Abstract
The composite membrane (PDFP-POPM) based on the blending of poly(vinylidene fluoride-co-hexafluoropropylene) (PDFP) and POPM (the copolymer of organic palygorskite and methyl methacrylate) was prepared by the phase-inversion method, and a gel polymer electrolyte (GPE) was obtained when the PDFP-POPM was activated by absorbing liquid electrolyte (LE). The SEM morphologies showed that the PDFP-POPM had a porous structure. The XRD results indicated that PDFP-POPM was an amorphous polymer and that the POPM could effectively suppress the crystallization of PDFP. The lithium ion transference number of GPE was higher than that of pristine POPM- and PDFP-based GPE. When the mass concentration of PDFP was 40%, the uptake of the PDFP-POPM and ionic conductivity of GPE reached the maximum values of 164% and 2.37 mS/cm, respectively. The electrochemical stability window of Li/GPE/SS batteries was over 4.7 V (vs. Li+/Li), and the Li/40PDFP-POPM GPE/LiFePO4 battery exhibited good cycling performance. The discharge capacity of the battery was 145mAh g−1 after 100 cycles and the columbic efficiency was over 95%.
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References
Castillo J, Qiao L, Santiago A, Judez X, Sáenz de Buruaga A, Jiménez-Martín G, Armand M, Zhang H, Li C (2022) Perspective of polymer-based solid-state Li-S batteries. Energy Mater 2(1):200003
Xiong X, Yan W, Zhu Y, Liu L, Fu L, Chen Y, Yu N, Wu Y, Wang B, Xiao R (2022) Li4Ti5O12 coating on copper foil as ion redistributor layer for stable lithium metal anode. Adv Energy Mater 12(13):2103112
Yuan J-J, Sun C-C, Fang L-F, Song Y-Z, Yan Y, Qiu Z-L, Shen Y-J, Li H-Y, Zhu B-K (2021) A lithiated gel polymer electrolyte with superior interfacial performance for safe and long-life lithium metal battery. J Energy Chem 55:313–322
Wang Y, Qiu J, Peng J, Li J, Zhai M (2017) One-step radiation synthesis of gel polymer electrolytes with high ionic conductivity for lithium-ion batteries. J Mater Chem A 5(24):12393–12399
Dhatarwal P, Choudhary S, Sengwa RJ (2018) Electrochemical performance of Li+-ion conducting solid polymer electrolytes based on PEO–PMMA blend matrix incorporated with various inorganic nanoparticles for the lithium ion batteries. Composites Commun 10:11–17
Li H, Chen YM, Ma XT, Shi JL, Zhu BK, Zhu LP (2011) Gel polymer electrolytes based on active PVDF separator for lithium ion battery. I: preparation and property of PVDF/poly(dimethylsiloxane) blending membrane. J Membr Sci 379(1–2):397–402
Wang G, Liu H, Liu J, Qiao S, Lu GM, Munroe P, Ahn H (2010) Mesoporous LiFePO4/C nanocomposite cathode materials for high power lithium ion batteries with superior performance. Adv Mater 22(44):4944–4948
Song A, Huang Y, Zhong X, Cao H, Liu B, Lin Y, Wang M, Li X (2017) Gel polymer electrolyte with high performances based on pure natural polymer matrix of potato starch composite lignocellulose. Electrochim Acta 245:981–992
Cheng X, Pan J, Zhao Y, Liao M, Peng H (2018) Gel polymer electrolytes for electrochemical energy storage. Adv Energy Mater 8(7):1702184–1702199
Liu B, Huang Y, Cao HJ, Zhao L, Huang YX, Song A, Lin YH, Li X, Wang MS (2018) A novel porous gel polymer electrolyte based on poly(acrylonitrile-polyhedral oligomeric silsesquioxane) with high performances for lithium-ion batteries. J Membr Sci 545:140–149
Kataoka H, Saito Y, Sakai T, Quartarone E, Mustarelli P (2000) Conduction mechanisms of PVDF-type gel polymer electrolytes of lithium prepared by a phase inversion process. J Phys Chem B 104(48):11460–11464
Li Y, Zhu J, Zhu P, Yan C, Jia H, Kiyak Y, Zang J, He J, Dirican M, Zhang X (2018) Glass fiber separator coated by porous carbon nanofiber derived from immiscible PAN/PMMA for high-performance lithium-sulfur batteries. J Membr Sci 552:31–42
Tian L, Wang M, Xiong L, Guo H, Huang C, Zhang H, Chen X (2018) The effect of different mixed organic solvents on the properties of p(OPal-MMA) gel electrolyte membrane for lithium ion batteries. Appl Sci 8(12):2587–2597
Li W, Yu, Pang Y, Liu J, Yuan, Liu G, Hui, Wang Y, Gang, Xia Y, Yao (2017) A PEO-based gel polymer electrolyte for lithium ion batteries. RSC Adv 7:23494–23501
Yuan C, Li J, Han P, Lai Y, Zhang Z, Liu J (2013) Enhanced electrochemical performance of poly(ethylene oxide) based composite polymer electrolyte by incorporation of nano-sized metal-organic framework. J Power Sources 240:653–658
Liu T, Chang ZW, Yin YB, Chen K, Zhang Y, Zhang XB (2018) The PVDF-HFP gel polymer electrolyte for Li-O2 battery. Solid State Ionics 318:88–94
Khan S, Fang CY, Ma YC, ulHaq M, Nisar M, Xu G, Liu Y, Han GR (2021) High-performance PVDF-HFP based gel polymer electrolyte modified by core-shell SiO2-PMMA for electrochromic devices. J Electrochem Soc 168(2):022504
Li X, Zhang M, He J, Wu D, Meng J, Ni P (2014) Effects of fluorinated SiO2 nanoparticles on the thermal and electrochemical properties of PP nonwoven/PVdF-HFP composite separator for Li-ion batteries. J Membr Sci 455:368–374
Jeong H-S, Hong SC, Lee S-Y (2010) Effect of microporous structure on thermal shrinkage and electrochemical performance of Al2O3/poly(vinylidene fluoride-hexafluoropropylene) composite separators for lithium-ion batteries. J Membr Sci 364(1–2):177–182
Kim KM, Park N-G, Ryu KS, Chang SH (2006) Characteristics of PVdF-HFP/TiO2 composite membrane electrolytes prepared by phase inversion and conventional casting methods. Electrochim Acta 51(26):5636–5644
Deka M, Kumar A (2010) Enhanced electrical and electrochemical properties of PMMA–clay nanocomposite gel polymer electrolytes. Electrochim Acta 55(5):1836–1842
Chen TT, Liao YH, Wang XS, Luo XY, Li XP, Li WS (2016) Investigation on high-safety lithium ion battery using polyethylene supported poly(methyl methacrylate-acrylonitrile-butyl acrylate) copolymer based gel electrolyte. Electrochim Acta 191:923–932
Tan SM, Johan MR (2011) Effects of MnO2 nano-particles on the conductivity of PMMA-PEO-LiClO4-EC polymer electrolytes. Ionics 17(6):485–490
Tian L, Xiong L, Chen X, Guo H, Zhang H, Chen X (2018) Enhanced electrochemical properties of gel polymer electrolyte with hybrid copolymer of organic palygorskite and methyl methacrylate. Materials 11(10):1814
Ahmad AL, Farooqui UR, Hamid NA (2018) Porous (PVDF-HFP/PANI/GO) ternary hybrid polymer electrolyte membranes for lithium-ion batteries. RSC Adv 8(45):25725–25733
Saikia D, Kumar A (2004) Ionic conduction in P(VDF-HFP)/PVDF–(PC + DEC)–LiClO 4 polymer gel electrolytes. Electrochim Acta 49(16):2581–2589
Bose P, Deb D, Bhattacharya S (2019) Ionanofluid plasticized P(VDF-HFP) nanocomposite gel polymer electrolyte for safer, high energy density lithium batteries. Mater Chem Front 7:1–36
Khan S, Fang C, Ma Y, Haq Mu, Nisar M, Xu G, Liu Y, Han G (2021) High-performance PVDF-HFP based gel polymer electrolyte modified by core-shell SiO2-PMMA for electrochromic devices. J Electrochem Soc 168(2):022504
Zhai W, Zhu Hj, Wang L, Liu XM, Yang H (2014) Study of PVDF-HFP/PMMA blended micro-porous gel polymer electrolyte incorporating ionic liquid [BMIM]BF4 for lithium ion batteries. Electrochim Acta 133:623–630
Xie H, Tang ZY, Li Z, He YB, Liu Y, Wang H (2008) PVDF-HFP composite polymer electrolyte with excellent electrochemical properties for Li-ion batteries. J Solid State Electrochem 12(11):1497–1502
Yan W, Gao X, Jin X, Liang S, Xiong X, Liu Z, Wang Z, Chen Y, Fu L, Zhang Y, Zhu Y, Wu Y (2021) Nonporous gel electrolytes enable long cycling at high current density for lithium-metal anodes. ACS Appl Mater Interfaces 13(12):14258–14266
Zhu YS, Xiao SY, Li MX, Chang Z, Wang FX, Gao J, Wu YP (2015) Natural macromolecule based carboxymethyl cellulose as a gel polymer electrolyte with adjustable porosity for lithium ion batteries. J Power Sources 288:368–375
Idris NH, Rahman MM, Wang J-Z, Liu H-K (2012) Microporous gel polymer electrolytes for lithium rechargeable battery application. J Power Sources 201:294–300
Saito Y, Kataoka H, Quartarone E, Mustarelli P (2002) Carrier migration mechanism of physically cross-linked polymer gel electrolytes based on PVDF membranes. J Phys Chem B 106(29):7200–7204
Zhai W, Zhu H-J, Wang L, Liu X-M, Yang H (2014) Study of PVDF-HFP/PMMA blended micro-porous gel polymer electrolyte incorporating ionic liquid [BMIM]BF4 for lithium ion batteries. Electrochim Acta 133:623–630
Zhao M, Zuo X, Ma X, Xiao X, Liu J, Nan J (2017) Self-supported PVdF/P(VC-VAc) blended polymer electrolytes for LiNi0.5Mn1.5O4/Li batteries. J Membr Sci 532:30–37
Thankamony RL, Chu H, Lim S, Yim T, Kim YJ, Kim TH (2014) Preparation and characterization of imidazolium-PEO-based Ionene/PVDF(HFP)/LiTFSI as a novel Gel polymer electrolyte. Macromol Res 23(1):38–44
Xiao Y, Jin Z, He L, Ma S, Wang C, Mu X, Song L (2020) Synthesis of a novel graphene conjugated covalent organic framework nanohybrid for enhancing the flame retardancy and mechanical properties of epoxy resins through synergistic effect. Compos B Eng 182:107616
Zhu Y, Wang F, Liu L, Xiao S, Chang Z, Wu Y (2013) Composite of a nonwoven fabric with poly(vinylidene fluoride) as a gel membrane of high safety for lithium ion battery. Energy Environ Sci 6(2):618–624
Wang YJ, Kim D (2007) PEGDA/PVdF/F127 gel type polymer electrolyte membranes for lithium secondary batteries. J Power Sources 166(1):202–210
Gopalan A, Santhosh P, Manesh K, Nho J, Kim S, Hwang C, Lee K (2008) Development of electrospun PVdF–PAN membrane-based polymer electrolytes for lithium batteries. J Membr Sci 325(2):683–690
Aram E, Ehsani M, Khonakdar HA (2015) Improvement of ionic conductivity and performance of quasi-solid-state dye sensitized solar cell using PEO/PMMA gel electrolyte. Thermochim Acta 615:61–67
Shi J, Xiong H, Yang Y, Shao H (2018) Nano-sized oxide filled composite PEO/PMMA/P(VDF-HFP) gel polymer electrolyte for rechargeable lithium and sodium batteries. Solid State Ionics 326:136–144
Bac A, Ciosek M, Bukat M, Marczewski M, Marczewska H, Wieczorek W (2006) The effect of type of the inorganic filler and dopant salt concentration on the PEO–LiClO4 based composite electrolyte–lithium electrode interfacial resistivity. J Power Sources 159(1):405–411
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The authors acknowledge the financial support by Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (No. E1390104).
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Yuan, G., Guo, H., Bo, L. et al. Study of poly (organic palygorskite-methyl methacrylate)/poly(vinylidene fluoride-co-hexafluoropropylene) blended gel polymer electrolyte for lithium-ion batteries. J Solid State Electrochem 27, 455–465 (2023). https://doi.org/10.1007/s10008-022-05339-z
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DOI: https://doi.org/10.1007/s10008-022-05339-z