The positronium negative ion: Classical properties aaand semiclassical quantization

Abstract:

Properties of collinear and planar periodic orbits for the positronium negative ion are examined with respect to the possibilities for semiclassical quantization. In contrast to other two-electron atomic systems as helium and H^- the relevant orbits for quantization are fully stable and permit a full torus quantization. However, for lower excitations the area of stability in phase-space is too small for a reliable torus quantization. Instead, a quasi-separability of the three-body system is used to apply effective one-dimensional (WKB) quantization.