Skip to main content
Log in

Adsorption of phenol onto rice straw biowaste for water purification

  • Original Paper
  • Published:
Clean Technologies and Environmental Policy Aims and scope Submit manuscript

Abstract

The adsorption technique has been studied using waste rice straw to adsorb phenol from aqueous solutions at room temperature. Batch adsorption studies were carried out under varying experimental conditions of contact time, operational temperature, pH of phenol solution, initial phenol concentration, adsorbent dose, and particle size. The time to reach equilibrium was found to be 3 h. Results showed that the equilibrium data for phenol-sorbent systems fitted the Freundlich model and Langmuir model within the concentration range studied. Adsorbed phenol could be regenerated by desorption with the help of 1M NaOH. The studies showed that the rice straw can be used as an efficient adsorbent material for removal of phenol and phenolic compounds from water and wastewater.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  • Aksu Z, Yener J (2001) A comparative adsorption/boisorption study of monochlorinated phenols onto various sorbent. Waste Manag 21:695–702

    Article  CAS  Google Scholar 

  • Amin MN, Kaneco S, Kitagawa T, Begum A, Katsumata H, Suzuki T, Ohta K (2006) Removal of arsenic in aqueous solutions by adsorption onto waste rice husk. Ind Eng Chem Res 45:8105–8110

    Article  CAS  Google Scholar 

  • Annachhatre AP, Gheewala SH (1996) Biodegradation of chlorinated phenolic compounds. Biotechnol Adv 14:35–56

    Article  CAS  Google Scholar 

  • APHA: American public health association (1985) Standard methods for the examination of water and wastewater 16edn, Washington, DC, USA

  • Banat FA, Al-Bashir B, Al-Asheh S, Hayajneh O (2000) Adsorption of phenol by bentonite. Envirn Pollut 107:391–398

    Article  CAS  Google Scholar 

  • Barraclough D, Kearney T, Croxford A (2005) Bound residues: environmental solution or future problems? Environ Pollut 133:85–90

    Article  CAS  Google Scholar 

  • Beker U, Ganbold B, Dertli H, Gülbayir DD (2010) Adsorption of phenol by activated carbon: influence of activation methods and solution pH. Energy Convers Manag 51:235–240

    Article  CAS  Google Scholar 

  • Bhatnagar A, Vilar VJP, Botelho CMS, Boaventura RAR (2010) Coconut-based biosorbents for water treatment-a review of the recent literature. Adv Colloid Interface Sci 160:1–15

    Article  CAS  Google Scholar 

  • Caturla F, Martin-Martinez JM, Molina-Sabio M, Rodrignez-Reinoso F, Torregrosa R (1998) Adsorption of substituted phenols on activated carbon. J Coll Interface Sci 124:528–534

    Article  Google Scholar 

  • Dabrowski A, Podkoscielny P, Hubicki Z, Barczak M (2005) Adsorption of phenolic compounds by activated carbon–a critical review. Chemosphere 58:1049–1070

    Article  CAS  Google Scholar 

  • Dursun G, Cicek H, Dursun AY (2005) Adsorption of phenol from aqueous solution by using carbonized beet pulp. J Hazard Mater B125:175–182

    Article  Google Scholar 

  • Edgehill R, Lu (Max) GQ (1998) Adsorption characteristics of carbonized bark for phenol penta phlorophenol. J Chem Technol Biotechnol 71:27–34

    Article  CAS  Google Scholar 

  • Esplugas S, Gimenez J, Contreras S, Pascual E, Rodriguez M (2000) Comparison of different advanced oxidation processes for phenol degradation. Water Res 36:1034–1042

    Article  Google Scholar 

  • Freundlich HMF (1906) Over the adsorption in solution. J Phys Chem 57:385–470

    CAS  Google Scholar 

  • Guo ZF, Ma RX, Li GJ (2006) Degradation of phenol by nanomaterial TiO2 in wastewater. Chem Eng J 119:55–59

    Article  CAS  Google Scholar 

  • Gupta VK, Sharma S, Yadav IS, Mohan D (1998) Utilization of bagasse fly ash generated in the sugar industry for the removal and recovery of phenol and p-nitrophenol from wastewater. J Chem Technol Biotechnol 71:180–186

    Article  CAS  Google Scholar 

  • Halouli KA, Drawish NM (1995) Effects of pH and inorganic salts on the adsorption of phenol from aqueous systems on activated decolourising charcoal. Sep Sci Technol 30:3313–3324

    Article  Google Scholar 

  • Hanchao LU, Suping F, Xiaolin D, Nannan Z, Yongli L (2011) Comparison of three sorbents for organic pollutant removal in drinking water. Energy Procedia 5:985–990

    Article  Google Scholar 

  • Haque KR (2008) Guide for assessment of effluent treatment plants, Department of environment ministry of environment and forest, Bangladesh, http://www.doe-bd.org/ETP_Assessment_Guide.pdf

  • Hsu NH, Wang SL, Lin YC, Sheng GD, Lee JF (2009) Reduction of Cr(VI) by crop-residue-derived black carbon. Environ Sci Technol 43:8801–8806

    Article  CAS  Google Scholar 

  • Khalid N, Ahmad S, Toheed A (2000) Potential of rice husks for antimony removal. Appl Radiat Isot 52:30–38

    Google Scholar 

  • Kummar S, Upadhyay SN, Upadhyay YD (1987) Removal of phenols by adsorption on fly ash. J Chem Technol Biotechnol 37:281–290

    Article  Google Scholar 

  • Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403

    Article  CAS  Google Scholar 

  • Lin SH, Chery MJ (2002) Adsorption of phenol & m-chlorphenol on organobentonites and repeated thermal regeneration. Waste Manag 22:595–603

    Article  CAS  Google Scholar 

  • Lorenzen L, Deventer JSJV, Landi WM (1995) Factors affecting the mechanism of the adsorption of arsenic species on activated carbon. Miner Eng 8:557–569

    Article  CAS  Google Scholar 

  • Lua AC, Jia QP (2009) Adsorption of phenol by oil-palm-shell activated carbons in a fixed bed. Chem Eng J 150:455–461

    Article  CAS  Google Scholar 

  • Maleki A, Mahvi AH, Mesdaghinia A, Naddafi K (2007) Degradation and toxicity reduction of phenol by ultrasound wave. Bull Chem Soc Ethiop 21:33–38

    CAS  Google Scholar 

  • Maleki A, Mahvi AH, Ebrahimi R, Khan J (2010) Evaluation of barley straw and its ash in removal of phenol from aqueous system. World Appl Sci J 8:369–373

    CAS  Google Scholar 

  • Mandal KG, Misra AK, Hati KM, Bandyopadhyay KK, Ghosh PK, Mohanty M (2004) Rice residue-management options and effects on soil properties and crop productivity. Food Agric Environ 2:224–231

    Google Scholar 

  • Mustafa AI, Alam MS, Amin MN, Bahadur NM, Habib MA (2008) Phenol removal from aqueous system by jute stick. Pak J Anal Environ Chem 9:92–95

    CAS  Google Scholar 

  • Nevskaia DM, Santianes A, Munoz V, Guerrero-Ruiz A (1999) Interaction of aqueous solutions of phenol with commercial activated carbons: an adsorption and kinetic study. Carbon 37:1065–1074

    Article  CAS  Google Scholar 

  • Radhika M, Palanivelu K (2006) Adsorptive removal of chlorophenols from aqueous solution by low cost adsorbent-kinetics and isotherm analysis. J Hazard Mater 38:116–124

    Article  Google Scholar 

  • Rashwan WE, Girgis BS (2004) Adsorption capacities of activated carbons derived from rice straw and water hyacinth in the removal of organic pollutants from Water. Adsorpt Sci Technol 22:181–194

    Article  CAS  Google Scholar 

  • Rengaraj S, Seuny-Hyeon M, Sivabalan R (2002) Agricultural solid waste for the removal of organics: adsorption of phenol from water and wastewater by palm seed coat activated carbon. Waste Manag 22:543–548

    Article  CAS  Google Scholar 

  • Rodgers JD, Jedral W, Bunce NJ (1999) Electrochemical oxidation of chlorinated phenols. Environ Sci Technol 33:1453–1457

    Article  CAS  Google Scholar 

  • Rzeszutek K, Chow A (1998) Extraction of phenols using polyurethane membrane. Talanta 46:507–519

    Article  CAS  Google Scholar 

  • Singh B, Shan YH, Johnson-Beebout SE, Singh Y, Buresh RJ (2008) Crop residue management for lowland rice-based cropping systems in Asia. Adv Agron 98:117–199

    Article  Google Scholar 

  • Srihari V, Das A (2008) Comparative studies on adsorptive removal of phenol by three agro-based carbons: Equilibrium and isotherm studies. Ecotoxicol Environ Saf 71:274–283

    Article  CAS  Google Scholar 

  • Srivastava SK, Tyagi R, Pal N, Mohan D (1997) Process development for removal of substituted phenol by carbonaceouse adsorbent obtained from fertilizer waste. J Environ Eng 123:842–851

    Article  CAS  Google Scholar 

  • Street M, Patrick JW, Camporroperez MJ (1995) Sorption of phenol and p-chlorophenol from water using convention and novel activated carbons. Water Sci Res 29:467–472

    Article  Google Scholar 

  • Tutem E, Apak R, Unal CF (1998) Adsorptive removal of chlorophenols from water by bituminous shale. Water Res 32:2315–2324

    Article  CAS  Google Scholar 

  • Uddin MT, Islam MS, Islam MA, Abedin MZ (2008) Uptake of phenol from aqueous solution by burned water hyacinth. Polish J Chem Technol 10:43–49

    Article  CAS  Google Scholar 

  • Williams PT, Nugranad N (2000) Comparison of products from the pyrolysis and catalytic of rice husks. Energy 25:493–513

    Article  CAS  Google Scholar 

  • Wikipedia, http://en.wikipedia.org/wiki/Agriculture_of_Bangladesh

  • Yang YN, Chun Y, Sheng GY, Huang MS (2004) pH-dependence of pesticide adsorption by wheat-residue-derived black carbon. Langmuir 20:6736–6741

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are grateful to the Chairman, Department of Applied Chemistry and Chemical Engineering, University of Dhaka, and also to the Director of the Centre of Excellence, Dhaka University, Bangladesh, for providing the laboratory facilities during the progress of this work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. N. Amin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Amin, M.N., Mustafa, A.I., Khalil, M.I. et al. Adsorption of phenol onto rice straw biowaste for water purification. Clean Techn Environ Policy 14, 837–844 (2012). https://doi.org/10.1007/s10098-012-0449-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10098-012-0449-6

Keywords

Navigation