Abstract
The morphology on collapsed monolayers at the air-water interface has been studied using phase contrast microscopy. It is found that the transition from randomly distributed to quasi-one dimensional crack pattern takes place, depending on the pH value of the subphase and the presence of specific divalent metal ions. In these macroscopic patterns, the former exhibits a surface roughening due to a monolayer buckling while the latter becomes more smooth and uniform. The occurrence of the former is instantaneous and the latter follows a slow dynamics, i.e., the crack propagation in monolayers occurs with a delay for crack nucleation. Thus the change of pattern indicates the existence of a dynamic transition. The transition is discussed with the scenario of a crack instability in brittle materials. The changes of viscous nature and of ion binding, and the compression direction probably operate for the observed behavior effectively.
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Hatta, E., Suzuki, D. & Nagao, J. Morphology transition and slow dynamics in the collapse of amphiphilic monolayers at the air-water interface. Eur. Phys. J. B 11, 609–614 (1999). https://doi.org/10.1007/s100510051188
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DOI: https://doi.org/10.1007/s100510051188