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Determination of mechanical and hydraulic properties of polyacrylamide-added bentonite-sand mixtures

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Abstract

Bentonite-sand mixtures are typically used in engineering applications such as cutoff walls for waste containment facilities or barriers in landfills and freshwater reservoirs. However, low or reduced mechanical and hydraulic performance of a bentonite-sand mixture might result in the failure of the engineering structure. In order to enhance the mechanical and hydraulic properties of a bentonite-sand mixture, an anionic and a cationic polyacrylamides with a content of 1, 2, 5, 10, and 15% respectively were added to the bentonite-sand mixtures. The polyacrylamides used in this study were water-soluble synthetic polymers with high molecular weights. They had enhanced flocculation capability when coming into contact with soil and water. Standard Proctor compaction, consolidated-drained direct shear, unconfined compression, falling-head permeability, and free swell tests were performed on the bentonite-sand mixtures that had different bentonite contents. Test results indicated that cohesion, unconfined compressive strength, maximum dry unit weight, and swell index increased while internal frictional angle, permeability, and optimum water content decreased as a result of the polyacrylamide addition. The rate of change was much higher when the polyacrylamide content was increased up to 2%. The performance of the anionic polyacrylamide was found to be slightly better than that of the cationic polyacrylamide in terms of both strength and permeability. In conclusion, 2% anionic polyacrylamide addition resulted in a sufficient increase in the shear and compressive strength, a slight increase in the swell index, and a sufficient decrease in the permeability of the bentonite-sand mixtures.

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References

  • Abdellah D, Gueddouda MK, Goual I, Souli H, Ghembaza MS (2020) Effect of landfill leachate on the hydromechanical behavior of bentonite-geomaterials mixture. Constr Build Mater 234:117356

    Google Scholar 

  • Al-Sanad HA, Eid WK, Ismael NF (1995) Geotechnical properties of oil-contaminated Kuwaiti sand. J Geotech Eng 121(5):407–412

    Google Scholar 

  • ASTM D698 (2012) Standard test methods for laboratory compaction characteristics of soil using standard effort. ASTM International, West Conshohocken, PA, USA

    Google Scholar 

  • ASTM D854 (2014) Standard test methods for specific gravity of soil solids by water pycnometer. ASTM International, West Conshohocken, PA, USA

    Google Scholar 

  • ASTM D2166 (2013) Standard test method for unconfined compressive strength of cohesive soil. ASTM International, West Conshohocken, PA, USA

    Google Scholar 

  • ASTM D3080 (2011) Standard test method for direct shear test of soils under consolidated drained conditions. ASTM International, West Conshohocken, PA, USA

    Google Scholar 

  • ASTM D4318 (2010) Standard test method for liquid limit, plastic limit and plasticity index of soils. ASTM International, West Conshohocken, PA, USA

    Google Scholar 

  • ASTM D5856 (2015) Standard test method for measurement of hydraulic conductivity of porous material using a rigid-wall, compaction-mold permeameter. ASTM International, West Conshohocken, PA, USA

    Google Scholar 

  • ASTM D5890 (2011) Standard test method for swell index of clay mineral component of geosynthetic clay liners. ASTM, West Conshohocken, PA, USA

    Google Scholar 

  • ASTM D5993 (2014) Standard test method for measuring mass per unit of geosynthetic clay liners. ASTM International, West Conshohocken, PA, USA

    Google Scholar 

  • ASTM D6913 (2017) Standard test methods for particle-size distribution (gradation) of soils using sieve analysis. ASTM International, West Conshohocken, PA, USA

    Google Scholar 

  • ASTM D7503 (2018) Standard test method for measuring the exchange complex and cation exchange capacity of inorganic fine-grained soils. ASTM International, West Conshohocken, PA, USA

    Google Scholar 

  • Benson CH, Jo HY, Musso T (2015) Hydraulic conductivity of organoclay and organoclay-sand mixtures to fuels and organic liquids. J Geotech Geoenviron Eng 141(2):04014094–04014091

    Google Scholar 

  • BS EN 1410 (2008) Chemicals used for treatment of water intended for human consumption. Cationic polyacrylamides. BSI, UK, 22p

    Google Scholar 

  • Burton GJ, Sheng D, Campbell C (2014) Bimodal pore size distribution of a high-plasticity compacted clay. Géotech Letters 4(2):88–93

    Google Scholar 

  • Chen J, Li Z, Zaho X, Li H (2011) Experimental study of bentonite–soil mixtures as antiseepage materials of constructed wetlands. J Environ Sci Health A Tox Hazard Subst Environ Eng 46(7):729–735

    Google Scholar 

  • Chien CC, Inyang HI, Everett LG (2006) Barrier systems for environmental contaminant containment and treatment. CRC Press, Boca Raton

    Google Scholar 

  • Chun-Ming Z, Wei-Min Y, Yong-Gui C, Bao C, Yu-Jun C (2013) Influence of salt solutions on the swelling pressure and hydraulic conductivity of compacted GMZ01 bentonite. Eng Geol 166:74–80

    Google Scholar 

  • Dafalla MA (2017) The compressibility and swell of mixtures for sand-clay liners. Adv Mater Sci Eng 3181794:9 p

  • Demdoum A, Gueddouda MK, Goual I (2017) Effect of water and leachate on hydraulic behavior of compacted bentonite, calcareous sand and tuff mixtures for use as landfill liners. Geotech Geol Eng 35(6):2677–2696

    Google Scholar 

  • Deng Y, Dixon JB, White GN, Loeppert RH, Juo ASR (2006) Bonding between polyacrylamideand smectite. Colloids and Surfaces 281:82–91

    Google Scholar 

  • Dimitrova R, Yanful E (2012) Factors affecting the shear strength of mine tailings/clay mixtures with varying clay content and clay mineralogy. Eng Geol 125:11–25

    Google Scholar 

  • Doley C, Das UK, Phukan PK, Dutta D, Bora PM (2016) A study on use of Brahmaputra river sand as a liner material for municipal landfills. J Mech Civ Eng 13(4):91–96

    Google Scholar 

  • Dupin HJ, McCarty PL (2000) Impact of colony morphologies and disinfection on biological clogging in porous media. Environ Sci Technol 34(8):1513–1520

    Google Scholar 

  • Ejezie JO, Jefferis SA, Lam C, Sedighi M, Ahmad SM (2020) Permeation behaviour of PHPA polymer fluids in sand. Geotechnique. https://doi.org/10.1680/jgeot.18.P.353

  • Gaucher EC, Blanc P (2006) Cement/clay interactions: a review: experiments, natural analogues, and modeling. Waste Manag 26:776–788

    Google Scholar 

  • Geng W, Likos WJ, Benson CH (2016) Viscosity of polymer-modified bentonite as a hydraulic performance index. Geo-Chicago 2016 GSP 271, 498–507

  • Gotvajn AŽ, Tišler T, Zagorc-Končan J (2009) Comparison of different treatment strategies for industrial landfill leachate. J Hazard Mater 162(2–3):1446–1456

    Google Scholar 

  • Guler E, Ozhan HO, Karaoglu S (2018) Hydraulic performance of anionic polymer-treated bentonite-granular soil mixtures. Appl Clay Sci 157:139–147

    Google Scholar 

  • Haase H, Schanz T (2015) Hydro-mechanical properties of calcigel polyacrylamide composites. Clay Miner 50(3):377–389

    Google Scholar 

  • Haase H, Schanz T (2016) Compressibility and saturated hydraulic permeability of claypolymer composites-experimental and theoretical analysis. Appl Clay Sci 130:62–75

    Google Scholar 

  • Hosney MS, Rowe RK (2017) Performance of polymer-enhanced bentonite-sand mixture for covering arsenic-rich gold mine tailings for up to 4 years. Can Geotech J 54(4):588–599

    Google Scholar 

  • Jafarian Y, Javdanian H, Haddad A (2018) Dynamic properties of calcareous and siliceous sands under isotropic and anisotropic stress conditions. Soils Found 58:172–184

    Google Scholar 

  • Jesmani M, Manesh AN, Hosseini SMR (2008) Optimum water content and maximum dry unit weight of clayey gravels at different compactive efforts. Electron J Geotech Eng 13:14 p

  • Jaynes DB (1990) Temperature variations effect on field-measured infiltration. Soil Sci Soc Am J 54:305–312

    Google Scholar 

  • Kim SJ, Choi DH, Sim DS, Oh YS (2005) Evaluation of bioremediation effectiveness on crude oil-contaminated sand. Chemosphere 59(6):845–852

    Google Scholar 

  • Knutsen H, Mæhlum T, Haarstad K, Slinde GA, Arp HPH (2019) Leachate emissions of short-and long-chain per-and polyfluoralkyl substances (PFASs) from various Norwegian landfills. Environ Sci: Processes Impacts. https://doi.org/10.1039/c9em00170k

  • Lam C, Jefferis SA (2014) The use of polymer solutions for deep excavations: lessons from Far Eastern experience. HKIE Transactions 21(4):262–271

    Google Scholar 

  • Lam C, Jefferis SA (2016) Performance of bored piles constructed using polymer fluids: lessons from European experience. J Perform Constr Facil 30(2):04015024

    Google Scholar 

  • Lam C, Jefferis SA (2017) Polymer support fluids in civil engineering. ICE Publishing, London. https://doi.org/10.1680/psfce.57869

    Article  Google Scholar 

  • Lam C, Jefferis SA, Martin CM (2014) Effects of polymer and bentonite support fluids on concrete-sand interface shear strength. Géotechnique 64(1):28–39

    Google Scholar 

  • Lam C, Jefferis SA, Suckling TP (2018) Treatment of bentonite fluid for excavation into chalk. Geotech Eng 171(6):518–529

    Google Scholar 

  • Latifi N, Horpibulsuk S, Meehan CL, Majid MZA, Tahir MM, Mohamad ED (2016) Improvement of problematic soils with biopolymer-an environmentally friendly soil stabilizer. J Mater Civ Eng 29 (2). https://doi.org/10.1061/(ASCE)MT.1943-5533.0001706

  • Liu Y, Gates WP, Bouazza A (2012) Improvement on the performance of geosynthetic clay liners using polymer modified bentonite. Geotech Eng 43(3):43–45

    Google Scholar 

  • Liu J, Feng Q, Wang Y, Bai Y, Wei J, Song Z (2017) The effect of polymer-fiber stabilization on the unconfined strength and shear strength of sand. Advances in Mater Sci Eng 1-9.https://doi.org/10.1155/2017/2370763

  • Mollins LH, Stewart DI, Cousens TW (1996) Predicting the properties of bentonite-sand mixtures. Clay Miner 31:243–252

    Google Scholar 

  • Naeini SA, Mahdavi A (2009) Effect of polymer on shear strength of silty sand. Ms. Thesis: Imam Khomeini International University, Qazvin, Iran

  • Ozhan HO (2018a) Hydraulic capability of polymer-treated GCLs in saline solutions at elevated temperatures. Appl Clay Sci 161:364–373

    Google Scholar 

  • Ozhan HO (2018b) Effects of temperature increase in 0.5 M MgCl2 solution on hydraulic capability of anionic polymer-treated geosynthetic clay liners used as barriers. J Environ Eng 144 (10). https://doi.org/10.1061/(ASCE)EE.1943-7870.0001451

  • Pusch R (2015) Bentonite clay: environmental properties and applications. CRC Press, 368 p

  • Razakamanantsoa AR, Barast G, Djeran-maigre I (2012) Hydraulic performance of activated calcium bentonite treated by polyionic charged polymer. Appl Clay Sci 59-60:103–114

    Google Scholar 

  • Razakamanantsoa AR, Djeran-Maigre I (2016) Longterm chemo-hydro mechanical behavior of compacted soil bentonite polymer complex submitted to synthetic leachate. Waste Manag 53:92–104

    Google Scholar 

  • Razakamanantsoa AR, Djeran-Maigre I, Barast G (2016) Characterisation of bentonite polymer for bottom liner use. Environ Geotech 3(1):28–35

    Google Scholar 

  • Rowe RK (2012) 3rd Indian geotechnical society: Ferroco Terzaghi oration design and construction of barrier systems to minimize environmental impacts due to municipal solid waste leachate and gas. Indian Geotech J 42(4):223–256

    Google Scholar 

  • Sarkar M, Dana K, Ghatak S, Banerjee A (2008) Polypropylene–clay composite prepared from Indian bentonite. Bull Mater Sci 31(1):23–28

    Google Scholar 

  • Seybold CA (1994) Polyacrylamide review: soil conditioning and environmental fate. Commun Soil Sci Plant Anal 25(11–12):2171–2185

    Google Scholar 

  • Shen SQ, Wei ML (2018) Hydraulic conductivity of polymer-amended sand-bentonite backfills permeated with lead nitrate solutions. Advances in Civil Engineering 9435194, 12 p

  • SNF Turkey (2016) http://www.snfturk.com/tr/snf-detay/104/flokulantlar. Accessed 22 August 2020

  • Theng BKG (2012) Formation and properties of clay-polymer complexes, 2nd edn. Elsevier, Amsterdam

    Google Scholar 

  • Tian K, Benson CH, Likos WJ (2016) Hydraulic conductivity of geosynthetic clay liners to low-level radioactive waste leachate. J Geotech Geoenviron Eng 142(8). https://doi.org/10.1061/(ASCE)GT.1943-5606.0001495

  • Tian K, Likos WJ, Benson CH (2019) Polymer elution and hydraulic conductivity of bentonite–polymer composite geosynthetic clay liners. J Geotech Geoenviron Eng 145(10):04019071

    Google Scholar 

  • Welling GE (2012) Engineering performance of polymer amended soils. Ms. Thesis: Polytechnic State University, California, USA

Download references

Funding

Financial support for obtaining the anionic and cationic polyacrylamides and the bentonite was provided by TUBITAK (The Scientific and Technological Research Council of Turkey) under 3501-Career Development Program with 114M282.

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Correspondence to Hakki O. Ozhan.

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Ozhan, H.O. Determination of mechanical and hydraulic properties of polyacrylamide-added bentonite-sand mixtures. Bull Eng Geol Environ 80, 2557–2571 (2021). https://doi.org/10.1007/s10064-020-02062-9

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  • DOI: https://doi.org/10.1007/s10064-020-02062-9

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