Abstract
Biomass gasification is the thermo-chemical conversion of biomass into producer gas. The latter can be then integrated in a combined heat and power unit or chemically converted into biofuels. Tar formation during biomass gasification is the main process disadvantage. Tar leads to fouling and clogging problems in the process, in addition to catalyst deactivation when production of chemicals is envisaged. Eliminating tar from the producer gas forms the trigger point for any further valorization. This work hence evaluates the efficiency of wet scrubbers on tar removal from producer gas, based on simulations conducted using Aspen Plus. Wet scrubbers are highly efficient tar removal methods suitable for small scale gasifiers and having a low cost. Two scrubbers are placed in series to increase the tar removal efficiency. The tar reduction efficiency is assessed function of the scrubbing liquid: rapeseed methyl ester and water. Sensitivity studies handling the variation of the liquid to gas ratio and the scrubbing liquid temperature were conducted to study their impact on the tar removal efficiency. Results showed that increasing the liquid to gas ratio and decreasing the scrubbing liquid temperature leads to higher tar removal efficiencies. However, the conducted economic analysis indicated that the operational cost increases as well. A balance between the non-aqueous scrubbing liquid higher tar removal efficiencies with lower utilities cost and the actual liquid cost makes water an alternative scrubbing liquid choice. Finally, the selection of the optimal conditions depends mainly on the required tar limit set for the producer gas application.
Graphic abstract
![](http://media.springernature.com/lw685/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Figa_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Fig7_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Fig8_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Fig9_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-021-02189-7/MediaObjects/10098_2021_2189_Fig10_HTML.png)
Similar content being viewed by others
Availability of data and material
The authors declare the availability of data and material is appeared as it is shown in this manuscript.
References
Amaral AF, Previtali D, Dell’Angelo A, Bisotti F, Di Pretoro A, Andoglu E, Colombo S, Manenti F (2019) Methanol production from biomass gasification: techno-economic assessment of different feedstocks. Chem Eng Trans 74:1237–1242. https://doi.org/10.3303/CET1974207
Anis S, Zainal ZA (2011) Tar reduction in biomass producer gas via mechanical, catalytic and thermal methods: a review. Renew Sustain Energy Rev 15(5):2355–2377. https://doi.org/10.1016/j.rser.2011.02.018
Bergman PCA., Paasen SVB van, Boerrigter H. (2002) The novel “OLGA” technology for complete tar removal from biomass producer gas. 10.
Boerrigter H, van Paasen SVB, Bergman PCA, Könemann JW, Emmen R, Wijnands A (2005) “OLGA” tar removal technology: Proof of-concept for application in integrated biomass gasification combined heat and power (CHP) systems. ECN Biomass, 58
Brandt P, Henriksen U (2000) Decomposition of tar in gas from updraft gasifier by thermal cracking. 4
Caprariis B, de Filippis PD, Hernandez AD, Petrullo A, Scarsella M, Verdone N (2017) Use of low cost natural materials for tar abatement process. Chem Eng Trans 57:91–96. https://doi.org/10.3303/CET1757016
Chen, S., Zhao, K., & Tang, Y. (2015). Modeling of Biodiesel Production from Rape-Seed Oil and Methanol. Proceedings of the 2015 International Symposium on Energy Science and Chemical Engineering. 2015 International Symposium on Energy Science and Chemical Engineering, Guangzhou City, China. https://doi.org/10.2991/isesce-15.2015.70
Eau de Paris. (2020). Une eau au juste prix—Eau de Paris. http://www.eaudeparis.fr/leau-au-quotidien/une-eau-au-juste-prix/
de Lasa H, Salaices E, Mazumder J, Lucky R (2011) Catalytic Steam Gasification of Biomass: Catalysts. Thermodynamics and Kinetics Chemical Reviews 111(9):5404–5433. https://doi.org/10.1021/cr200024w
DeVincentis, J. (2008). Aspen Plus Biodiesel Model. Aspen Technology, 13
Eurostat. (2021). Electricity prices for non-household consumers—Bi-annual data (from 2007 onwards) (Statistical NRG_PC_205). https://ec.europa.eu/eurostat/statistics-explained/index.php/Electricity_price_statistics#Electricity_prices_for_non-household_consumers
Gateau P, Van Dievoet F, Bouillon V, Vermeersch G, Claude S, Staat F (2005) Environmentally friendly properties of vegetable oil methyl esters. Oléagineux, Corps Gras, Lipides 12(4):308–313. https://doi.org/10.1051/ocl.2005.0308
Harb R, Rivera-Tinoco R, Nemer M, Zeghondy B, Bouallou C (2020a) Towards synthetic fuels production from biomass gasification: tar content at low temperatures. Biomass Bioenerg 137:105540. https://doi.org/10.1016/j.biombioe.2020.105540
Harb R, Rivera-Tinoco R, Nemer M, Zeghondy B, Bouallou C (2020b) Process simulation of tar removal from gasification producer gas. Chem Eng Trans 81:6. https://doi.org/10.3303/CET2081156
Lotfi S, Ma W, Austin K, Kumar A (2019) A wet packed-bed scrubber for removing tar from biomass producer gas. Fuel Process Technol 193:197–203. https://doi.org/10.1016/j.fuproc.2019.05.024
Milne TA, Evans RJ, Abatzaglou N (1998) Biomass Gasifier “‘Tars’”: Their Nature, Formation, and Conversion (NREL/TP-570–25357, ON: DE00003726, 3726). https://doi.org/10.2172/3726
Neste. (2015, February 19). Biodiesel prices (SME & FAME). Neste Worldwide. https://www.neste.com/investors/market-data/biodiesel-prices-sme-fame
Pallozzi V, Di Carlo A, Bocci E, Carlini M (2018) Combined gas conditioning and cleaning for reduction of tars in biomass gasification. Biomass Bioenerg 109:85–90. https://doi.org/10.1016/j.biombioe.2017.12.023
Phuphuakrat T, Namioka T, Yoshikawa K (2011) Absorptive removal of biomass tar using water and oily materials. Biores Technol 102(2):543–549. https://doi.org/10.1016/j.biortech.2010.07.073
Qin Y, Huang H, Wu Z, Feng J, Li W, Xie K (2007) Characterization of tar from sawdust gasified in the pressurized fluidized bed. Biomass Bioenerg 31(4):243–249. https://doi.org/10.1016/j.biombioe.2006.06.017
Rabou L (2014) Biomethane in the EDGaR program and at ECN. 6.
Rapagnà S, Jand N, Kiennemann A, Foscolo PU (2000) Steam-gasification of biomass in a fluidised-bed of olivine particles. Biomass Bioenerg 19(3):187–197. https://doi.org/10.1016/S0961-9534(00)00031-3
Schmid M, Beirow M, Schweitzer D, Waizmann G, Spörl R, Scheffknecht G (2018) Product gas composition for steam-oxygen fluidized bed gasification of dried sewage sludge, straw pellets and wood pellets and the influence of limestone as bed material. Biomass Bioenerg 117:71–77. https://doi.org/10.1016/j.biombioe.2018.07.011
Thunman H, Seemann M, Vilches TB, Maric J, Pallares D, Ström H, Berndes G, Knutsson P, Larsson A, Breitholtz C, Santos O (2018) Advanced biofuel production via gasification – lessons learned from 200 man-years of research activity with Chalmers’ research gasifier and the GoBiGas demonstration plant. Energy Science and Engineering 6(1):6–34. https://doi.org/10.1002/ese3.188
Turton, R., Shaeiwitz, J. A., Bhattacharyya, D., & Whiting, W. B. (2018). Analysis, synthesis, and design of chemical processes (5th edition). Pearson
Unyaphan S, Tarnpradab T, Takahashi F, Yoshikawa K (2017) An investigation of low cost and effective tar removal techniques by venturi scrubber producing syngas microbubbles and absorbent regeneration for biomass gasification. Energy Procedia 105:406–412. https://doi.org/10.1016/j.egypro.2017.03.333
Valderrama Rios ML, González AM, Lora EES, Almazán del Olmo OA (2018) Reduction of tar generated during biomass gasification: a review. Biomass Bioenerg 108:345–370. https://doi.org/10.1016/j.biombioe.2017.12.002
Meijden CM van der (2014) The MILENA gasification technology for the production of Bio-Methane (Presentation ECN-L--14–0.37; ECN Biomass and Energy Efficiency, p. 30)
Weston P (2014) Tar Destruction in a Coandă Tar Cracker. University of Sheffield
Woolcock PJ, Brown RC (2013) A review of cleaning technologies for biomass-derived syngas. Biomass Bioenerg 52:54–84. https://doi.org/10.1016/j.biombioe.2013.02.036
Zwart R, Van Der Heijden S, Emmen R, Dall Bentzen J, Ahrenfeldt J, Stoholm P, Korgh J (2010) Tar removal from low-temperature gasifiers. ECN, 73.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflicts of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Code availability
The authors declare the availability of simulations is appeared as it is shown in this manuscript.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Harb, R., Rivera-Tinoco, R., Zeghondy, B. et al. Evaluating the impact of several scrubbing systems on the tar removal efficiency from producer gas. Clean Techn Environ Policy 24, 379–392 (2022). https://doi.org/10.1007/s10098-021-02189-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10098-021-02189-7