Abstract
V2O5 is a promising candidate for cathode active material for Li-ion batteries due to its high theoretical specific capacity but suffers from poor rate capability and cycling stability. To cover these disadvantages, in this work, a low-cost and facile sol-gel method to prepare TiO2-coated V2O5 microspheres is developed for the first time. The prepared V2O5@TiO2 composite could deliver an initial capacity of 297.7 mAh g−1 at a current density of 100 mA g−1 in the potential range of 2.0–4.0 V (vs. Li+/Li). Moreover, the capacity of 247.0 mA h g−1 could be delivered at 1000 mA g−1, and 86% of capacity could be retained after 100 cycles. Even at a large current density of 5000 mA g−1, it could still deliver a high capacity of 197.3 mA h g−1 with a capacity retention of 93.5% after 200 cycles. The outstanding rate and cycling stability of V2O5@TiO2 composite indicate that it holds bright prospect for using as an excellent cathode material for rechargeable lithium batteries.
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Acknowledgments
We thank Ms. Jiamei Liu at the Instrument Analysis Center of Xi’an Jiaotong University for her assistance with XPS measurement.
Funding
This work was financially supported by the National Natural Science Foundation of China (Grant no. 51777152), the Natural Science Foundation of Shaanxi Province (Grant no. 2019JLZ-09), the Fundamental Research Funds for the Central Universities (Granted nos. XJJ2018055 and XJJ2016020), and the Scientific Research Foundation for the Returned Overseas Chinese Scholars.
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Ma, M., Ji, F., Du, X. et al. V2O5@TiO2 composite as cathode material for lithium-ion storage with excellent performance. J Solid State Electrochem 24, 2419–2425 (2020). https://doi.org/10.1007/s10008-020-04782-0
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DOI: https://doi.org/10.1007/s10008-020-04782-0