Abstract
Sulfate attack–induced expansion of cement-treated aggregates is a well-known problem to be addressed causing remarkable heave in road and railway subgrades. The specific surface area (SSA) of the materials influences chemical reactions significantly. In this study, cement, sodium sulfate, and basalt powder were ground in a ball mill for 0 (without grinding), 5, 10, 30, and 60 min respectively to achieve different SSA gradients. Under the curing condition of a constant temperature of 10 °C and humidity of 70%, with 5% cement, the effects of sodium sulfate contents and SSA gradients on the expansion of sulfate attack in cement-treated aggregate (SACA) were investigated during 60 days in laboratory. Based on nitrogen absorption methods, microscopic tests, and swelling tests, the results show that, grinding within 60 min, the respective peak value of SSAs of cement, mixture of 3% (or 8%) sodium sulfate and basalt powder, and mixture of 3% (or 8%) sodium sulfate, cement, and basalt powder was 1.867 m2/g, 1.109 m2/g (or 1.393 m2/g), and 1.128 m2/g (or 1.404 m2/g), respectively. The SSAs increase as the aggregates refined, then decrease as the aggregates gathered. The strain variation can be generally divided into four stages with 3% sodium sulfate attack in cement-treated aggregate (3% SACA): rapid strain increase, short stagnation, continuous heave, and constant strain. Two stages of strain variation have been observed with 8% sodium sulfate attack in cement-treated aggregate (8% SACA): rapid strain increase, and a constant strain. Finer needle-like ettringite crystals (average length: 0.5–1 μm) filling in the smaller holes produce the greater expansion induced by SACA. Based on grey incidence analysis, the SSAs of cement, mixture of sodium sulfate and basalt powder (S+B), and the whole mixture of cement, sodium sulfate, and basalt powder (C+S+B) have a significant effect on strain. This work provides theoretical support for amending SACA at the SSA level.
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References
Adams AG, Dukes OM, Tabet W, Cerato AB, Miller GA (2008) Sulfate induced heave in Oklahoma soils due to lime stabilization. Geotech Spec Publ 179:444–451. https://doi.org/10.1061/40972(311)56
Alonso EE, Ramon A (2013) Massive sulfate attack to cement-treated railway embankments. Géotechnique 63(10):857–870. https://doi.org/10.1680/geot.sip13.p.023
Callister WD (2001) Fundamentals of material science and engineering. Wiley, New York
Crammond N (2002) The occurrence of thaumasite in modern construction - a review. Cem Concr Compos 24(3):393–402. https://doi.org/10.1016/s0958-9465(01)00092-0
Deng M, Tang M (1994) Formation and expansion of ettringitee crystals. Cem Concr Res 24(1):199–126. https://doi.org/10.1016/0008-8846(94)90092-2
Eriksen K (2003) Thaumasite attack on concrete at Marbjerg waterworks. Cem Concr Compos 25(8):1147–1150. https://doi.org/10.1016/S0958-9465(03)00151-3
Ghasemi Y, Emborg M, Cwirzen A (2019) Exploring the relation between the flow of mortar and specific surface area of its constituents. Constr Build Mater 211:492–501. https://doi.org/10.1016/j.conbuildmat.2019.03.260
Gupta S, Muthukrishnan S, Kua HW (2020) Comparing influence of inert biochar and silica rich biochar on cement mortar–Hydration kinetics and durability under chloride and sulfate environment. Constr Build Mater. https://doi.org/10.1016/j.conbuildmat.2020.121142
Hou J, Li J, Chen Y (2017) Coupling effect of landfill leachate and temperature on the microstructure of stabilized clay. Bull Eng Geol Environ 78:629–640. https://doi.org/10.1007/s10064-017-1099-z
Knopp J, Moormann C (2016) Ettringite swelling in the treatment of sulfate-containing soils used as subgrade for road constructions. Procedia Eng 143:128–137
Little D, Nair S, Herbert B (2010) Addressing sulfate-induced heave in lime treated soils. J Geotech Geoenviron Eng 136(1):110–118. https://doi.org/10.1061/(asce)gt.1943-5606.0000185
Liu SF, Lin Y (2010) Grey systems: theory and applications. Springer-Verlag, Berlin, Germany
Long S, Wu Y, Liu C (1995) Investigation on the formation of ettringite in the presence of BaO. Cem Concr Res 25(7):1417–1422. https://doi.org/10.1016/0008-8846(95)00136-Z
Luo Y, Zhou S, Wang C, Fang Z (2019) Effects of cations in sulfate on the thaumasite form of sulfate attack of cementitious materials. Constr Build Mater 229:1–9. https://doi.org/10.1016/j.conbuildmat.2019.116865
Ma B, Gao X, Byars EA, Zhou QZ (2006) Thaumasite formation in a tunnel of Bapanxia Dam in Western China. Cem Concr Res 36(4):716–722. https://doi.org/10.1016/j.cemconres.2005.10.011
Ma KL, Long GC, Xie YJ (2012) Railway tunnel concrete lining damaged by formation of gypsum, thaumasite and sulfate crystallization products in southwest of China. J Cent South Univ 19(8):2340–2347. https://doi.org/10.1007/s11771-012-1280-2
Ma X, Copuroglu O, Schlangen E, Han N, Xing F (2018) Expansion and degradation of cement paste in sodium sulfate solutions. Constr Build Mater 158(15):410–422. https://doi.org/10.1016/j.conbuildmat.2017.10.026
Mehdipour I, Khayat KH (2017) Effect of particle-size distribution and specific surface area of different binder systems on packing density and flow characteristics of cement paste. Cem Concr Compos 78:120–131. https://doi.org/10.1016/j.cemconcomp.2017.01.005
Orejarena L, Fall M (2010) The use of artificial neural networks to predict the effect of sulfate attack on the strength of cemented paste backfill. Bull Eng Geol Environ 69:659–670. https://doi.org/10.1007/s10064-010-0326-7
Ouyang C, Nanni A, Chang WF (1988) Internal and external sources of sulfate ions in portland cement mortar: two types of chemical attack. Cem Concr Res 18(5):699–709. https://doi.org/10.1016/0008-8846(88)90092-0
Peng G (2013) Materials in civil engineering. Huazhong University of Science & Technology Press, Wu Han
Ping X, Beaudoin JJ (1992) Mechanism of sulphate expansion I. Thermodynamic principle of crystallization pressure. Cem Concr Res 22(4):631–640. https://doi.org/10.1016/0008-8846(92)90015-N
Puppala AJ, Intharasombat N, Vempati R (2005) Experimental studies on ettringite induced heaving in soils. J Geotech Geoenviron 31(3):325–337. https://doi.org/10.1061/(asce)1090-0241(2005)131:3(325)
Puppala AJ, Saride S, Dermatas D, Al-Shamrani M, Chikyaly V (2010) Forensic investigations to evaluate sulfate-induced heave attack on a tunnel shotcrete liner. J Mater Civ Eng 22(9):914–922. https://doi.org/10.1061/(asce)mt.1943-5533.0000087
Rahman MM, Bassuoni MT (2014) Thaumasite sulfate attack on concrete: mechanisms, influential factors and mitigation. Constr Build Mater 73:652–662. https://doi.org/10.1016/j.conbuildmat.2014.09.034
Raja PSK, Thyagaraj T (2020) Sulfate effects on sulfate-resistant cement-treated expansive soil. Bull Eng Geol Environ 79:2367–2380. https://doi.org/10.1007/s10064-019-01714-9
Romer M, Holzer L, Pfiffner M (2003) Swiss tunnel structures: concrete damage by formation of thaumasite. Cem Concr Compos 25(8):1111–1117. https://doi.org/10.1016/S0958-9465(03)00141-0
Sahu S, Badger S, Thaulow N (2002) Evidence of thaumasite formation in Southern California concrete. Cem Concr Compos 24:379–384. https://doi.org/10.1016/S0958-9465(01)00090-7
Santhanam M, Cohen MD, Olek J (2003) Effects of gypsum formation on the performance of cement mortars during external sulfate attack. Cem Concr Res 33(3):325–332. https://doi.org/10.1016/S0008-8846(02)00955-9
Slater D, Floyd M, Wimpenny DE (2003) A summary of the highways agency thaumasite investigation in gloucestershire: the scope of work and main findings. Cem Concr Compos 25(8):1067–1076. https://doi.org/10.1016/S0958-9465(03)00131-8
Steiger M (2005) Crystal growth in porous materials-I: the crystallization pressure of large crystals. J Cryst Growth 282(3-4):455–469. https://doi.org/10.1016/j.jcrysgro.2005.05.007
TB (2010) (National Railway Administration of the People’s Republic of China Codes). Code for soil test of railway engineering. TB 10102-2010. Beijing: China Railway Publishing House
Tosun N (2006) Determination of optimum parameters for multi-performance characteristics in drilling by using grey relational analysis. Int J Adv Manuf Technol 28:450–455. https://doi.org/10.1007/s00170-004-2386-y
Wang L, Roy A, Seals RK, Metcalf JB (2003) Stabilization of sulfate-containing soil by cementitious mixtures mechanical properties. Transp Res Record: J Transp Res Board 1837:12–19. https://doi.org/10.3141/1837-02
Wang Y, He X, Su Y, Huang J, Ma B (2017) Effect of silica fume on the thaumasite form of sulfate attack on cement-based materials. J Wuhan Univ Technol Mater sci:1108–1114. https://doi.org/10.1007/s11595-017-1718-3
Wang P, Ye Y, Zhang Q, Liu J, Yao J (2020) Investigation on the sulfate attack-induced heave of a ballastless track railway subgrade. Transp Geotech 23:224–392. https://doi.org/10.1016/j.trgeo.2020.100316
Wu M, Zhang Y, Ji Y, She W, Yang L, Liu G (2020) A comparable study on the deterioration of limestone powder blended cement under sodium sulfate and magnesium sulfate attack at a low temperature. Constr Build Mater 243:1–10. https://doi.org/10.1016/j.conbuildmat.2020.118279
Zeng Q, Wang C, Luo Y, Yu C (2018) Huang Qm Luo C (2018) Effect of temperatures on TSA in cement mortars under electrical field. Constr Build Mater 162:88–95. https://doi.org/10.1016/j.conbuildmat.2017.12.015
Zhou Q, Hill J, Byars EA, Cripps JC, Lynsdale CJ, Sharp JH (2006) The role of pH in thaumasite sulfate attack. Cem Concr Res 36(1):160–170. https://doi.org/10.1016/j.cemconres.2005.01.003
Zhu Z, Xu W, Chen H, Tan Z (2020) Evolution of microstructures of cement paste via continuous-based hydration model of non-spherical cement particles. Compos Part B: Eng 185:1–14. https://doi.org/10.1016/j.compositesb.2020.107795
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This research was supported by the National Natural Science Foundation of China (No. 41801055), Fundamental Research Funds for the Central Universities (No. 2020YJS122), and the project funded by China railway Corporation under Grant (No. 2017G002-S).
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Wang, Q., Liu, J., Wang, P. et al. Influence of specific surface area on sulfate attack–induced expansion of cement-treated aggregates. Bull Eng Geol Environ 80, 4841–4854 (2021). https://doi.org/10.1007/s10064-021-02200-x
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DOI: https://doi.org/10.1007/s10064-021-02200-x