Abstract:
We show how to compute the optical functions (reflectivity, transmission, and absorption) of polydiacetylene chains diluted in their monomer matrix exposed to a uniform electric field in the chain direction, in the excitonic energy region. Adopting a model electron-hole potential, we derived an analytical expression for the effective chain susceptibility, which gives the optical functions. The resulting absorption shows excitonic peaks below the gap and Franz-Keldysh oscillations above the gap. The method has been applied for a 3BCMU polydiacetylene chain, showing a good agreement with experimental spectra.
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Received 5 November 1998 and Received in final form 23 February 1999
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Dressler, M., Bassani, F. & Czajkowski, G. Electro-optical properties of excitons in polydiacetylene chains. Eur. Phys. J. B 10, 681–686 (1999). https://doi.org/10.1007/s100510050900
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DOI: https://doi.org/10.1007/s100510050900