Large copper isotope effect on the pseudogap in the high-temperature superconductor HoBa ₂ Cu ₄ O ₈

Abstract:

The copper isotope effect (⁶³Cu vs. ⁶⁵Cu) on the relaxation rate of crystal-field excitations in the slightly underdoped high-temperature superconductor HoBa₂Cu₄O₈ has been investigated by inelastic neutron scattering. For the ⁶³Cu compound there is clear evidence for the opening of an electronic gap in the normal state at T ^* ≈ 160 K far above T _c = 79.0 K. Upon substitution of ⁶³Cu by ⁶⁵Cu, T _c decreases marginally to 78.6 K, whereas T ^* is increased to about 185 K. This large copper isotope shift Δ T ^* ( Cu ) = T ^* ( ⁶⁵ Cu ) - T ^* ( ⁶³ Cu ) ≈ 25 K - together with the corresponding oxygen isotope shift Δ T ^* ( O ) = T ^* ( ¹⁸ O ) - T ^* ( ¹⁶ O ) ≈ 50 K found in an earlier investigation - suggests that phonons or lattice fluctuations involving both the copper and the oxygen ions are important for the pairing mechanism in high-T _c materials.