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Enhanced corrosion and wear resistance of Zn–Ni/Cu–Al2O3 composite coating prepared by cold spray

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Abstract

In order to improve the cathodic protection and wear resistance of cold spraying Zn-based coatings, Zn–Ni/Cu–Al2O3 composite coating was prepared by co-depositing Zn powders, nickel-coated Cu powders, and Al2O3 powders on the steel substrate using the low-pressure cold spraying method. The structure and composition of Zn–Ni/Cu–Al2O3 coatings were analyzed by scanning electron microscopy, energy dispersive spectrum analysis, and X-ray diffraction, respectively. And their wear and corrosion resistance were tested. The results show that the structure of the Zn–Ni/Cu–Al2O3 composite coating is compact and the nickel powder is evenly distributed in the coating. Compared with the Zn–Al2O3 coating and Zn–Cu–Al2O3 coating, the Zn–Ni/Cu–Al2O3 composite coating has better wear resistance in air and stronger corrosion resistance in the 3.5 wt.% NaCl solutions. The Zn–Ni/Cu–Al2O3 coating has the lowest corrosion rate and maximum impedance after the immersion and scratch tests. Due to the promoting effect of Ni, the Zn–Ni/Cu–Al2O3 coating can quickly form a dense protective layer of corrosion products, which makes the Zn–Ni/Cu–Al2O3 composite coating has better cathodic protection and defect self-repair performance.

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Funding

This work was supported by the National Natural Science Foundation of China (No. 52105176 and No. 51709049), the National Key R&D Program of China (2021YFB3400601), and the Program for Guangdong Introducing Innovative and Entrepreneurial Teams (2019BT02Z393).

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Correspondence to Guibin Tan or Liuyan Zhang.

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Liu, Y., Tan, G., Tang, J. et al. Enhanced corrosion and wear resistance of Zn–Ni/Cu–Al2O3 composite coating prepared by cold spray. J Solid State Electrochem 27, 439–453 (2023). https://doi.org/10.1007/s10008-022-05335-3

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  • DOI: https://doi.org/10.1007/s10008-022-05335-3

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