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Synthesis of poly[(amic acid)-co-(amic ester)] precursors and studies of their imidization using FT-IR and FT-Raman spectroscopy

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Materials Research Innovations

Abstract.

A pollyimide precursor, poly[(amic acid)-co-(amic ester)] (PAAE), was prepared by partial esterification of poly(amic acid) (PAA). To investigate the thermal imidization behavior of PAAE, several different PAAEs were synthesized by varying the fraction of the amic ester moiety. They were then imidized using a stepwise heating process. The conversion of PAAE to polyimide was investigated as a function of ester fraction and temperature by monitoring the changes in the imide II (1374 cm–1) and CH stretching vibrational modes (2935 cm–1) using FT-IR and FT-Raman spectroscopy, respectively. The degree of imidization for a given temperature was compared with expected values.

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Acknowledgement.

This work was supported by Korea Science and Engineering Foundation (KOSEF) (Grant R05-2000-00017).

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Authors and Affiliations

  1. Department of Polymer Science and Technology, Chonbuk National University, Chonju 561-756, Korea

    Keunok Han Yu, Yang Hyun Yoo, John Moon Rhee & Myong-Hoon Lee

  2. Department of Chemistry, Kunsan National University, Chonbuk 573-701, Korea

    Soo-Chang Yu

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  1. Keunok Han Yu
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  2. Yang Hyun Yoo
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  3. John Moon Rhee
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  4. Myong-Hoon Lee
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Correspondence to Keunok Han Yu.

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Yu, K.H., Yoo, Y.H., Rhee, J.M. et al. Synthesis of poly[(amic acid)-co-(amic ester)] precursors and studies of their imidization using FT-IR and FT-Raman spectroscopy. Mat Res Innovat 7, 51–56 (2003). https://doi.org/10.1007/s10019-002-0225-z

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  • DOI: https://doi.org/10.1007/s10019-002-0225-z

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