jun-ge Zhi
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  8. Yu-ping Dong  (董宇平)
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Corresponding author

Correspondence to Yu-ping Dong  (董宇平).

Additional information

This work was financially supported by the National Natural Science Foundation of China (Nos. 20474007, 20634020), the Specialized Research Fund for the Doctoral Program of High Education of China (No. 20050007018) and Basic research foundation of Beijing Institute of Technology.

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Xiao, Mm., Tong, B., Zhao, W. et al. Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates. Chin J Polym Sci 28, 331–336 (2010). https://doi.org/10.1007/s10118-010-9014-0

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  • DOI: https://doi.org/10.1007/s10118-010-9014-0

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