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Freeze-thaw stability, glass transition, and retrogradation of high hydrostatic pressure-assisted hydroxypropylated corn starch

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Abstract

Effects of high hydrostatic pressure (HHP) and the propylene oxide (PO) concentration on the freeze-thaw stability, glass transition temperature (Tg′), and retrogradation degree of HHP-assisted hydroxypropylated corn starch were investigated. HHP-assisted hydroxypropylated corn starches were prepared using propylene oxide (4, 8, and 12%, v/w) at 25°C for 15 min under HHP (100, 200, 300, and 400 MPa). The freeze-thaw stability, Tg′, ice melting enthalpy (H i ), and retrogradation degree of HHP-assisted hydroxypropylated corn starches showed patterns different from native corn starch. In general, higher pressures and PO levels lowered Tg′ and H i values, and the retrogradation degree. The highest freeze-thaw stability was observed in HHP-assisted hydroxypropylated corn starch prepared using 12% PO at 400 MPa for 15 min. Retrogradation kinetics of hydroxypropylated corn starch gels observed from the glass transition temperature, ice melting enthalpy, and retrogradation degree revealed that recrystallization occurred with instantaneous nucleation, followed by rod-like growth of crystals.

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References

  1. Osman EM. Starch in the food industry. Vol. II, pp. 163–210. In: Starch: Chemistry and Technology. Whistler RL, BeMiller JN, Paschall EF (eds). Academic Press, New York, NY, USA (1967)

    Google Scholar 

  2. Dias FF, Tekchandani HK, Mehta D. Modified starches and their use by food industries. Indian Food Ind. Mag 16: 33–39 (1997)

    Google Scholar 

  3. Pal J, Singhal RS, Kulkarni PR. A comparative account of conditions of synthesis of hydroxypropyl derivative from corn and amaranth starch. Carbohyd. Polym. 43: 155–162 (2000)

    Article  CAS  Google Scholar 

  4. Shi X, BeMiller JN. Aqueous leaching of derivatized amylose from hydroxypropylated common corn starch granules. Starch-Stärke 54: 16–19 (2002)

    Article  CAS  Google Scholar 

  5. Pal J, Singhal RS, Kulkarni PR. Physicochemical properties of hydroxypropyl derivative from corn and amaranth starch. Carbohyd. Polym. 48: 49–53 (2002)

    Article  CAS  Google Scholar 

  6. B3aszczak W, Fornal J, Kiseleva VI, Yuryev VP, Sergeev AI, Sadowska J. Effect of high pressure on thermal, structural and osmotic properties of waxy maize and Hylon VII starch blends. Carbohyd. Polym. 68: 387–396 (2007)

    Article  Google Scholar 

  7. Kim HS, Choi HS, Kim BY, Baik MY. Ultra high pressure (UHP)-assisted hydroxypropylation of corn starch. Carbohyd. Polym. 83: 755–761 (2011)

    Article  CAS  Google Scholar 

  8. Choi HW, Lee JH, Ahn SC, Kim BY, Baik MY. Effects of ultra high pressure, pressure time and HCl concentration on non-thermal starch hydrolysis using ultra high pressure. Starch-Stärke 61: 334–343 (2009)

    Article  CAS  Google Scholar 

  9. Lee JH, Choi HW, Kim BY, Chung MS, Kim DS, Choi SW, Lee DU, Park SJ, Hur NY, Baik MY. Nonthermal starch hydrolysis using ultra high pressure: I. Effects of acids and starch concentrations. LWT-Food Sci. Technol. 39: 1125–1132 (2006)

    Article  CAS  Google Scholar 

  10. Hwang DK, Kim BY, Baik MY. Physicochemical properties of nonthermally cross- linked corn starch with phosphorus oxychloride using ultra high pressure (UHP). Starch-Stärke 61: 438–447 (2009)

    Article  CAS  Google Scholar 

  11. Choi HS, Kim HS, Park CS, Kim BY, Baik MY. Ultra high pressure (UHP)-assisted acetylation of corn starch. Carbohyd. Polym. 78: 862–868 (2009)

    Article  CAS  Google Scholar 

  12. Lim SS. Physicochemical properties of non-thermally dual modified corn starch using ultra high pressure (UHP). MS thesis, Kyung Hee University, Yongin, Korea (2011)

    Google Scholar 

  13. Kaur L, Singh N, Singh J. Factors influencing the properties of hydroxypropylated potato starches. Carbohyd. Polym. 55: 211–223 (2004)

    Article  CAS  Google Scholar 

  14. Lawal OS. Starch hydroxyalkylation: Physicochemical properties and enzymatic digestibility of native and hydroxypropylated finger millet (Eleusine coracana) starch. Food Hydrocolloid. 23: 415–425 (2009)

    Article  CAS  Google Scholar 

  15. Colwell KH, Axford DWE, Chamberlain N, Elton GAH. Effect of storage temperature on the aging of concentrated wheat starch gels. J. Sci. Food Agr. 20: 550–555 (1969)

    Article  CAS  Google Scholar 

  16. Pongsawatmanit R, Temsiripong T, Ikeda S, Nishinari K. Influence of tamarind seed xyloglucan on rheological properties and thermal stability of tapioca starch. J. Food Eng. 77: 41–50 (2006)

    Article  CAS  Google Scholar 

  17. Choi SG, Kerr WL. Effect of hydroxypropylation on retrogradation and water dynamics in wheat starch gels using 1H NMR. Cereal Chem. 80: 290–296 (2003)

    Article  CAS  Google Scholar 

  18. Wattanachant S, Muhammad K, Hashim DM, Rahman RA. Effect of crosslinking reagents and hydroxypropylation levels on dualmodified sago starch properties. Food Chem. 80: 463–471 (2003)

    Article  CAS  Google Scholar 

  19. Hoover R, Hannouz D, Ontario F, Sosulski F. Effects of hydroxypropylation on thermal properties, starch digestibility and freeze-thaw stability of field pea (Pisum sativum cv. Trapper) starch. Starch-Stärke 40: 383–387 (1998)

    Article  Google Scholar 

  20. Perera C, Hoover R. Influence of hydroxypropylation on retrogradation properties of native, defatted and heat-moisture treated potato starches. Food Chem. 64: 361–375 (1999)

    Article  CAS  Google Scholar 

  21. Wootton M, Manatsathit A. The influence of molar substitution on the water binding capacity of hydroxypropyl maize starches. Starch-Stärke 35: 92–94 (1983)

    Article  CAS  Google Scholar 

  22. Gunaratne A, Corke H. Effect of hydroxypropylation and alkaline treatment in hydroxypropylation on some structural and physicochemical properties of heat-moisture treated wheat, potato and waxy maize starches. Carbohyd. Polym. 68: 305–313 (2007)

    Article  CAS  Google Scholar 

  23. Koo HJ, Park SH, Jo JS, Kim BY, Baik MY. Gelatinization and retrogradation of 6-year-old Korean ginseng starches studied by DSC. LWT-Food Sci.Technol. 38: 59–65 (2005)

    Article  CAS  Google Scholar 

  24. Baik MY, Kim KJ, Cheon KC, Ha YC, Kim WS. Recrystallization kinetics and glass transition of rice starch gel system. J. Agr. Food Chem. 45: 4242–4248 (1997)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Food Science and Biotechnology, Institute of Life Science and Resources, Kyung Hee University, Yongin, Gyeonggi, 446-701, Korea

    Suntitham Chotipratoom, Jong-Hyun Choi, Ji-Eun Bae, Byung Yong Kim & MooYeol Baik

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  1. Suntitham Chotipratoom
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  2. Jong-Hyun Choi
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  3. Ji-Eun Bae
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  4. Byung Yong Kim
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  5. MooYeol Baik
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Correspondence to MooYeol Baik.

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Chotipratoom, S., Choi, JH., Bae, JE. et al. Freeze-thaw stability, glass transition, and retrogradation of high hydrostatic pressure-assisted hydroxypropylated corn starch. Food Sci Biotechnol 24, 1327–1333 (2015). https://doi.org/10.1007/s10068-015-0170-4

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  • DOI: https://doi.org/10.1007/s10068-015-0170-4

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