Journal of Solid State Electrochemistry

, Volume 22, Issue 5, pp 1517–1524 | Cite as

Electrochemical study of PtRh/C and PtRhNi/C electrocatalysts for ethylene glycol oxidation

  • V. L. Marinho
  • L. A. Pocrifka
  • R. R. Passos
Original Paper


In the last decades, the ethylene glycol has been considered as another option of fuel, in both acid and alkaline solutions, for fuel cells application. Pt-based electrocatalysts are used in this type of technology but it is necessary to add a second or third oxophilic metal to form bimetallic or trimetallic alloys. Alloys with a second or a third metal modify electrocatalytic properties of Pt in order to overcome poisoning effects and enhancement of the electrocatalytic activity of platinum-based electrocatalyst. PtRh/C and PtRhNi/C electrocatalysts were prepared by alcohol reduction method, and their catalytic activity and stability were evaluated by cyclic voltammetry and chronoamperometry, in alkaline medium using a KOH solution with ethylene glycol in concentrations of 0.5 and 1.0 mol L−1. The results showed that the binary electrocatalyst has a higher electrocatalytic performance and obtain about 90% more energy density than PtRhNi/C. This result indicates that the higher amount of Rh in the alloy presents a synergistic effect with Pt. Chronoamperometry tests show that both electrocatalysts have an active surface and tolerance to poisoning by intermediate products, and the presence of Ni in the ternary electrocatalyst contributes to raise this tolerance.


Funding information

The authors thank CNPq (Grants # 554613/2010-7 and # 456336/2013-3), FAPEAM, IFAM, and CAPES for funding this study.


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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2017

Authors and Affiliations

  • V. L. Marinho
    • 1
    • 2
  • L. A. Pocrifka
    • 1
  • R. R. Passos
    • 1
  1. 1.Federal University of AmazonasManausBrazil
  2. 2.Federal Institute of AmazonasParintinsBrazil

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