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TiO2@SnO2@TiO2 triple-shell nanotube anode for high-performance lithium-ion batteries

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Abstract

TiO2@SnO2@TiO2 triple-shell nanotubes are fabricated using electrospun polyacrylonitrile (PAN) nanofiber template and plasma-enhanced atomic layer deposition (PEALD). The triple-shell nanotubes have a uniform diameter of ~200 nm, and the thickness of each shell is ~10 nm. The triple-shell nanotube electrode exhibits high reversible capacity of 550 mA g−1 after 60 cycles at the current density of 50 mA g−1, stable cyclability, and high-rate performance (296 mA g−1 at high current density of 5 A g−1) as an anode for lithium-ion batteries. The excellent electrochemical properties are attributed to the structural robustness of the triple-shell nanotubes against pulverization.

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Acknowledgments

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science, ICT, and Future Planning (MSIP) (No. NRF-2015R1A5A1037627).

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Authors and Affiliations

  1. Department of Materials Science and Engineering and Research Institute of Advanced Materials (RIAM), Seoul National University, Seoul, 151-744, South Korea

    Jeong-Hoon Jean, Hoyoung Kwak, Won-Sik Kim, Hong-Chan Kim, Kyu-Young Park, Honggu Kim, Ho-Sung Yang, Woong-Ryeol Yu, Kisuk Kang & Seong-Hyeon Hong

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  1. Jeong-Hoon Jean
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  2. Hoyoung Kwak
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  3. Won-Sik Kim
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Correspondence to Seong-Hyeon Hong.

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Jean, JH., Kwak, H., Kim, WS. et al. TiO2@SnO2@TiO2 triple-shell nanotube anode for high-performance lithium-ion batteries. J Solid State Electrochem 21, 2365–2371 (2017). https://doi.org/10.1007/s10008-017-3584-5

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  • DOI: https://doi.org/10.1007/s10008-017-3584-5

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