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Effect of pH on the precipitation of hydroxyapatite on silica gels

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Materials Research Innovations

Abstract.

Silica-HAp composites have been produced with particle size ranging from several nm to few μm, through control of the pH of the solution, which also controls morphology. A calcium ions reservoir has been made available as a Ca/EDTA soluble complex allowing the production of HAp at low temperature and short periods of time (hours). The presence of silica seems to promote the formation of HAp under these conditions.

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References

  1. Park JB (1984) Biomaterials science and engineering. Plenum Press, New York

  2. Ravaglioli A, Krajewski A (1992) Bioceramics: Materials properties and applications. Chapman & Hall, London

  3. Khon DH, Ducheyne P (1991) Materials science and technology: A comprehensive treatment, medical and dental materials, vol. 14, VCH

    Google Scholar 

  4. Yoshimura M, Suda H (1994) Hydroxyapatite and related materials. CRC Press, Boca Raton

  5. Monma H, Kamiya Y (1987) J Mater Sci 22: 4247

    CAS  Google Scholar 

  6. Fang Y, Agrawal DM (1992) J Mater Res 7: 8

    Google Scholar 

  7. Black J (1992) Biological performance of materials. In: Fundamentals of biocompatibility, 2nd edn. Marcel Dekker Inc, New York, p 3

  8. LeGeros RZ (1988) Adv Dent Res 2: 164

    CAS  PubMed  Google Scholar 

  9. Arita I, Wilkinson D, Mondragron M, Castaño VM (1995) Biomaterials 16: 403

    Article  CAS  PubMed  Google Scholar 

  10. Arita I, Wilkinson D, Castaño VM (1994) J Mater Sci: Mater In Medicine 6: 19

  11. Lavenia C (1991) Am Ceram Soc Bull 70: 95

    Google Scholar 

  12. Helmus MN (1991) MRS Bull 16: 33

    CAS  Google Scholar 

  13. Brinker CJ, Scherer GW (1990) Sol-gel science. Academic Press, San Diego

  14. Rivera E, Bonilla M, Hernández R, Rodríguez R, Castaño VM (1997) J Mater Synthesis and Proc 5: 153

    CAS  Google Scholar 

  15. Rivera E, Brostow W, Rodríguez R, Castaño VM (2001) J Mater Sci: Mater In Med (in press)

    Google Scholar 

  16. Bris E, Hardouin P (1998) Les matériaux en phosphate de calcium. Aspects fondamentaux, Sauramps medical, Montpellier

  17. Mao C, Li H, Cui F, Feng Q, Ma C (1999) J Mater Chem 9: 2573

    Article  CAS  Google Scholar 

  18. Ducheyne P, Beight J, Cuckler J, Evans B, Radin S (1990) Biomaterials 11: 531

    CAS  PubMed  Google Scholar 

  19. Montero ML, Saenz A, Castaño VM (2002) Mater Lett (in press)

  20. Saenz A, Salas P, Rivera E, Montero ML, Castaño VM (2002) J Mater Tech ( in press)

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Acknowledgements.

One of us (A.S.) acknowledges the financial support obtained from ICTP via CLAF-M for research visits to Mexico We also acknowledge the financial support from ANUIES-CSUCA for scientific visits to Mexico (A.S. and M.M.) and to Costa Rica (V.C.). and CONACYT through project 32605-U. We are also thankful to L. Carapia, P. Salas, E. Méndez and T. Falcon.

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Correspondence to Victor M. Castaño.

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Sáenz, A., Montero, M.L., Mondragón, G. et al. Effect of pH on the precipitation of hydroxyapatite on silica gels. Mat Res Innovat 7, 68–73 (2003). https://doi.org/10.1007/s10019-003-0230-x

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  • DOI: https://doi.org/10.1007/s10019-003-0230-x

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