Skip to main content

Advertisement

Log in

MOF assisted synthesis of new porous nickel phosphate nanorods as an advanced electrode material for energy storage application

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

A highly uniform porous 1-D nickel pyrophosphate (PNP) nanorods have been developed by a simple and green approach for the first time and served as excellent electrode materials for energy storage application. The as-prepared materials were characterized by XRD, FE-SEM, HR-TEM and cyclic voltammetry methods. The PNP materials have demonstrated good performance in capacitance, with a higher specific capacitance of 1517 F g−1 at 0.5 A g−1, good capacity retention (58%) at 5 A g−1, and excellent cyclic stability up to 3000 charge-discharge cycles (81.5%).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Parthiban P, Karthikeyan K et al (2019) Understanding the thermal treatment effect of two-dimensional siloxene sheets and the origin of superior electrochemical eneregy storage performances. ACS Appl Mater Interfaces 11:624–633

    Google Scholar 

  2. Ko T-H, Radhakrishnan S et al (2016) Core/shell-like NiCo2O4-decorated MWCNT hybrids prepared by a dry synthesis technique and its supercapacitor applications. Mater Lett 166:105–109

    CAS  Google Scholar 

  3. Venkadesh A, Radhakrishnan S, Mathiyarasu J (2017) Eco-friendly synthesis and morphology-dependent superior electrocatalytic properties of CuS nanostructures. Electrochim Acta 246:544–552

    CAS  Google Scholar 

  4. Radhakrishnan S, Kim HY, Kim BS (2016) Expeditious and eco-friendly fabrication of highly uniform microflower superstructures and their applications in highly durable methanol oxidation and high-performance supercapacitors. J Mater Chem A 4:12253–12262

    CAS  Google Scholar 

  5. Pan N, Wang B, Wang X, Hou JG (2010) Manipulating and tailoring the properties of 0-D and 1-D nanomaterials. J Mater Chem 20:5567–5581

    CAS  Google Scholar 

  6. Radhakrishnan S, Sumathi C, Umar A et al (2013) Polypyrrole-poly(3,4-ethylenedioxythiophene)-Ag (PPy-PEDOT-Ag) nanocomposite films for label-free electrochemical DNA sensing. Biosens Bioelectron 47:133–140

    CAS  PubMed  Google Scholar 

  7. Underhill AE, Watkins DM (1980) One-dimensional metallic complexes. Chem Soc Rev 9:429–448

    CAS  Google Scholar 

  8. Liu Z, Xu J, Chen D, Shen G (2015) Flexible electronics based on inorganic nanowires. Chem Soc Rev 44:161–192

    CAS  PubMed  Google Scholar 

  9. Vimal Kumar M, Karthikeyan K et al (2019) Two dimensional famatinite sheets decorated on reduced graphene oxide: a novel electrode for high performance supercapacitors. J Power Sources 433:126648

    Google Scholar 

  10. Shukla AK, Banerjee A, Ravikumar MK, Jalajakshi A (2012) Electrochemical capacitors: technical challenges and prognosis for future markets. Electrochim Acta 84:165–173

    Google Scholar 

  11. Wang F, Wu X, Yuan X et al (2017) Latest advances in supercapacitors: from new electrode materials to novel device designs. Chem Soc Rev 46:6816–6854

    CAS  PubMed  Google Scholar 

  12. Shao Y, Li J, Li Y et al (2017) Flexible quasi-solid-state planar micro-supercapacitor based on cellular graphene films. Mater Horizons 4:1145–1150

    CAS  Google Scholar 

  13. Xu J, Lin F, Doeff MM, Tong W (2017) A review of Ni-based layered oxides for rechargeable Li-ion batteries. J Mater Chem A 5:874–901

    CAS  Google Scholar 

  14. Ko T-H, Seong J-G et al (2019) Dual functional nickel cobalt/MWCNT composite electrode-based electrochemical capacitor and enyzymeless glucose biosensor applications: influence of Ni/Co molar ratio. J Ind Eng Chem 73:1–7

    CAS  Google Scholar 

  15. Zhang L, Shi D, Liu T et al (2019) Nickel-based materials for supercapacitors. Mater Today 25:35–65

    CAS  Google Scholar 

  16. Chen Z, Xiong D-B et al (2019) Construction of a novel hierarchical structured NH4-co-Ni phosphate toward an ultrastable aqueous hybrid capacitor. Nanoscale 8:6636–6645

    Google Scholar 

  17. Wang M, Jin F et al (2017) Multihierarchical strucutre of hybridized phosphates anchored on reduced graphene oxide for high power hybrid energy storage devices. ACS Sustain Chem Eng 5:5679–5685

    CAS  Google Scholar 

  18. Wang M, Zhao Y et al (2018) Interference-rich core-shell ammonium nickel cobalt phosphate for high performance aquous hybrid energy storage device without a depressed power density. Electrochim Acta 272:184–191

    CAS  Google Scholar 

  19. Zhao Y, Chen Z et al (2016) Hybridized phosphate with ultrathin nanoslices and single crystal microplatelets for high performance supercapacitors. Sci Rep 6:17613

    CAS  PubMed  PubMed Central  Google Scholar 

  20. Wang B, Yang Y et al (2019) Nickel cobalt pyrophosphate porous microplates for high performance and durable charge storage. Sci Adv Mater 11:396–402

    CAS  Google Scholar 

  21. Sun P, Li Z, Zhang L et al (2018) Synthesis of cobalt-nickel pyrophosphates/N-doped graphene composites with high rate capability for asymmetric supercapacitor. J Alloys Compd 750:607–616

    CAS  Google Scholar 

  22. Rezaei M, Najafi Chermahini A, Dabbagh HA et al (2019) Furfural oxidation to maleic acid with H2O2 by using vanadyl pyrophosphate and zirconium pyrophosphate supported on well-ordered mesoporous KIT-6. J Environ Chem Eng 7:102855

    Google Scholar 

  23. Wei C, Yang S, Liu W et al (2019) Hierarchically porous bowknot-like sodium doped Ni2P2O7 -Co2P2O7 with improved supercapacitor performances. Appl Surf Sci 465:763–771

    CAS  Google Scholar 

  24. Moosavifard SE, Kaverlavani SK, Shamsi J, Bakouei A (2017) Hierarchical multi-shelled nanoporous mixed copper cobalt phosphide hollow microspheres as a novel advanced electrode for high-performance asymmetric supercapacitors. J Mater Chem A 5:18429–18433

    CAS  Google Scholar 

  25. Pramanik M, Imura M, Lin J et al (2015) Shape-controlled synthesis of mesoporous iron phosphate materials with crystallized frameworks. Chem Commun 51:13806–13809

    CAS  Google Scholar 

  26. Bhaumik A, Inagaki S (2001) Mesoporous titanium phosphate molecular-sieves with ion-exchange capacity. J Am Chem Soc 123:691–696

    CAS  PubMed  Google Scholar 

  27. Zhang F, Bao Y, Ma S et al (2017) Hierarchical flower-like nickel phenylphosphonate microspheres and their calcined derivatives for supercapacitor electrodes. J Mater Chem A 5:7474–7481

    CAS  Google Scholar 

  28. Pramanik M, Salunkhe RR, Imura M, Yamauchi Y (2016) Phosphonate-derived nanoporous metal phosphates and their superior energy storage application. ACS Appl Mater Interfaces 8:9790–9797

    CAS  PubMed  Google Scholar 

  29. Zhang R, Russo PA, Feist M et al (2017) Synthesis of nickel phosphide electrocatalysts from hybrid metal Phosphonates. ACS Appl Mater Interfaces 9:14013–14022

    CAS  PubMed  Google Scholar 

  30. Hix GB, Harris KDM (1998) Synthesis of layered nickel phosphonate materials based on a topotactic approach. J Mater Chem 8:579–584

    CAS  Google Scholar 

  31. Chen C, Zhang N, He Y et al (2016) Controllable fabrication of amorphous co-Ni pyrophosphates for tuning electrochemical performance in supercapacitors. ACS Appl Mater Interfaces 8:23114–23121

    CAS  PubMed  Google Scholar 

  32. Pang H, Zhang YZ, Run Z et al (2015) Amorphous nickel pyrophosphate microstructures for high-performance flexible solid-state electrochemical energy storage devices. Nano Energy 17:339–347

    CAS  Google Scholar 

  33. Reddy AE, Anitha T, Muralee Gopi CVV et al (2018) NiMoO4@NiWO4 honeycombs as a high performance electrode material for supercapacitor applications. Dalt Trans 47:9057–9063

    CAS  Google Scholar 

  34. Su L, Wang Y, Sha Y, Hao M (2016) Ternary active site Co3O4/NiO/MnO2 electrode with enhanced capacitive performances. J Alloys Compd 656:585–589

    CAS  Google Scholar 

  35. Wei C, Cheng C, Wang S et al (2015) Sodium-doped mesoporous Ni2P2O7 hexagonal tablets for high-performance flexible all-solid-state hybrid supercapacitors. Chem Asian J 10:1731–1737

    CAS  PubMed  Google Scholar 

  36. Niu L, Li Z, Xu Y et al (2013) Simple synthesis of amorphous NiWO4 nanostructure and its application as a novel cathode material for asymmetric supercapacitors. ACS Appl Mater Interfaces 5:8044–8052

    CAS  PubMed  Google Scholar 

  37. Zhou W, Kong D, Jia X et al (2014) NiCo2O4 nanosheet supported hierarchical core-shell arrays for high-performance supercapacitors. J Mater Chem A 2:6310–6315

    CAS  Google Scholar 

  38. Liang X, Nie K, Ding X et al (2018) Highly compressible carbon sponge supercapacitor electrode with enhanced performance by growing nickel-cobalt Sulfide nanosheets. ACS Appl Mater Interfaces 10:10087–10095

    CAS  PubMed  Google Scholar 

  39. Liu Y, Wang Z, Zhong Y et al (2017) Molecular design of mesoporous NiCo2O4 and NiCo2S4 with sub-micrometer-polyhedron architectures for efficient pseudocapacitive energy storage. Adv Funct Mater 27:1–10

    Google Scholar 

  40. Laheaar A, Przygocki P et al (2015) Appropriate methods for evaluating the efficiency and capacitive behavior of different types of supercapacitors. Electrochem Commun 60:21–25

    CAS  Google Scholar 

  41. Eftekhari A (2017) Energy efficienty: a critically important but neglected factor in battery research. Sustain. Energy Fuel 1:2053–2060

    CAS  Google Scholar 

  42. Aricò AS, Bruce P, Scrosati B, Tarascon J-M, Van Schalkwijk W (2005) Nanostructured materials for advanced energy conversion and storage devices. Nat Mater 4:366–377

    PubMed  Google Scholar 

  43. Davis ME (2002) Ordered porous materials for emerging applications. Nature 417:813–821

    CAS  Google Scholar 

Download references

Acknowledgments

Dr. S. Radhakrishnan acknowledges the DST, New Delhi, India for the DST-Inspire Faculty Award (DST/INSPIRE/04/2015/002259).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. Radhakrishnan.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

ESM 1

(DOCX 1248 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Suganya, P., Venkadesh, A., Mathiyarasu, J. et al. MOF assisted synthesis of new porous nickel phosphate nanorods as an advanced electrode material for energy storage application. J Solid State Electrochem 23, 3429–3435 (2019). https://doi.org/10.1007/s10008-019-04446-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-019-04446-8

Keywords

Navigation