Abstract
The groundwater system of the Eva Verda basin (Saint Marcel Valley, southern side of the middle Aosta Valley, Italy) has many springs that can be used as sources for drinking water. This area is near the disused Servette mine, which can be a pollutant source (metals and sulfides) for the springs located downhill. Aquifer characterization was done using a multidisciplinary approach: geostructural, lithological, hydrogeological and geochemical. In particular, the geostructural analysis showed that the preferential water-flow direction is controlled by tectonics and that it has a trend along the slope toward the downhill springs. The mine drainage flow direction is in agreement with this trend and can pollute the springs. Chemical analysis revealed three water groups: (1) SO 2-4 –Ca2+–Mg2+ rich water (mine drainage), (2) HCO -3 –SO 2-4 –Ca2+ rich water and (3) HCO -3 –Ca2+ rich water (freshwater). The second group of water results from the different percentage mix between the first and the third waters. The low percentage of mine polluted water demonstrates that there is a high dilution and low pollution of waters that can be exploited for drinking.
Résumé
Le système hydrogéologique du basin versant d’Eva Verda (Vallée de Saint-Marcel, affluent méridional de la vallée moyenne d’Aoste, Italie) comprend tant de sources qu’elles sont utilisées pour l’alimentation en eau potable. Cette région est située à proximité de la mine désaffectée de la Servette, qui peut être à l’origine de contaminations (métaux et sulfates) pour les sources situées à l’aval. La caractérisation de l’aquifère a été réalisée selon une approche pluridisciplinaire : géologie structurale, lithologie, hydrogéologie et géochimie. L’analyse structurale a montré que les directions des écoulements préférentiels de l’eau est contrôlé par la tectonique et influence l’organisation des sources le long de la pente. La direction de l’écoulement issu du drainage minier est en cohérence avec cette organisation et peut ainsi contaminer les sources. Les analyses chimiques mettent en évidence trois familles distinctes: (1) eau riche en SO 2-4 –Ca2+–Mg2+ (drainage minier), (2) eau riche en HCO -3 –SO 2-4 –Ca2+ et (3) eau riche en HCO -3 –Ca2+ (eau douce). Le deuxième groupe d’eau est le résultat d’un mélange entre les deux autres groupes. Le faible pourcentage d’eau contaminée par le drainage minier indique qu’au vu du faible taux de dilution et de pollution, l’eau des sources peut être utilisé pour l’alimentation en eau potable.
Resumen
El sistema de aguas subterráneas de la cuenca Eva Verda (Valle Saint Marcel – parte meridional del Valle Aosta medio en Italia) tiene muchos manantiales que pueden ser usados como fuente de agua potable. Este área está cerca de la mina abandonada Servette, que puede ser una fuente de contaminantes (metales y sulfuros) para los manantiales situados pendiente abajo. La caracterización del acuífero fue hecha usando un enfoque multidisciplinario: geoestructural, litológico, hidrogeológico y geoquímica. En particular, el análisis geoestructural mostró que el sentido preferencial de flujo del agua está controlado por la tectónica y que ello tiene una tendencia a lo largo de la pendiente hacia los manantiales ubicadas en la parte baja. El sentido de flujo del drenaje de la mina está de acuerdo con esta tendencia y puede contaminar los manantiales. Los análisis químicos revelaron tres grupos de agua: (1) agua rica en HCO -3 –SO 2-4 –Ca2+ (drenaje de la mina), (2) agua rica en HCO -3 –SO 2-4 –Ca2+ y (3) agua rica en HCO -3 –Ca2+ (agua dulce). El segundo grupo de agua es la resultante de una mezcla de diferentes porcentajes entre la primera y tercera agua. El bajo porcentaje de agua contaminada de la mina demuestra que existe una alta dilución y baja contaminación de las aguas que pueden ser explotadas para el consumo.
摘要
Saint Marcel峡谷位于意大利中Aosta峡谷南侧的Eva Verda盆地含水层系统有许多可以饮用的泉水出露。该区附近废弃的Servette矿, 可能是山下泉水的污染源 (金属和硫化物) 。采用多手段方法描述了含水层特征, 包括地质构造、岩性、水文地质和地球化学。地质构造分析表明, 优势流向受构造控制, 并有向坡下泉水出露点方向流动的趋势。尾矿水流向与此流向一致, 会污染泉水。水化学分析揭示了三种类型的水: (i) SO 2-4 -Ca2+- Mg2+型水 (尾矿水), (ii) HCO -3 - SO 2-4 - Ca2+型水, (iii) HCO -3 - Ca2+型水 (淡水) 。第二种水是由第一种和第三种水按不同比例混合而成。矿坑污染水的比例较低说明该水存在高稀释和低污染, 可作为饮用水加以开发利用。
Resumo
O sistema de águas subterrâneas da bacia de Eva Verda (vale de Saint Marcel – lado sul do vale médio de Aosta, Itália) possui muitas nascentes que podem ser utilizadas como origens para água de abastecimento. Esta área é próxima da mina abandonada de Servette, que pode ser uma fonte poluidora (metais e sulfuretos) para as nascentes situadas abaixo na encosta. A caracterização do aquífero foi feita utilizando uma aproximação multidisciplinar: geoestrutural, litológica, hidrogeológica e geoquímica. Em particular, a análise geoestrutural mostrou que a direcção preferencial de fluxo é controlada pela tectónica e que este apresenta uma direcção tendencial de escoamento ao longo do declive em direcção às nascentes abaixo na encosta. A direcção de escoamento de drenagem da mina está de acordo com esta direcção e pode poluir as nascentes. As análises químicas revelaram três grupos de águas: (1) águas ricas em HCO -3 –SO 2-4 –Ca2+ (drenagem da mina), (2) águas ricas em HCO -3 –SO 2-4 –Ca2+ e (3) águas ricas em HCO -3 –Ca2+ (água doce). O segundo grupo de águas resulta da diferente percentagem de mistura entre o primeiro e o terceiro grupo. A baixa percentagem de água poluída pela mina demonstra que existe uma diluição elevada e uma poluição reduzida das águas, as quais podem ser exploradas para abastecimento de água potável.









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Acknowledgements
We would like to thank the Aosta Valley Region and Saint-Marcel municipalities for their assistance. In particular, we thank Prof. C. Dossi for the use of the Analytical Chemistry Laboratory of Insubria University. The authors are also indebted to Prof. G. Godard (Institut de Physique du Globe de Paris et Université Paris-Diderot, France), Dr S. Galli, Prof. N. Masciocchi, Dr A. Centurini (Università degli Studi dell’Insubria, Como, Italy) and Eng. C. Lorenzo (Politecnico di Milano, Italy). Dr S. Terrana and Dr R. Gambillara contributed equally to this work.
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Terrana, S., Gambillara, R., Scesi, L. et al. Characterization of the Eva Verda basin aquifer (Saint Marcel, Aosta Valley, Italy) through geochemical and geostructural methods and analysis. Hydrogeol J 18, 487–499 (2010). https://doi.org/10.1007/s10040-009-0494-3
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DOI: https://doi.org/10.1007/s10040-009-0494-3


