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Theoretical Study on the Second Hyperpolarizabilities for Small Radical Systems

  • 5th International Conference on NEAR FIELD OPTICS and RELATED TECHNOLOGIES (NFO-5)
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Abstract

We study the second hyperpolarizabilities (ɣ) for anion, neutral and cation radicals and find that magnitudes of ɣ (| ɣ |) of the radicals are sensitively influenced by features of each charged state. It is also found that electron-correlation dependence of ɣ could be related to the resonance structure contributing to the ground state of the molecules.

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Authors and Affiliations

  1. Graduate School of Science, Osaka University, Department of Chemistry, Osaka, 560-0043, Japan

    Satoru Yamada, Masayoshi Nakano, Masamichi Nishino & Kizashi Yamaguchi

Authors
  1. Satoru Yamada
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  2. Masayoshi Nakano
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  3. Masamichi Nishino
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  4. Kizashi Yamaguchi
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Corresponding author

Correspondence to Satoru Yamada.

Additional information

This paper was originally presented at the 5th International Conference on NEAR FIELD OPTICS and RELATED TECHNOLOGIES (NFO-5), which was held on December 6–10, 1998 at Coganoi Bay Hotel, Shirahama, Japan, in cooperation with the Japan Society of Applied Physics and Mombusho Grant-in Aid for Scientific Research on Priority Areas “Near-field Nano-optics” Project, sponsored by Japan Society for the Promotion of Science.

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Yamada, S., Nakano, M., Nishino, M. et al. Theoretical Study on the Second Hyperpolarizabilities for Small Radical Systems. OPT REV 6, 237–241 (1999). https://doi.org/10.1007/s10043-999-0237-7

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  • DOI: https://doi.org/10.1007/s10043-999-0237-7

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